The Organometallic Chemistry of the Transition Metals PDF Download
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Author: Robert H. Crabtree
Publisher: John Wiley & Sons
ISBN: 0471718750
Category : Science
Languages : en
Pages : 600
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Book Description
Fully updated and expanded to reflect recent advances, this Fourth Edition of the classic text provides students and professional chemists with an excellent introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications.
Author: Robert H. Crabtree
Publisher: John Wiley & Sons
ISBN: 0471718750
Category : Science
Languages : en
Pages : 600
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Book Description
Fully updated and expanded to reflect recent advances, this Fourth Edition of the classic text provides students and professional chemists with an excellent introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications.
Author: Abel M. Maharramov
Publisher: John Wiley & Sons
ISBN: 1119113857
Category : Science
Languages : en
Pages : 481
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Book Description
This book aims to overview the role of non-covalent interactions, such as hydrogen and halogen bonding, π-π, π-anion and electrostatic interactions, hydrophobic effects and van der Waals forces in the synthesis of organic and inorganic compounds, as well as in design of new crystals and function materials. The proposed book should allow to combine, in a systematic way, recent advances on the application of non-covalent interactions in synthesis and design of new compounds and functional materials with significance in Inorganic, Organic, Coordination, Organometallic, Pharmaceutical, Biological and Material Chemistries. Therefore, it should present a multi- and interdisciplinary character assuring a rather broad scope. We believe it will be of interest to a wide range of academic and research staff concerning the synthesis of new compounds, catalysis and materials. Each chapter will be written by authors who are well known experts in their respective fields.
Author: T. Keii
Publisher: Elsevier
ISBN: 0080887546
Category : Technology & Engineering
Languages : en
Pages : 597
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Book Description
Recent development of a new generation of Ziegler-Natta Catalysts using either magnesium dichloride as carrier or methylaluminoxane as cocatalyst has markedly stimulated the research activity in the field of olefin polymerization. These discoveries have not only yielded economical processes for polyolefin production but also opened the way to a new generation of novel polymers. Moreover, the nature of active species is being clarified well by the effort to simplify catalyst systems. The present volume includes 38 papers from the 31 lectures and 18 posters presented at the symposium on `Recent Developments in Olefin Polymerization Catalysts', which covered the following topics: Overview of super-active homogeneous and heterogeneous catalysts, kinetic profile of olefin polymerization including copolymerization, characterization of catalysts and polymers, methods for the determination of active center concentration, role of Lewis bases on the catalysts isospecificity, polymerization mechanisms, and synthetic pathways for functionalized polyolefins. The contents are well balanced between fundamental research and application as well as between homogeneous and heterogeneous catalyst systems.
Author: Yasushi Nishihara
Publisher: Springer Science & Business Media
ISBN: 3642323685
Category : Science
Languages : en
Pages : 247
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Book Description
“Applied Cross-Coupling Reactions” provides students and teachers of advanced organic chemistry with an overview of the history, mechanisms and applications of cross-coupling reactions. Since the discovery of the transition-metal-catalyzed cross-coupling reactions in 1972, numerous synthetic uses and industrial applications have been developed. The mechanistic studies of the cross-coupling reactions have disclosed that three fundamental reactions: oxidative addition, transmetalation, and reductive elimination, are involved in a catalytic cycle. Cross-coupling reactions have allowed us to produce a variety of compounds for industrial purposes, such as natural products, pharmaceuticals, liquid crystals and conjugate polymers for use in electronic devices. Indeed, the Nobel Prize for Chemistry in 2010 was awarded for work on cross-coupling reactions. In this book, the recent trends in cross-coupling reactions are also introduced from the point of view of synthesis design and catalytic activities of transition-metal catalysts.
