Sensor Based Modeling of Chemical Mechanical Planarization (CMP) of Copper for Semiconductor Applications PDF Download
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Author: Upendra Milind Phatak
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author: Upendra Milind Phatak
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author: Sakthi Jaya Rahul Ravichandran
Publisher:
ISBN:
Category :
Languages : en
Pages : 110
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Copper electrochemical mechanical polishing (Cu ECMP) has attracted many scientists in the field of semiconductor manufacturing industry, as they are investigating whether to replace chemical mechanical polishing (CMP) with Cu ECMP after the introduction of porous low - k dielectric materials because of its increased efficiency and better quality. An approach to locating real time variations in Cu ECMP processes has been identified. The various regions in Cu ECMP, active, passive, trans-passive, and transient regions have been explored through current and voltage signals obtained from a data acquisition setup hooked up with the process. Extensive work has been done in characterizing and optimizing the process, but little work has been done in correlating the key process input variables (KPIV) such as voltage, platen speed and wafer carrier speed with the key process output variables (KPOV) such as the material removal rate (MRR) and surface roughness (Ra) using time-frequency patterns of the current-voltage signals and statistical models. Based on these analytical methods, optimal surface value was realized in the transient/trans-passive region. A mathematical model depicting ECMP was implemented in COMSOL to understand the characteristics of the process, which will be a great breakthrough in the field of semiconductor manufacturing.
Author: Robert Leon Opila
Publisher: The Electrochemical Society
ISBN: 9781566772600
Category : Technology & Engineering
Languages : en
Pages : 664
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This volume contains the proceedings of the third international symposium on Chemical Mechanical Planarization integrated circuit device manufacturing held at the 196th Meeting of the Electrochemical Society in Honolulu, Hawaii. ( October 20 -22 1999).
Author: Seungchoun Choi
Publisher:
ISBN:
Category :
Languages : en
Pages : 166
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With stringent requirements of copper chemical mechanical planarization (CMP), such as minimized step heights, enhanced uniformity and minimal defects, the CMP process needs to be improved based on a fundamental understanding of the material removal mechanisms. Also, with the stringent requirements, the problems in copper CMP process cannot be resolved solely improving the process itself; rather, systemic understanding of the entire manufacturing processes is necessary, demanding a robust copper CMP model to be implemented to design for manufacturing (DfM) tools. Previous models heavily relied on Preston's equation (), which needs to be calibrated for every new set of processing parameters, slowing down the process development. Previous models focused on limited interactions of the consumables and the workpiece during copper CMP, being insufficient at capturing the synergies between chemical and mechanical aspects of copper CMP. Therefore, a quantitative and physicochemical model of copper CMP that predicts material removal rate (MRR) was proposed while focusing on the interplay of consumables and copper and the synergies between chemical and mechanical aspects of the process. While considering the synergies, two mechanisms of the material removal during copper CMP were suggested: chemically dominant and mechanically dominant mechanisms. The total MRR during copper CMP was determined by summing those two contributions. The chemically dominant mechanism attributed the material removal during copper CMP to the removal of the protective material formed on the surface of copper and to the chemical dissolution of copper from the surface both at regions occupied and not occupied by the protective material with different rates. The kinetics of the formation of the protective material at the millisecond scale were studied through electrochemical experiments and theoretical analysis where a governing equation for the adsorption of benzotriazole (BTA) was constructed and solved. It was found that the grown protective material (CuBTA) during copper CMP was only a fraction of a monolayer partly occupying the surface of a wafer. This was because the time allowed for the adsorption of BTA on the surface of copper was limited by the time between consecutive asperity and copper interactions, which was only of the order of one millisecond. The formation and the removal of the protective material were assumed to be balanced during CMP, yielding a constant chemically dominant MRR. The removal of the protective material by abrasion with abrasive particles was investigated by in situ electrochemical measurement during polishing. The removal efficiency of a pad asperity where abrasive particles are embedded was evaluated from the measurements and was compared with the theoretical analysis. It showed a good agreement and suggested that the copper during CMP is mostly deformed elastically by the abrasive particles. The influence of the concentration of copper ions on the kinetics of the formation of the protective material was also investigated using potential-step chronoamperometry