Relaxation Processes in Molecular Excited States

Relaxation Processes in Molecular Excited States PDF Author: J. Fünfschilling
Publisher: Springer Science & Business Media
ISBN: 9400908636
Category : Science
Languages : en
Pages : 282

Get Book Here

Book Description
Relaxation phenomena of excited molecular states are abundant in all nature. They mediate such key processes as photochemical reactions or even the pathways of ordinary chemical reactions. However, for a long time the main research in electronic relaxation processes was concerned with anorganic solids, in part because of their great technological importance (photography, semiconductors ... ) in part also because these compounds were the "workhorses" of the solid state physicists. In the last 30 years, there was a steadily increasing interest in organic molecular systems, first in molecular crystals and later in all forms of molecular solids (glasses, polymers, membranes, ... ). The present volume combines papers on quite different types of relaxation phenomena: the type of solid studied, the electronic states involved, the physical processes responsible for the relaxations are all different. Nevertheless, after reading this book, a more clear and complete picture of the phenomenon "relaxa tion" emerges that proves that this volume is more than just a collection of individual articles. The volume starts with the paper "Spin-lattice and spin-spin relaxation in photo-excited triplet states in molecular crystals" by Jan Schmidt. Even in these seemingly simple systems of isolated guest molecules in a single crystal host, the relaxation phenomena are quite involved and a very thorough investigation is necessary to find the key relaxation processes. The end of the article provides a bridge to the following paper: it treats interactions of two molecules (dimers), where resonant interactions become important and lead to new, characteristic relaxation processes.

Relaxation Processes in Molecular Excited States

Relaxation Processes in Molecular Excited States PDF Author: J. Fünfschilling
Publisher: Springer Science & Business Media
ISBN: 9400908636
Category : Science
Languages : en
Pages : 282

Get Book Here

Book Description
Relaxation phenomena of excited molecular states are abundant in all nature. They mediate such key processes as photochemical reactions or even the pathways of ordinary chemical reactions. However, for a long time the main research in electronic relaxation processes was concerned with anorganic solids, in part because of their great technological importance (photography, semiconductors ... ) in part also because these compounds were the "workhorses" of the solid state physicists. In the last 30 years, there was a steadily increasing interest in organic molecular systems, first in molecular crystals and later in all forms of molecular solids (glasses, polymers, membranes, ... ). The present volume combines papers on quite different types of relaxation phenomena: the type of solid studied, the electronic states involved, the physical processes responsible for the relaxations are all different. Nevertheless, after reading this book, a more clear and complete picture of the phenomenon "relaxa tion" emerges that proves that this volume is more than just a collection of individual articles. The volume starts with the paper "Spin-lattice and spin-spin relaxation in photo-excited triplet states in molecular crystals" by Jan Schmidt. Even in these seemingly simple systems of isolated guest molecules in a single crystal host, the relaxation phenomena are quite involved and a very thorough investigation is necessary to find the key relaxation processes. The end of the article provides a bridge to the following paper: it treats interactions of two molecules (dimers), where resonant interactions become important and lead to new, characteristic relaxation processes.

Excited States

Excited States PDF Author: Edward C. Lim
Publisher:
ISBN:
Category : Energy levels (Quantum mechanics)
Languages : en
Pages : 368

Get Book Here

Book Description


Relaxation Processes in Electronically Excited Molecules (A) Intramolecular Excimers (B) Excited State Proton Transfer

Relaxation Processes in Electronically Excited Molecules (A) Intramolecular Excimers (B) Excited State Proton Transfer PDF Author: Phaedon Avouris
Publisher:
ISBN:
Category : Excited state chemistry
Languages : en
Pages : 530

Get Book Here

Book Description


Excited States V5

Excited States V5 PDF Author: Edward Lim
Publisher: Elsevier
ISBN: 0323159982
Category : Science
Languages : en
Pages : 217

Get Book Here

Book Description
Excited States, Volume 5 consists of three concise and detailed chapters. These chapters cover the topics of excited-state potential surfaces of polyatomic molecules; vibronic spectroscopy of benzene; and quantum statistical mechanical (QSM) theory for molecular relaxation processes. Chapter 1 discusses excited-state potential surfaces with focus on ab initio calculations. Simple methods of computational schemes are also presented in this chapter. Chapter 2 reviews the excited electronic states of benzene. This chapter also includes the basic theory of benzene electronic excitations and the various types of spectroscopy (absorption, vibrational Raman, and electron-impact). Lastly, Chapter 3 presents a unified QSM theory, phenomenological theory of irreversible thermodynamics, and kinetics. The focus of QSM theory is on the nonlinear domain and is used to construct a nonlinear theory for the relaxation of excited molecules that are electric, vibrating, and rotating. This volume is a good reference for students and researchers studying in the field of chemistry and physics.

