Author: Rainer Klages
Publisher: John Wiley & Sons
ISBN: 3527658726
Category : Science
Languages : en
Pages : 402
Book Description
This book offers a comprehensive picture of nonequilibrium phenomena in nanoscale systems. Written by internationally recognized experts in the field, this book strikes a balance between theory and experiment, and includes in-depth introductions to nonequilibrium fluctuation relations, nonlinear dynamics and transport, single molecule experiments, and molecular diffusion in nanopores. The authors explore the application of these concepts to nano- and biosystems by cross-linking key methods and ideas from nonequilibrium statistical physics, thermodynamics, stochastic theory, and dynamical systems. By providing an up-to-date survey of small systems physics, the text serves as both a valuable reference for experienced researchers and as an ideal starting point for graduate-level students entering this newly emerging research field.
Nonequilibrium Statistical Physics of Small Systems
Author: Rainer Klages
Publisher: John Wiley & Sons
ISBN: 3527658726
Category : Science
Languages : en
Pages : 402
Book Description
This book offers a comprehensive picture of nonequilibrium phenomena in nanoscale systems. Written by internationally recognized experts in the field, this book strikes a balance between theory and experiment, and includes in-depth introductions to nonequilibrium fluctuation relations, nonlinear dynamics and transport, single molecule experiments, and molecular diffusion in nanopores. The authors explore the application of these concepts to nano- and biosystems by cross-linking key methods and ideas from nonequilibrium statistical physics, thermodynamics, stochastic theory, and dynamical systems. By providing an up-to-date survey of small systems physics, the text serves as both a valuable reference for experienced researchers and as an ideal starting point for graduate-level students entering this newly emerging research field.
Publisher: John Wiley & Sons
ISBN: 3527658726
Category : Science
Languages : en
Pages : 402
Book Description
This book offers a comprehensive picture of nonequilibrium phenomena in nanoscale systems. Written by internationally recognized experts in the field, this book strikes a balance between theory and experiment, and includes in-depth introductions to nonequilibrium fluctuation relations, nonlinear dynamics and transport, single molecule experiments, and molecular diffusion in nanopores. The authors explore the application of these concepts to nano- and biosystems by cross-linking key methods and ideas from nonequilibrium statistical physics, thermodynamics, stochastic theory, and dynamical systems. By providing an up-to-date survey of small systems physics, the text serves as both a valuable reference for experienced researchers and as an ideal starting point for graduate-level students entering this newly emerging research field.
Thermodynamics and Statistical Mechanics of Small Systems
Author: Andrea Puglisi
Publisher: MDPI
ISBN: 3038970573
Category : Mathematics
Languages : en
Pages : 335
Book Description
This book is a printed edition of the Special Issue "Thermodynamics and Statistical Mechanics of Small Systems" that was published in Entropy
Publisher: MDPI
ISBN: 3038970573
Category : Mathematics
Languages : en
Pages : 335
Book Description
This book is a printed edition of the Special Issue "Thermodynamics and Statistical Mechanics of Small Systems" that was published in Entropy
Thermodynamics of Information Processing in Small Systems
Author: Takahiro Sagawa
Publisher: Springer Science & Business Media
ISBN: 4431541683
Category : Science
Languages : en
Pages : 126
Book Description
This thesis presents a general theory of nonequilibrium thermodynamics for information processing. Ever since Maxwell's demon was proposed in the nineteenth century, the relationship between thermodynamics and information has attracted much attention because it concerns the foundation of the second law of thermodynamics. From the modern point of view, Maxwell's demon is formulated as an information processing device that performs measurement and feedback at the level of thermal fluctuations. By unifying information theory, measurement theory, and the recently developed theory of nonequilibrium statistical mechanics, the author has constructed a theory of "information thermodynamics," in which information contents and thermodynamic variables are treated on an equal footing. In particular, the maximum work that can be extracted by the demon and the minimum work that is needed for measurement and information erasure by the demon has been determined. Additionally, generalizations of nonequilibrium relations such as a Jarzynski equality for classical stochastic systems in the presence of feedback control have been derived. One of the generalized equalities has recently been verified experimentally by using sub-micron colloidal particles. The results obtained serve as fundamental principles for information processing in small thermodynamic systems, and are applicable to nanomachines and nanodevices.
