Phase Behavior of Light Gases in Hydrocarbon and Aqueous Solvents PDF Download
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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 56
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Book Description
Under previous support from the Department of Energy, an experimental facility has been established and operated to measure valuable vapor-liquid equilibrium data for systems of interest in the production and processing of coal fluids. To facilitate the development and testing of models for prediction of the phase behavior for such systems, we have acquired substantial amounts of data on the equilibrium phase compositions for binary mixtures of heavy hydrocarbon solvents with a variety of supercritical solutes, including hydrogen, methane, ethane, carbon monoxide, and carbon dioxide. The present project focuses on measuring the phase behavior of light gases and water in Fischer-Tropsch (F-T) type solvents at conditions encountered in indirect liquefaction processes and evaluating and developing theoretically-based correlating frameworks to predict the phase behavior of such systems. Specific goals of the proposed work include (a) developing a state-of-the-art experimental facility to permit highly accurate measurements of equilibrium phase compositions (solubilities) of challenging F-T systems, (b) measuring these properties for systematically-selected binary, ternary and molten F-T wax mixtures to provide critically needed input data for correlation development, (c) developing and testing models suitable for describing the phase behavior of such mixtures, and (d) presenting the modeling results in generalized, practical formats suitable for use in process engineering calculations. During the present reporting period, our solubility apparatus was refurbished and restored to full service. To test the experimental apparatus and procedures used, measurements were obtained for the solubility Of C02 in benzene at 160°F. Having confirmed the accuracy of the newly acquired data in comparison with our previous measurements and data reported in the literature for this test system, we have begun to measure the solubility of hydrogen in hexane. The measurements for this system will cover the temperature range from 160 to 280°F at pressures to 2,500 psia. As part of our model evaluation efforts, we examined the predictive abilities of an alternative approach we have proposed for calculating the phase behavior properties of highly non-ideal systems. Using this approach, the liquid phase fugacities generated from an equation of state (EOS) are augmented by a fugacity deviation function correction. The correlative abilities of this approach are compared with those of an EOS equipped with the recently introduced Wong-Sandler (MWS) mixing rules. These two approaches are compared with the current methods for vapor-liquid equilibrium (VLE) calculations, i.e., the EOS (0/0) approach with the van der Waals mixing rules and the split (y/0) approach. The evaluations were conducted on a database comprised of non-ideal low pressure binary systems as well as asymmetric high pressure binary systems. These systems are of interest in the coal liquefaction and utilization processes. The Peng-Robinson EOS was selected for the purposes of this evaluation.
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 56
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Book Description
Under previous support from the Department of Energy, an experimental facility has been established and operated to measure valuable vapor-liquid equilibrium data for systems of interest in the production and processing of coal fluids. To facilitate the development and testing of models for prediction of the phase behavior for such systems, we have acquired substantial amounts of data on the equilibrium phase compositions for binary mixtures of heavy hydrocarbon solvents with a variety of supercritical solutes, including hydrogen, methane, ethane, carbon monoxide, and carbon dioxide. The present project focuses on measuring the phase behavior of light gases and water in Fischer-Tropsch (F-T) type solvents at conditions encountered in indirect liquefaction processes and evaluating and developing theoretically-based correlating frameworks to predict the phase behavior of such systems. Specific goals of the proposed work include (a) developing a state-of-the-art experimental facility to permit highly accurate measurements of equilibrium phase compositions (solubilities) of challenging F-T systems, (b) measuring these properties for systematically-selected binary, ternary and molten F-T wax mixtures to provide critically needed input data for correlation development, (c) developing and testing models suitable for describing the phase behavior of such mixtures, and (d) presenting the modeling results in generalized, practical formats suitable for use in process engineering calculations. During the present reporting period, our solubility apparatus was refurbished and restored to full service. To test the experimental apparatus and procedures used, measurements were obtained for the solubility Of C02 in benzene at 160°F. Having confirmed the accuracy of the newly acquired data in comparison with our previous measurements and data reported in the literature for this test system, we have begun to measure the solubility of hydrogen in hexane. The measurements for this system will cover the temperature range from 160 to 280°F at pressures to 2,500 psia. As part of our model evaluation efforts, we examined the predictive abilities of an alternative approach we have proposed for calculating the phase behavior properties of highly non-ideal systems. Using this approach, the liquid phase fugacities generated from an equation of state (EOS) are augmented by a fugacity deviation function correction. The correlative abilities of this approach are compared with those of an EOS equipped with the recently introduced Wong-Sandler (MWS) mixing rules. These two approaches are compared with the current methods for vapor-liquid equilibrium (VLE) calculations, i.e., the EOS (0/0) approach with the van der Waals mixing rules and the split (y/0) approach. The evaluations were conducted on a database comprised of non-ideal low pressure binary systems as well as asymmetric high pressure binary systems. These systems are of interest in the coal liquefaction and utilization processes. The Peng-Robinson EOS was selected for the purposes of this evaluation.