Radiationless Transitions

Radiationless Transitions PDF Author: Sheng Lin
Publisher: Elsevier
ISBN: 0323150276
Category : Science
Languages : en
Pages : 440

Get Book Here

Book Description
Radiationless Transitions is a critical discussion of research studies on the theory and experiments in radiationless transitions. This book is composed of nine chapters, and begins with discussions on the theory and experiment of photophysical processes of single vibronic levels and/or single rovibronic levels. The subsequent chapters deal with the spectroscopic investigations of intramolecular vibrational relaxation; the dynamics of molecular excitation by light; and the photophysical processes of small molecules in condensed phase. The discussions then shift to the high pressure effects on molecular luminescence and the internal conversion involving localized excitations, presenting one qualitative and one quantitative example, as well as the intersystem crossing with localized excitations. A chapter explores the energy transfer processes that occur after a molecule in solution is excited by light, with an emphasis on solid solutions in which the large amplitude molecular motion is largely quenched. This chapter also looks into the liquid solutions in which the molecules can translate and rotate under the influence of fluctuating forces from the liquid. The concluding chapter focuses on ultrafast processes. Researchers in the fields of physics, chemistry, and biology will benefit from this book.

Springer Handbook of Inorganic Photochemistry

Springer Handbook of Inorganic Photochemistry PDF Author: Detlef Bahnemann
Publisher: Springer Nature
ISBN: 3030637131
Category : Science
Languages : en
Pages : 1914

Get Book Here

Book Description
The handbook comprehensively covers the field of inorganic photochemistry from the fundamentals to the main applications. The first section of the book describes the historical development of inorganic photochemistry, along with the fundamentals related to this multidisciplinary scientific field. The main experimental techniques employed in state-of-art studies are described in detail in the second section followed by a third section including theoretical investigations in the field. In the next three sections, the photophysical and photochemical properties of coordination compounds, supramolecular systems and inorganic semiconductors are summarized by experts on these materials. Finally, the application of photoactive inorganic compounds in key sectors of our society is highlighted. The sections cover applications in bioimaging and sensing, drug delivery and cancer therapy, solar energy conversion to electricity and fuels, organic synthesis, environmental remediation and optoelectronics among others. The chapters provide a concise overview of the main achievements in the recent years and highlight the challenges for future research. This handbook offers a unique compilation for practitioners of inorganic photochemistry in both industry and academia.

Molecular Photonics

Molecular Photonics PDF Author: Kazuyuki Horie
Publisher: John Wiley & Sons
ISBN: 3527613218
Category : Technology & Engineering
Languages : en
Pages : 216

Get Book Here

Book Description
New organic compounds with interesting and improved electronic and photonic properties are being reported on a daily basis, with new light-triggered materials being designed for molecular and bioelectronic devices. The relatively new concept of molecular photonics embraces photochemistry and photophysics, dealing with light-induced changes in materials and their electronic states as well as the field of optics. This volume begins with a background and survey of current light-related research fields, moving on to the fundamentals of molecular photonics. Subsequent chapters deal with the characteristics of photochemical reaction and typical processes of photophysical chemistry, while the last two chapters focus on the study of materials-induced changes in light. The most important concepts are summarized in overview tables to promote active understanding of new topics. .

The World of Quantum Chemistry

The World of Quantum Chemistry PDF Author: R. Daudel
Publisher: Springer Science & Business Media
ISBN: 9401021562
Category : Science
Languages : en
Pages : 321

Get Book Here

Book Description
Proceedings of the First International Congress of Quantum Chemistry, held at Menton, France, July 4-10, 1973

Computational Optical Imaging

Computational Optical Imaging PDF Author: Zhengjun Liu
Publisher: Springer Nature
ISBN: 9819714559
Category :
Languages : en
Pages : 420

Get Book Here

Book Description


Instrumental Methods of Chemical Analysis

Instrumental Methods of Chemical Analysis PDF Author: Dr. B. K. Sharma
Publisher: Krishna Prakashan Media
ISBN: 9788182830196
Category :
Languages : en
Pages : 1726

Get Book Here

Book Description