Recombination Between Carbon Monoxide and Excited Oxygen Atoms PDF Download
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Author: Atomic Energy Research Establishment (Harwell, England)
Publisher:
ISBN:
Category :
Languages : en
Pages : 12
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Author: Atomic Energy Research Establishment (Harwell, England)
Publisher:
ISBN:
Category :
Languages : en
Pages : 12
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Author: J. H. Tait
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ISBN:
Category :
Languages : en
Pages : 12
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Author: Theodore A. Brabbs
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ISBN:
Category : Aerodynamics
Languages : en
Pages : 28
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Author: Richard Bruce Solo
Publisher:
ISBN:
Category : Carbon monoxide
Languages : en
Pages : 216
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Author: Anthony M. Dean
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ISBN:
Category :
Languages : en
Pages : 27
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For some time now this laboratory has been utilizing nitrous oxide as a high temperature source of oxygen atoms. Recently, an independent technique has been used to calibrate the detector system for oxygen atoms. With this calibration factor known, more refined experiments have been performed in which the absolute oxygen atom concentration can be monitored as a function of time. It was found that only slight modifications of earlier rate constant assignments were required to quantitatively explain these new results. In this light it is now felt that the dissociation kinetics of N2O are reasonably well understood. Thus the CO2 production rate in N2O/CO mixtures has been measured in an attempt to determine k sub r. It is shown that small amount of impurities can drastically affect the CO2 production rate. Analysis of this impurity effect has yielded estimates of the actual recombination rate constant between 2100 and 3200 K. The value of k sub r determined in this way is shown to be consistent with the recent measurements of k sub d reported by Wagner, and Kiefer, which yielded normal activation energies for CO2 dissociation.
Author: B. F. Myers
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Category :
Languages : en
Pages : 29
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A search has been made for materials which could act as effective catalysts for oxygen atom recombination. Ten gases have been examined for this effect in the temperature range 297 K to 753 K over a pressure interval of 0.2 mm to 2.0 mm Hg. No effective catalysts were discovered among the following gases: boron trifluoride, carbon dioxide, carbon tetrafluoride, sulfur hexafluoride, carbonyl sulfide, carbon disulfide, carbon monoxide, monomethylamine, stannic chloride and sulfur dioxide. A few solids were tested and of these graphite exhibited interesting catalytic activity. An indication of its possible effectiveness was given by calculating the ratio of the rate loss of oxygen atoms in its presence to that in its absence. The upper limit to this ratio was found to be 2500 at 10 to the -4th power atmosphere and 300 K. (Author).
Author: Edward Weissberger
Publisher:
ISBN:
Category : Oxygen
Languages : en
Pages : 188
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Author: Albert S. Bergendahl
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Category :
Languages : en
Pages : 23
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Author:
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Category : Aeronautics
Languages : en
Pages : 1368
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Author: J. C. Greaves
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ISBN:
Category : Electric discharges through gases
Languages : en
Pages : 9
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