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 62
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Book Description
Under previous support from the US Department of Energy, an experimental facility has been established and operated to measure valuable vapor-liquid equilibrium data for systems of interest in the production and processing of coal fluids. To facilitate the development and testing of models for prediction of the phase behavior for such systems, we have acquired substantial amounts of data on the equilibrium phase compositions for binary mixtures of heavy hydrocarbon solvents with a variety of supercritical solutes, including hydrogen, methane, ethane, carbon monoxide, and carbon dioxide. The present project focuses on measuring the phase behavior of light gases and water in Fischer-Tropsch (F-T) type solvents at conditions encountered in indirect liquefaction processes and evaluating and developing theoretically-based correlating frameworks to predict the phase behavior of such systems. Specific goals of the proposed work include (a) developing a state-of-the-art experimental facility to permit highly accurate measurements of equilibrium phase compositions (solubilities) of challenging F-T systems, (b) measuring these properties for systematically-selected binary, ternary and molten F-T wax mixtures to provide critically needed input data for correlation development, (c) developing and testing models suitable for describing the phase behavior of such mixtures, and (d) presenting the modeling results in generalized, practical formats suitable for use in process engineering calculations. During the present reporting period, the solubilities of hydrogen in n-hexane, carbon monoxide in cyclohexane, and nitrogen in phenanthrene and pyrene were measured using a static equilibrium cell over the temperature range from 344.3 to 433.2 K and pressures to 22.8 MPa. The uncertainty in these new solubility measurements is estimated to be less than 0.001 in mole fraction. The data were analyzed using the Peng-Robinson (PR) equation of state (EOS). In general, the PR EOS represents the experimental data well when a single interaction parameter (C{sub ij}) is used for each isotherm. In addition, the predictive capability of the modified Park-Gasem-Robinson (PGR) equation of state (EOS) was evaluated for selected carbon dioxide + normal paraffins, ethane + normal paraffins, and hydrogen + normal paraffins. A set of mixing rules was proposed for the modified EOS to extend its predictive capabilities to mixtures. The predicted bubble point pressures for the ethane + n-paraffin and carbon dioxide + n-paraffin binaries were compared to those of the Peng-Robinson (PR), simplified-perturbed-hard-chain theory (SPHCT) and original PGR equations. The predictive capability of the proposed equation is better or comparable to the PR, SPHCT and original PGR equations of state for the ethane binaries (%AAD of 1.9) and carbon dioxide binaries (%AAD of 2.0). For the hydrogen binaries, the modified PGR EOS showed much better performance (%AAD of 1.7) than the original PGR equation and comparable to the PR equation.
Author: University of Michigan. College of Engineering
Publisher:
ISBN:
Category : Hydrocarbons
Languages : en
Pages : 118
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Book Description
Author: Karen Schou Pedersen
Publisher: CRC Press
ISBN: 1040002099
Category : Science
Languages : en
Pages : 642
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Book Description
Developed in conjunction with several oil companies using experimental data for real reservoir fluids, Phase Behavior of Petroleum Reservoir Fluids introduces industry standard methods for modeling the phase behavior of petroleum reservoir fluids at different stages in the process. Keeping mathematics to a minimum, this book discusses sampling, characterization, compositional analyses, and equations of state used to simulate various pressure–volume–temperature (PVT) properties of reservoir fluids. The Third Edition has been updated throughout. Reflects advances in equation of state modeling for reservoir fluids and CO2-rich fluids Presents association models along with non-classical mixing rules for handling fluids with aqueous components Has an extended coverage of reservoir fluid communication, energy properties, and asphaltene precipitation Provides practical knowledge essential for achieving optimal design and cost-effective operations in a petroleum processing plant This book offers engineers working in the energy sector a solid understanding of the phase behavior of the various fluids present in a petroleum reservoir.