using two types of copper microelectrode, namely a three dimensional and a planar electrode. The amount of copper ion may easily build up to a level that exceeds the solubility product of Cu(II)BTA2. Under these conditions, Cu(II)BTA2 can nucleate, consuming the protective material formed on the surface of copper. This phenomenon is highly undesirable as it increases the dissolution rates at the regions where the protective material is removed, worsening the topography after copper CMP. The mechanically dominant MRR was determined from the volume of a wafer that is plastically deformed by indentation of abrasives that are squeezed between pad asperities and the wafer. The shear stress induced in copper by the force applied on an abrasive is lower than the ideal shear strength of copper, which is the relevant property for plasticity at this length scale. However, the crystallographic defects in the copper crystal may reduce the hardness of the material, allowing the material to be plastically deformed. Especially the roughness of the surface induced by chemical additives in the slurry greatly reduces the resistance to plastic deformation of copper. Because of the localized spatial distribution of those crystallographic defects the plastic deformation occurs only locally. Also, only a part of the plastically deformed material will be detached from the surface, contributing to the MRR. While applying this mechanism, the discrepancy of the MRR behavior with varying size and concentration of abrasives between the prediction and the experimental observations was resolved by proposing a new mechanism that determines the number of abrasives participating in the abrasion of the material. The transport mechanisms of abrasive particles toward a wafer and the electrostatic interactions between abrasives were considered to affect the number of abrasive particles deposited on the surface of a wafer. If the deposition of abrasives on the surface of a wafer is limited by the diffusion of abrasives, the MRR decreases with the size of the abrasives. In contrast, the MRR increases with the size of abrasives if the deposition of the abrasives is limited by the jamming limit of the deposited abrasives at the surface of the wafer. Also, micrometer sized abrasives increases the MRR when the size is increased because the deposition of abrasives is limited by the interception mechanism of the abrasives. The proposed model successfully captured the synergies between chemical and mechanical aspects and quantitatively predicted the MRR during copper CMP. In the future, the model will be applied to predict the pattern dependent variability of topography of a wafer after CMP. The proposed model quantitatively predicts the local MRR of copper. Along with a robust model for dielectric and barrier materials, the model can predict the topography after CMP, contributing to the optimization of the CMP process.
Author: Dongkai Shangguan
Publisher: CRC Press
ISBN: 1040028640
Category : Technology & Engineering
Languages : en
Pages : 463
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Book Description
In the “More than Moore” era, performance requirements for leading edge semiconductor devices are demanding extremely fine pitch interconnection in semiconductor packaging. Direct copper interconnection has emerged as the technology of choice in the semiconductor industry for fine pitch interconnection, with significant benefits for interconnect density and device performance. Low-temperature direct copper bonding, in particular, will become widely adopted for a broad range of highperformance semiconductor devices in the years to come. This book offers a comprehensive review and in-depth discussions of the key topics in this critical new technology. Chapter 1 reviews the evolution and the most recent advances in semiconductor packaging, leading to the requirement for extremely fine pitch interconnection, and Chapter 2 reviews different technologies for direct copper interconnection, with advantages and disadvantages for various applications. Chapter 3 offers an in-depth review of the hybrid bonding technology, outlining the critical processes and solutions. The area of materials for hybrid bonding is covered in Chapter 4, followed by several chapters that are focused on critical process steps and equipment for copper electrodeposition (Chapter 5), planarization (Chapter 6), wafer bonding (Chapter 7), and die bonding (Chapter 8). Aspects related to product applications are covered in Chapter 9 for design and Chapter 10 for thermal simulation. Finally, Chapter 11 covers reliability considerations and computer modeling for process and performance characterization, followed by the final chapter (Chapter 12) outlining the current and future applications of the hybrid bonding technology. Metrology and testing are also addressed throughout the chapters. Business, economic, and supply chain considerations are discussed as related to the product applications and manufacturing deployment of the technology, and the current status and future outlook as related to the various aspects of the ecosystem are outlined in the relevant chapters of the book. The book is aimed at academic and industry researchers as well as industry practitioners, and is intended to serve as a comprehensive source of the most up-to-date knowledge, and a review of the state-of-the art of the technology and applications, for direct copper interconnection and advanced semiconductor packaging in general.
