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Author: Norbert Auner
Publisher: Wiley-VCH
ISBN: 9783527306701
Category : Science
Languages : en
Pages : 0
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Book Description
Never Change a winning team. The fifth volume in this renowned series retains the established and successful concept: Leading experts from academia and industry present a comprehensive and detailed overview of the latest results in organosilicon chemistry. Synthesis and characterization of new organosilicon compounds Applications in polymer and materials science Summary of the latest research results The result is a unique collection of first-hand information, vital for every expert working in this field. From the contents: Reactions of Silicon Atoms- An Access to Unusual Molecules New Reactions of Stable Silylenes Synthesis and Chemistry of Some Bridged Silicocations Synthesis of a Highly Enantiomerically Enriched Silyllithium Compound Experimental Determination of the Inversion Barriers of Oligosily Anions SiO and SiOSiN Chains, Rings, and Cages Novel Cyclic and Polycyclic Chalcogenides of Silicon Organosilicon Compounds in Medicine and Cosmetics Organosilicon Chemistry and Nanoscience Sustainable Silicon Production The Role of Silanes in Filled and Crosslinked Polymers Catalytic Hydrosilylation of Fatty Compounds Novel Routes fro the Preparation of Nanoporous Silica Particles Aluminosiloxanes as Molecular Models for Aluminosilicates
Author: Norbert Auner
Publisher: Wiley-VCH
ISBN: 9783527306701
Category : Science
Languages : en
Pages : 0
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Book Description
Never Change a winning team. The fifth volume in this renowned series retains the established and successful concept: Leading experts from academia and industry present a comprehensive and detailed overview of the latest results in organosilicon chemistry. Synthesis and characterization of new organosilicon compounds Applications in polymer and materials science Summary of the latest research results The result is a unique collection of first-hand information, vital for every expert working in this field. From the contents: Reactions of Silicon Atoms- An Access to Unusual Molecules New Reactions of Stable Silylenes Synthesis and Chemistry of Some Bridged Silicocations Synthesis of a Highly Enantiomerically Enriched Silyllithium Compound Experimental Determination of the Inversion Barriers of Oligosily Anions SiO and SiOSiN Chains, Rings, and Cages Novel Cyclic and Polycyclic Chalcogenides of Silicon Organosilicon Compounds in Medicine and Cosmetics Organosilicon Chemistry and Nanoscience Sustainable Silicon Production The Role of Silanes in Filled and Crosslinked Polymers Catalytic Hydrosilylation of Fatty Compounds Novel Routes fro the Preparation of Nanoporous Silica Particles Aluminosiloxanes as Molecular Models for Aluminosilicates
Author: Stephan Pawlenko
Publisher: Walter de Gruyter
ISBN: 3110862387
Category : Science
Languages : en
Pages : 201
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Book Description
Author: Vladimir Ya Lee
Publisher: Academic Press
ISBN: 0128019913
Category : Science
Languages : en
Pages : 758
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Book Description
Organosilicon Compounds: Theory and Experiment (Synthesis), volume 1, comprises two parts. The first part, Theory, covers state-of-the-art computational treatments of unusual nonstandard organosilicon compounds that classical bonding theory fails to describe adequately. The second part, Experiment (Synthesis), describes recent synthetic advances in the preparation of a variety of organosilicon compounds with different coordination numbers of the central silicon: from tetracoordinate to low-coordinate to hypercoordinate derivatives. Organosilicon Compounds: From Theory to Synthesis to Applications provides a comprehensive overview of this important area of organic and organometallic chemistry, dealing with compounds containing carbon–silicon bonds. This field, which includes compounds that are widely encountered in commercial products such as in the fabrication of sealants, adhesives, and coatings, has seen many milestone discoveries reported during the last two decades. Beginning with the theoretical aspects of organosilicon compounds' structure and bonding, the book then explores their synthetic aspects, including main group element organosilicon compounds, transition metal complexes, silicon cages and clusters, low-coordinate organosilicon derivatives (cations, radicals, anions, multiple bonds to silicon, silaaromatics), and more. Next, readers will find valuable sections that explore physical and chemical properties of organosilicon compounds by means of X-ray crystallography, 29Si NMR spectroscopy, photoelectron spectroscopy, and other methods. Finally, the work delves into applications for industrial uses and in many related fields, such as polymers, material science, nanotechnology, bioorganics, and medicinal silicon chemistry. - Features valuable contributions from prominent experts that cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects of modern organosilicon chemistry - Covers important breakthroughs in the field, along with the historically significant achievements of the past - Includes applied information for a wide range of specialists, from junior and senior researchers (from both academia and industry) - Ideal reference for those working in organometallic, organosilicon, main group element, transition metal, and industrial silicon chemistry, as well as those from interdisciplinary fields, such as polymer, material science, and nanotechnology
Author: Ernest W. Colvin
Publisher: Butterworth-Heinemann
ISBN: 148314223X
Category : Science
Languages : en
Pages : 361
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Book Description
Silicon in Organic Synthesis provides an introduction to the organic chemistry of silicon. This book places particular emphasis on the concept of silicon as a "ferryman, mediating the transformation of one wholly organic molecule into another. The book begins by reviewing the discovery and development of organosilicon compounds. This is followed by separate chapters on the physical properties of organosilicon compounds; the preparation of a-metallated organosilanes, which play a key role in preparative organosilicon chemistry; migration/rearrangement reactions of silicon; the preparation and chemistry of vinylsilanes, allylsilanes, arylsilanes, and organosilyl metallic compounds. Subsequent chapters cover the synthesis of compounds such as alkene, alkynylsilanes, allenylsilanes, silylketenes, alkyl silyl ethers, acyloxysilanes, and silyl enol ethers. This book aims to serve as a timely introduction to organic chemistry for students and practitioners of synthetic organic chemistry, as well as provide a source of useful information and possibly of new ideas to those already experienced in the area.