Author: M. A. Hildebrand
Publisher:
ISBN:
Category : Hydrocarbons
Languages : en
Pages : 28
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Book Description
Author: Alireza Bahadori
Publisher: Gulf Professional Publishing
ISBN: 0128034467
Category : Technology & Engineering
Languages : en
Pages : 556
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Book Description
Fluid Phase Behavior for Conventional and Unconventional Oil and Gas Reservoirs delivers information on the role of PVT (pressure-volume-temperature) tests/data in various aspects, in particular reserve estimation, reservoir modeling, flow assurance, and enhanced oil recovery for both conventional and unconventional reservoirs. This must-have reference also prepares engineers on the importance of PVT tests, how to evaluate the data, develop an effective management plan for flow assurance, and gain perspective of flow characterization, with a particular focus on shale oil, shale gas, gas hydrates, and tight oil making. This book is a critical resource for today’s reservoir engineer, helping them effectively manage and maximize a company’s oil and gas reservoir assets. Provides tactics on reservoir phase behavior and dynamics with new information on shale oil and gas hydrates Helps readers Improve on the effect of salt concentration and application to C02-Acid Gas Disposal with content on water-hydrocarbon systems Provides practical experience with PVT and tuning of EOS with additional online excel spreadsheet examples
Author: Chang Samuel Hsu
Publisher: Springer
ISBN: 3319493477
Category : Science
Languages : en
Pages : 1243
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Book Description
This handbook provides a comprehensive but concise reference resource for the vast field of petroleum technology. Built on the successful book "Practical Advances in Petroleum Processing" published in 2006, it has been extensively revised and expanded to include upstream technologies. The book is divided into four parts: The first part on petroleum characterization offers an in-depth review of the chemical composition and physical properties of petroleum, which determine the possible uses and the quality of the products. The second part provides a brief overview of petroleum geology and upstream practices. The third part exhaustively discusses established and emerging refining technologies from a practical perspective, while the final part describes the production of various refining products, including fuels and lubricants, as well as petrochemicals, such as olefins and polymers. It also covers process automation and real-time refinery-wide process optimization. Two key chapters provide an integrated view of petroleum technology, including environmental and safety issues.Written by international experts from academia, industry and research institutions, including integrated oil companies, catalyst suppliers, licensors, and consultants, it is an invaluable resource for researchers and graduate students as well as practitioners and professionals.
Author: Curtis H. Whitson
Publisher: Society of Petroleum Engineers
ISBN:
Category : Business & Economics
Languages : en
Pages : 248
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Book Description
Phase Behavior provides the reader with the tools needed to solve problems requiring a description of phase behavior and specific pressure/volume/temperature (PVT) properties.
Author: Sauro Pierucci
Publisher: Elsevier
ISBN: 008053130X
Category : Technology & Engineering
Languages : en
Pages : 1207
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Book Description
This book includes papers presented at ESCAPE-10, the 10th European Symposium on Computer Aided Process -Engineering, held in Florence, Italy, 7-10th May, 2000. The scientific program reflected two complementary strategic objectives of the 'Computer Aided Process Engineering' (CAPE) Working Party: one checked the status of historically consolidated topics by means of their industrial application and their emerging issues, while the other was addressed to opening new windows to the CAPE audience by inviting adjacent Working Parties to co-operate in the creation of the technical program. The former CAPE strategic objective was covered by the topics: Numerical Methods, Process Design and Synthesis, Dynamics & Control, Process Modeling, Simulation and Optimization. The latter CAPE strategic objective derived from the European Federation of Chemical Engineering (EFCE) promotion of scientific activities which autonomously and transversely work across the Working Parties' terms of references. These activities enhance the exchange of the know-how and knowledge acquired by different Working Parties in homologous fields. They also aim to discover complementary facets useful to the dissemination of tools and of novel procedures. As a consequence, the Working Parties 'Environmental Protection', 'Loss Prevention and Safety Promotion' and 'Multiphase Fluid Flow' were invited to assist in the organization of sessions in the area of: A Process Integrated Approach for: Environmental Benefit, Loss Prevention and Safety, Computational Fluid Dynamics. A total of 473 abstracts from all over the world were evaluated by the International Scientific Committee. Out of them 197 have been finally selected for the presentation and reported into this book. Their authors come from thirty different countries. The selection of the papers was carried out by twenty-eight international reviewers. These proceedings will be a major reference document to the scientific and industrial community and will contribute to the progress in Computer Aided Process Engineering.
Author: M. R. Riazi
Publisher: ASTM International
ISBN: 9780803133617
Category : Technology & Engineering
Languages : en
Pages : 425
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Book Description
The last three chapters of this book deal with application of methods presented in previous chapters to estimate various thermodynamic, physical, and transport properties of petroleum fractions. In this chapter, various methods for prediction of physical and thermodynamic properties of pure hydrocarbons and their mixtures, petroleum fractions, crude oils, natural gases, and reservoir fluids are presented. As it was discussed in Chapters 5 and 6, properties of gases may be estimated more accurately than properties of liquids. Theoretical methods of Chapters 5 and 6 for estimation of thermophysical properties generally can be applied to both liquids and gases; however, more accurate properties can be predicted through empirical correlations particularly developed for liquids. When these correlations are developed with some theoretical basis, they are more accurate and have wider range of applications. In this chapter some of these semitheoretical correlations are presented. Methods presented in Chapters 5 and 6 can be used to estimate properties such as density, enthalpy, heat capacity, heat of vaporization, and vapor pressure. Characterization methods of Chapters 2-4 are used to determine the input parameters needed for various predictive methods. One important part of this chapter is prediction of vapor pressure that is needed for vapor-liquid equilibrium calculations of Chapter 9.