Publisher: Springer Science & Business Media
ISBN: 4431541683
Category : Science
Languages : en
Pages : 126
Book Description
This thesis presents a general theory of nonequilibrium thermodynamics for information processing. Ever since Maxwell's demon was proposed in the nineteenth century, the relationship between thermodynamics and information has attracted much attention because it concerns the foundation of the second law of thermodynamics. From the modern point of view, Maxwell's demon is formulated as an information processing device that performs measurement and feedback at the level of thermal fluctuations. By unifying information theory, measurement theory, and the recently developed theory of nonequilibrium statistical mechanics, the author has constructed a theory of "information thermodynamics," in which information contents and thermodynamic variables are treated on an equal footing. In particular, the maximum work that can be extracted by the demon and the minimum work that is needed for measurement and information erasure by the demon has been determined. Additionally, generalizations of nonequilibrium relations such as a Jarzynski equality for classical stochastic systems in the presence of feedback control have been derived. One of the generalized equalities has recently been verified experimentally by using sub-micron colloidal particles. The results obtained serve as fundamental principles for information processing in small thermodynamic systems, and are applicable to nanomachines and nanodevices.
Statistical Mechanics of Nonequilibrium Liquids
Author: Denis J. Evans
Publisher: ANU E Press
ISBN: 1921313234
Category : Science
Languages : en
Pages : 318
Book Description
"There is a symbiotic relationship between theoretical nonequilibrium statistical mechanics on the one hand and the theory and practice of computer simulation on the other. Sometimes, the initiative for progress has been with the pragmatic requirements of computer simulation and at other times, the initiative has been with the fundamental theory of nonequilibrium processes. This book summarises progress in this field up to 1990"--Publisher's description.
Publisher: ANU E Press
ISBN: 1921313234
Category : Science
Languages : en
Pages : 318
Book Description
"There is a symbiotic relationship between theoretical nonequilibrium statistical mechanics on the one hand and the theory and practice of computer simulation on the other. Sometimes, the initiative for progress has been with the pragmatic requirements of computer simulation and at other times, the initiative has been with the fundamental theory of nonequilibrium processes. This book summarises progress in this field up to 1990"--Publisher's description.
Statistical Physics of Non Equilibrium Quantum Phenomena
Author: Yves Pomeau
Publisher: Springer Nature
ISBN: 3030343944
Category : Science
Languages : en
Pages : 232
Book Description
This book provides an introduction to topics in non-equilibrium quantum statistical physics for both mathematicians and theoretical physicists. The first part introduces a kinetic equation, of Kolmogorov type, which is needed to describe an isolated atom (actually, in experiments, an ion) under the effect of a classical pumping electromagnetic field which keeps the atom in its excited state(s) together with the random emission of fluorescence photons which put it back into its ground state. The quantum kinetic theory developed in the second part is an extension of Boltzmann's classical (non-quantum) kinetic theory of a dilute gas of quantum bosons. This is the source of many interesting fundamental questions, particularly because, if the temperature is low enough, such a gas is known to have at equilibrium a transition, the Bose–Einstein transition, where a finite portion of the particles stay in the quantum ground state. An important question considered is how a Bose gas condensate develops in time if its energy is initially low enough.
Publisher: Springer Nature
ISBN: 3030343944
Category : Science
Languages : en
Pages : 232
Book Description
This book provides an introduction to topics in non-equilibrium quantum statistical physics for both mathematicians and theoretical physicists. The first part introduces a kinetic equation, of Kolmogorov type, which is needed to describe an isolated atom (actually, in experiments, an ion) under the effect of a classical pumping electromagnetic field which keeps the atom in its excited state(s) together with the random emission of fluorescence photons which put it back into its ground state. The quantum kinetic theory developed in the second part is an extension of Boltzmann's classical (non-quantum) kinetic theory of a dilute gas of quantum bosons. This is the source of many interesting fundamental questions, particularly because, if the temperature is low enough, such a gas is known to have at equilibrium a transition, the Bose–Einstein transition, where a finite portion of the particles stay in the quantum ground state. An important question considered is how a Bose gas condensate develops in time if its energy is initially low enough.
Nonequilibrium Statistical Mechanics of Heterogeneous Fluid Systems
Author: Andrei G. Bashkirov
Publisher: CRC Press
ISBN: 9780849328602
Category : Science
Languages : en
Pages : 180
Book Description
There is a wide variety of heterogeneous fluid systems that possess interphase surfaces. This monograph is devoted to pioneering studies in nonequilibrium statistical mechanics of such systems. Starting from the Liouville equation, the equations of surface hydrodynamics are derived with allowance for discontinuities of thermodynamic parameters of interphase boundaries. Brownian motion of a large solid particle in a fluid and nucleation are treated as results of fluctuations of flows across particle surfaces. With the use of the Gibbs method, a shock wave in a gas is considered as a sort of an interphase surface, and the surface tension of a shock front is introduced for the first time.