Author: Norbert Auner
Publisher: John Wiley & Sons
ISBN: 3527620419
Category : Science
Languages : en
Pages : 371
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Book Description
Do you need to know what's new in organosilicon chemistry? This book provides in-depth coverage of the latest developments in this interdisciplinary and fast-evolving field: - selectivity and reactivity of organosilicon compounds - new synthetic applications - structure and bonding - applications in materials and polymer science Written by leading experts, this book is a well-referenced and critical overview of modern silicon chemistry. 'I recommend this book to the student and the practitioner in this new, very different, and very exciting field'. Eugene G. Rochow /Harvard University
Author: Grish Chandra
Publisher:
ISBN: 9783662148211
Category :
Languages : en
Pages : 348
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Book Description
Author: Prof. Dr. Shigeyoshi Inoue
Publisher: MDPI
ISBN: 3038976385
Category : Science
Languages : en
Pages : 228
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Book Description
The chemistry of silicon has always been a field of major concern due to its proximity to carbon on the periodic table. From the molecular chemist’s viewpoint, one of the most interesting differences between carbon and silicon is their divergent coordination behavior. In fact, silicon is prone to form hyper-coordinate organosilicon complexes, and, as conveyed by reports in the literature, highly sophisticated ligand systems are required to furnish low-coordinate organosilicon complexes. Tremendous progress in experimental, as well as computational, techniques has granted synthetic access to a broad range of coordination numbers for silicon, and the scientific endeavor, which was ongoing for decades, was rewarded with landmark discoveries in the field of organosilicon chemistry. Molecular congeners of silicon(0), as well as silicon oxides, were unveiled, and the prominent group 14 metalloid proved its applicability in homogenous catalysis as a supportive ligand or even as a center of catalytic activity. This book focuses on the most recent advances in the coordination chemistry of silicon with transition metals as well as main group elements, including the stabilization of low-valent silicon species through the coordination of electron donor ligands. Therefore, this book is associated with the development of novel synthetic methodologies, structural elucidations, bonding analysis, and also possible applications in catalysis or chemical transformations using related organosilicon compounds.
Author: Walter Noll
Publisher: Elsevier
ISBN: 0323141404
Category : Technology & Engineering
Languages : en
Pages : 716
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Book Description
Chemistry and Technology of Silicones retains the nature of a monograph despite its expanded scope, giving the reader in condensed form not only a wide-ranging but also a thorough review of this rapidly growing field. In contrast to some other monographs on organosilicon compounds that have appeared in the interim, the silicones occupy in this edition the central position, and the technological part of the work is entirely devoted to them. This book comprises 12 chapters, and begins with a general discussion of the chemistry and molecular structure of the silicones. The following chapters then discuss preparation of silanes with nonfunctional organic substituents; monomeric organosilicon compounds RnSiX4-n; and organosilanes with organofunctional groups. Other chapters cover preparation of polyorganosiloxanes; the polymeric organosiloxanes; other organosilicon polymers; production of technical silicone products from polyorganosiloxanes; properties of technical products; applications of technical silicone products in various branches of industry; esters of silicic acid; and analytical methods. This book will be of interest to practitioners in the fields of molecular chemistry.
Author: S. N. Borisov
Publisher: Springer
ISBN: 9781461586296
Category : Science
Languages : en
Pages : 0
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Book Description
There are numerous criteria for measuring the growth and development of branches of chemistry. This valuable book illustrates a particular aspect of the growth of organosilicon chemistry. The extent of this field has developed so greatly in recent years that it now is desirable to reclassify parts to bring together hitherto frag mented and relatively disparate sections. This has been accomplished by the presently available large units which have been deSignated as "organosilicon heterocompounds. " Simplified expressions of such classification are structural units of the general type C - Si - heteroelement and heteroelement-C - Si, in which there are attached to the organosilicon moiety elements such as oxygen, nitrogen, metals, etc. This arrangement per mits the correlation of extensive material, which will be invalu able to chemists in many areas, both in and out of organosi- con chemistry. Because of the wealth of information, the authors are currently engaged in the preparation of companion volumes arranged on this general principle. The scope is broad, and includes material which will prove highly interesting and useful to those in academic, industrial, and governmental circles. There is not only a wide coverage of the literature generally, but the listings of patent references and of general reviews and books are among the most complete so far presented.
Author: Michael A. Brook
Publisher: Wiley-Interscience
ISBN: 9780471196587
Category : Science
Languages : en
Pages : 704
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Book Description
A comprehensive, up-to-date reference to synthetic applications of organosilicon chemistry Organic, organometallic, and polymer chemistry as well as materials science all utilize silicon in various forms, yet there is little cross-fertilization of ideas and applications among the disciplines. This book presents a much-needed overview of silicon chemistry, allowing fundamental and applied scientists to take full advantage of progress made within and outside their primary fields of expertise. With an emphasis on the preparation and reactivity of silicon compounds in organic, organometallic, and polymer chemistry, the author examines a broad range of useful topics-from mechanisms to syntheses of and syntheses using different organofunctional silanes. Numerous schemes as well as up-to-date examples from academia and industry will help readers to solve current synthetic problems and explore ideas for future research. Clear, concise coverage includes: * The mechanistic basis for the development of new silicon-based reactions * Formation and cleavage of silane reagents and functional siliconheteroatom compounds * Silicones, silica, polysilanes, and other silicon-containing polymers * Properties of molecules containing silicon, including bioactivity * Methods for the preparation of Si-C compounds * Silicon in organic synthesis * An extensive functional group index for easy access to functional group transformations