Author: Richard C. Ropp
Publisher: Newnes
ISBN: 0444595538
Category : Science
Languages : en
Pages : 1201
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Book Description
Encyclopedia of the Alkaline Earth Compounds is a compilation describing the physical and chemical properties of all of the alkaline earth compounds that have been elucidated to date in the scientific literature. These compounds are used in applications such as LEDs and electronic devices such as smart phones and tablet computers. Preparation methods for each compound are presented to show which techniques have been successful. Structures and phase diagrams are presented where applicable to aid in understanding the complexities of the topics discussed. With concise descriptions presenting the chemical, physical and electrical properties of any given compound, this subject matter will serve as an introduction to the field. This compendium is vital for students and scientific researchers in all fields of scientific endeavors, including non-chemists. 2013 Honorable Mention in Chemistry & Physics from the Association of American Publishers' PROSE Awards Presents a systematic coverage of all known alkaline earth inorganic compounds and their properties Provides a clear, consistent presentation based on groups facilitatating easy comparisons Includes the structure of all the compounds in high quality full-color graphics Summarizes all currently known properties of the transition metals compounds Lists the uses and applications of these compounds in electronics, energy, and catalysis
Author: Norio Miyaura
Publisher: Springer
ISBN: 354045313X
Category : Science
Languages : en
Pages : 253
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Book Description
In 1972, a very powerful catalytic cycle for carbon-carbon bond formation was 2 first discovered by the coupling reaction of Grignard reagents at the sp -carbon. Over the past 30 years, the protocol has been substantially improved and expanded to other coupling reactions of Li,B,N,O,Al,Si,P,S,Cu,Mn,Zn,In,Sn, and Hg compounds. These reactions provided an indispensable and simple methodology for preparative organic chemists. Due to the simplicity and rel- bility in the carbon-carbon, carbon-heteroatom, and carbon-metalloid bo- formations,as well as high efficiency of the catalytic process,the reactions have been widely employed by organic chemists in various fields. Application of the protocol ranges from various syntheses of complex natural products to the preparation of biologically relevant molecules including drugs, and of sup- molecules, and to functional materials. The reactions on solid surfaces allow robot synthesis and combinatorial synthesis. Now, many organic chemists do not hesitate to use transition metal complexes for the transformation of org- ic molecules. Indeed, innumerable organic syntheses have been realized by the catalyzed reactions of transition metal complexes that are not achievable by t- ditional synthetic methods. Among these, the metal-catalyzed cross-coupling reactions have undoubtedly contributed greatly to the development of such a new area of “metal-catalyzed organic syntheses”. An excellent monograph for the cross-coupling reactions and other met- catalyzed C-C bond-forming reactions recently appeared in Metal-catalyzed Cross-coupling Reactions (Wiley-VCH,1998).
Author: Steven P. Nolan
Publisher: Wiley-VCH
ISBN: 9783527334902
Category : Science
Languages : en
Pages : 0
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Book Description
This comprehensive reference and handbook covers in depth all major aspects of the use of N-heterocyclic carbene-complexes in organic synthesis: from the theoretical background to characterization, and from cross-coupling reactions to olefin metathesis. Edited by a leader and experienced scientist in the field of homogeneous catalysis and use of NHCs, this is an essential tool for every academic and industrial synthetic chemist.
Author: J. A. McCleverty
Publisher: Newnes
ISBN: 0080913164
Category : Science
Languages : en
Pages : 11845
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Book Description
Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.
Author: Dennis G. Hall
Publisher: John Wiley & Sons
ISBN: 3527606823
Category : Science
Languages : en
Pages : 571
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Book Description
For the first time, the whole field of organoboronic acids is presented in one comprehensive handbook. Professor Dennis Hall, a rising star within the community, covers all aspects of this important substance class, including applications in chemistry, biology and medicine. Starting with an introduction to the structure, properties, and preparation of boronic acid derivatives, together with an overview of their reactions and applications, the book goes on to look at metal-catalyzed borylation of alkanes and arenas, coupling reactions and rhodium-catalyzed additions of boronic acids to alkenes and carbonyl compounds. There follows chapters on copper-promoted C-O and C-N cross-coupling of boronic acids, recent applications in organic synthesis, as well as alpha-haloalkylboronic esters in asymmetric synthesis. Later sections deal with cycloadditions, organoboronic acids, oxazaborolidines as asymmetric inducers, and boronic acid based receptors and sensors. The whole is rounded off with experimental procedures, making this invaluable reading for organic, catalytic and medicinal chemists, as well as those working in organometallics.
Author: J.W. Gorrod
Publisher: Elsevier
ISBN: 0080525512
Category : Science
Languages : en
Pages : 773
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Book Description
This book provides for the first time a single comprehensive source of information on the analytical chemistry of nicotine and related alkaloids. The editors have brought together scientists from academia and the tobacco industry to describe the state-of-the-art of the chemistry and analytical methods for measurement of nicotine. Both the scope and detail of the book are impressive. Chapters describe the history, pharmacology and toxicology of nicotine, the biosynthesis of nicotine and other alkaloids in the tobacco plant, the general chemistry of nicotine and the analytical methodologies that have been used to measure nicotine and related alkaloids in biological specimens, in tobacco and pharmaceutical products and in tobacco smoke. There is also a comprehensive review of the chemistry and toxicology of nicotine-derived nitrosamines, an important class of tobacco carcinogens.