Publisher: CRC Press
ISBN: 9780849328602
Category : Science
Languages : en
Pages : 180
Book Description
There is a wide variety of heterogeneous fluid systems that possess interphase surfaces. This monograph is devoted to pioneering studies in nonequilibrium statistical mechanics of such systems. Starting from the Liouville equation, the equations of surface hydrodynamics are derived with allowance for discontinuities of thermodynamic parameters of interphase boundaries. Brownian motion of a large solid particle in a fluid and nucleation are treated as results of fluctuations of flows across particle surfaces. With the use of the Gibbs method, a shock wave in a gas is considered as a sort of an interphase surface, and the surface tension of a shock front is introduced for the first time.
Non-Equilibrium Thermodynamics
Author: S. R. De Groot
Publisher: Courier Corporation
ISBN: 0486153509
Category : Science
Languages : en
Pages : 532
Book Description
Classic monograph treats irreversible processes and phenomena of thermodynamics: non-equilibrium thermodynamics. Covers statistical foundations and applications with chapters on fluctuation theory, theory of stochastic processes, kinetic theory of gases, more.
Publisher: Courier Corporation
ISBN: 0486153509
Category : Science
Languages : en
Pages : 532
Book Description
Classic monograph treats irreversible processes and phenomena of thermodynamics: non-equilibrium thermodynamics. Covers statistical foundations and applications with chapters on fluctuation theory, theory of stochastic processes, kinetic theory of gases, more.
Topics In Statistical Mechanics (Second Edition)
Author: Brian Cowan
Publisher: World Scientific
ISBN: 1786349809
Category : Science
Languages : en
Pages : 451
Book Description
Building on the material learned by students in their first few years of study, Topics in Statistical Mechanics (Second Edition) presents an advanced level course on statistical and thermal physics. It begins with a review of the formal structure of statistical mechanics and thermodynamics considered from a unified viewpoint. There is a brief revision of non-interacting systems, including quantum gases and a discussion of negative temperatures. Following this, emphasis is on interacting systems. First, weakly interacting systems are considered, where the interest is in seeing how small interactions cause small deviations from the non-interacting case. Second, systems are examined where interactions lead to drastic changes, namely phase transitions. A number of specific examples is given, and these are unified within the Landau theory of phase transitions. The final chapter of the book looks at non-equilibrium systems, in particular the way they evolve towards equilibrium. This is framed within the context of linear response theory. Here fluctuations play a vital role, as is formalised in the fluctuation-dissipation theorem.The second edition has been revised particularly to help students use this book for self-study. In addition, the section on non-ideal gases has been expanded, with a treatment of the hard-sphere gas, and an accessible discussion of interacting quantum gases. In many cases there are details of Mathematica calculations, including Mathematica Notebooks, and expression of some results in terms of Special Functions.
Publisher: World Scientific
ISBN: 1786349809
Category : Science
Languages : en
Pages : 451
Book Description
Building on the material learned by students in their first few years of study, Topics in Statistical Mechanics (Second Edition) presents an advanced level course on statistical and thermal physics. It begins with a review of the formal structure of statistical mechanics and thermodynamics considered from a unified viewpoint. There is a brief revision of non-interacting systems, including quantum gases and a discussion of negative temperatures. Following this, emphasis is on interacting systems. First, weakly interacting systems are considered, where the interest is in seeing how small interactions cause small deviations from the non-interacting case. Second, systems are examined where interactions lead to drastic changes, namely phase transitions. A number of specific examples is given, and these are unified within the Landau theory of phase transitions. The final chapter of the book looks at non-equilibrium systems, in particular the way they evolve towards equilibrium. This is framed within the context of linear response theory. Here fluctuations play a vital role, as is formalised in the fluctuation-dissipation theorem.The second edition has been revised particularly to help students use this book for self-study. In addition, the section on non-ideal gases has been expanded, with a treatment of the hard-sphere gas, and an accessible discussion of interacting quantum gases. In many cases there are details of Mathematica calculations, including Mathematica Notebooks, and expression of some results in terms of Special Functions.