Author: Shyam P. Murarka
Publisher: Wiley-Interscience
ISBN:
Category : Science
Languages : en
Pages : 376
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A complete guide to the state of the art and future direction of copper interconnect technology Owing to its performance advantages, copper metallization for IC interconnect is attracting tremendous interest in the semiconductor community worldwide. This timely book provides scientists and engineers with a much-needed, comprehensive reference on the fundamentals and applications of this emerging technology. The authors draw on more than a decade of intimate involvement with copper interconnect research, integrating the vast amounts of available knowledge and making clear the connection between mechanistic principles and relevant technologies. In-depth, cutting-edge discussions include: * The effects of copper in semiconductor materials, especially silicon * The fundamental chemistry and electro-chemistry of copper * The effects of copper on insulating materials such as glass and polymers * Intermetallic and interfacial reactions of copper in layered structures * Current and projected applications of copper in integrated circuits Copper-Fundamental Mechanisms for Microelectronic Applications also features extensive references, tables, and over 100 illustrations-including dual Damascene patterning necessary for copper interconnects. It is an excellent resource for anyone seeking to explore the current literature and gain insight into opportunities opening in the field.
Author: Babu Suryadevara
Publisher: Woodhead Publishing
ISBN: 0128218193
Category : Technology & Engineering
Languages : en
Pages : 650
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Advances in Chemical Mechanical Planarization (CMP), Second Edition provides the latest information on a mainstream process that is critical for high-volume, high-yield semiconductor manufacturing, and even more so as device dimensions continue to shrink. The second edition includes the recent advances of CMP and its emerging materials, methods, and applications, including coverage of post-CMP cleaning challenges and tribology of CMP. This important book offers a systematic review of fundamentals and advances in the area. Part one covers CMP of dielectric and metal films, with chapters focusing on the use of current and emerging techniques and processes and on CMP of various materials, including ultra low-k materials and high-mobility channel materials, and ending with a chapter reviewing the environmental impacts of CMP processes. New content addressed includes CMP challenges with tungsten, cobalt, and ruthenium as interconnect and barrier films, consumables for ultralow topography and CMP for memory devices. Part two addresses consumables and process control for improved CMP and includes chapters on CMP pads, diamond disc pad conditioning, the use of FTIR spectroscopy for characterization of surface processes and approaches for defection characterization, mitigation, and reduction. Advances in Chemical Mechanical Planarization (CMP), Second Edition is an invaluable resource and key reference for materials scientists and engineers in academia and R&D. Reviews the most relevant techniques and processes for CMP of dielectric and metal films Includes chapters devoted to CMP for current and emerging materials Addresses consumables and process control for improved CMP, including post-CMP
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 798
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The novel consumables studied were abrasive-free copper CMP slurries and high-pressure micro jet technology as an alternative to diamond pad conditioning. Abrasive-free slurries were found to be effective in copper removal and were shown to demonstrate similar removal rate and coefficient of friction (COF) trends as conventional abrasive slurry CMP, while possibly decreasing wafer defects. Fundamental information from the friction spectrum indicated that the periodicity of the cyclic passivation layer formation and removal in copper CMP may be on the order of 10 milliseconds. HPMJ technology was found to be a possible alternative to diamond conditioning with some decrease in removal rate. A controlled atmosphere polishing (CAP) system was used and demonstrated that gaseous additives can feasibly be introduced real-time during a polish. Addition of complexing agents were found to increase removal rates, however it was found that direct etching of copper oxide on the copper surface was not the primary mechanism responsible for removal rate increases during CMP with low oxidant concentrations. Alternatively, it was found that direct etching of the copper oxide is significant in systems containing much higher oxidant concentrations, 1 wt% hydrogen peroxide for example. It was for this reason that a third removal step, chemical dissolution, was added to the two-step removal rate model. The remainder of the work in this dissertation was concerned with characterizing and modeling the copper oxidation and copper oxide dissolution steps of the three-step model separately and applying the appropriate expressions into the CMP removal rate model. The copper oxidation process was found to demonstrate oxide growth, or passivation behavior, at pH of 5 and higher. The oxide growth process was governed by oxidized copper migration through the oxide film. The copper oxide dissolution process was controlled by dissolution of the complexing agent through a dissolution byproduct film. These steps were characterizedand applied to the three-step removal rate and predicted removal rate data quite well with one fitting parameter that varied within one order of magnitude. Two real-time experimental measurements, COF and leading pad temperature, can be input into the model to predict removal rates during a polish.
Author: Kelly Marie Fishbeck
Publisher:
ISBN:
Category : Atomic force microscopy
Languages : en
Pages : 144
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Author:
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 1006
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