Part One: Synthesis and Characterization of Copper Complexes of Alkyl Thiolates and Detailed Ligand to Metal Charge Transfer (LMCT) Spectra of Cu(II) and Ni(II) - N2S2 Complexes PDF Download
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Author: Elizabeth K. John
Publisher:
ISBN:
Category : Complex compounds
Languages : en
Pages : 344
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Author: Elizabeth K. John
Publisher:
ISBN:
Category : Complex compounds
Languages : en
Pages : 344
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Author: Robert Paul Houser
Publisher:
ISBN:
Category :
Languages : en
Pages : 408
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Author: Maximilian Joost
Publisher: Springer
ISBN: 3319186906
Category : Science
Languages : en
Pages : 244
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Book Description
This thesis addresses the coordination chemistry and reactivity of copper and gold complexes with a focus on the elucidation of (i) the metal-mediated activation of σ-bonds and (ii) the migratory insertion reaction. Both processes are of considerable importance in organometallic chemistry, but remain elusive for Cu and Au complexes. In this work, the author contributes significant advances: The first σ-SiH complexes of copper are experimentally and computationally characterized, yielding valuable insights into σ-bond activation processes for copper. Evidence for a highly unusual migratory syn insertion of unsaturated organic molecules into the gold-silicon bond of silylgold (I) complexes is provided and the corresponding mechanism identified. The intermolecular oxidative addition of σ-SiSi, σ-CC and σ-CX (X=halogen) bonds with molecular gold (I) complexes is studied in detail, effectively demonstrating that this reaction, usually considered to be impossible for gold, is actually highly favored, provided an adequate ligand is employed. The use of small-bite angle bis (phosphine) gold (I) complexes allows for the first time the oxidative addition of σ-CC and σ-CX bonds for gold (I). These results shed light on an unexpected reactivity pattern of gold complexes and may point the way to 2-electron redox transformations mediated by this metal, opening up new perspectives in gold catalysis.
Author: Khin Htay Htay
Publisher:
ISBN:
Category : Copper compounds
Languages : en
Pages : 278
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Author: Björn Gustafsson
Publisher:
ISBN: 9789172915152
Category :
Languages : en
Pages :
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Author: Kenneth D. Karlin
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 518
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Author: K.D. Karlin
Publisher: Springer Science & Business Media
ISBN: 940116875X
Category : Science
Languages : en
Pages : 510
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Book Description
Bioinorganic Chemistry of Copper focuses on the vital role of copper ions in biology, especially as an essential metalloenzyme cofactor. The book is highly interdisciplinary in its approach--the outstanding list of contributors includes coordination chemists, biochemists, biophysicists, and molecular biologists. Chapters are grouped into major areas of research interest in inorganic copper chemistry, spectroscopy, oxygen chemistry, biochemistry, and molecular biology. The book also discusses basic research of great potential importance to pharmaceutical scientists. This book is based on the first Johns Hopkins University Copper Symposium, held in August 1992. Researchers in chemistry, biochemistry, molecular biology, and medicinal chemistry will find it to be an essential reference on its subject.
Author: Susan Marie Carrier
Publisher:
ISBN:
Category :
Languages : en
Pages : 336
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Author: Khadija Humaid Mohamed Al Yahmedi
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author: Scott Jackson Dantley
Publisher:
ISBN:
Category : Chemistry
Languages : en
Pages : 130
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