Equilibrium and Non-equilibrium Statistical Mechanics
Author: Carolyn M. Van Vliet
Publisher: World Scientific
ISBN: 9812704779
Category : Science
Languages : en
Pages : 987
Book Description
This book encompasses our current understanding of the ensemble approach to many-body physics, phase transitions and other thermal phenomena, as well as the quantum foundations of linear response theory, kinetic equations and stochastic processes. It is destined to be a standard text for graduate students, but it will also serve the specialist-researcher in this fascinating field; some more elementary topics have been included in order to make the book self-contained.The historical methods of J Willard Gibbs and Ludwig Boltzmann, applied to the quantum description rather than phase space, are featured. The tools for computations in the microcanonical, canonical and grand-canonical ensembles are carefully developed and then applied to a variety of classical and standard quantum situations. After the language of second quantization has been introduced, strongly interacting systems, such as quantum liquids, superfluids and superconductivity, are treated in detail. For the connoisseur, there is a section on diagrammatic methods and applications.In the second part dealing with non-equilibrium processes, the emphasis is on the quantum foundations of Markovian behaviour and irreversibility via the Pauli-Van Hove master equation. Justifiable linear response expressions and the quantum-Boltzmann approach are discussed and applied to various condensed matter problems. From this basis the Onsager-Casimir relations are derived, together with the mesoscopic master equation, the Langevin equation and the Fokker-Planck truncation procedure. Brownian motion and modern stochastic problems such as fluctuations in optical signals and radiation fields briefly make the round.
Publisher: World Scientific
ISBN: 9812704779
Category : Science
Languages : en
Pages : 987
Book Description
This book encompasses our current understanding of the ensemble approach to many-body physics, phase transitions and other thermal phenomena, as well as the quantum foundations of linear response theory, kinetic equations and stochastic processes. It is destined to be a standard text for graduate students, but it will also serve the specialist-researcher in this fascinating field; some more elementary topics have been included in order to make the book self-contained.The historical methods of J Willard Gibbs and Ludwig Boltzmann, applied to the quantum description rather than phase space, are featured. The tools for computations in the microcanonical, canonical and grand-canonical ensembles are carefully developed and then applied to a variety of classical and standard quantum situations. After the language of second quantization has been introduced, strongly interacting systems, such as quantum liquids, superfluids and superconductivity, are treated in detail. For the connoisseur, there is a section on diagrammatic methods and applications.In the second part dealing with non-equilibrium processes, the emphasis is on the quantum foundations of Markovian behaviour and irreversibility via the Pauli-Van Hove master equation. Justifiable linear response expressions and the quantum-Boltzmann approach are discussed and applied to various condensed matter problems. From this basis the Onsager-Casimir relations are derived, together with the mesoscopic master equation, the Langevin equation and the Fokker-Planck truncation procedure. Brownian motion and modern stochastic problems such as fluctuations in optical signals and radiation fields briefly make the round.
Microcanonical Thermodynamics: Phase Transitions In "Small" Systems
Author: Dieter H E Gross
Publisher: World Scientific
ISBN: 9814493643
Category : Science
Languages : en
Pages : 287
Book Description
Boltzmann's formula S = In[W(E)] defines the microcanonical ensemble. The usual textbooks on statistical mechanics start with the microensemble but rather quickly switch to the canonical ensemble introduced by Gibbs. This has the main advantage of easier analytical calculations, but there is a price to pay — for example, phase transitions can only be defined in the thermodynamic limit of infinite system size. The question how phase transitions show up from systems with, say, 100 particles with an increasing number towards the bulk can only be answered when one finds a way to define and classify phase transitions in small systems. This is all possible within Boltzmann's original definition of the microcanonical ensemble.Starting from Boltzmann's formula, the book formulates the microcanonical thermodynamics entirely within the frame of mechanics. This way the thermodynamic limit is avoided and the formalism applies to small as well to other nonextensive systems like gravitational ones. Phase transitions of first order, continuous transitions, critical lines and multicritical points can be unambiguously defined by the curvature of the entropy S(E,N). Special attention is given to the fragmentation of nuclei and atomic clusters as a peculiar phase transition of small systems controlled, among others, by angular momentum.The dependence of the liquid-gas transition of small atomic clusters under prescribed pressure is treated. Thus the analogue to the bulk transition can be studied. The book also describes the microcanonical statistics of the collapse of a self-gravitating system under large angular momentum.
Publisher: World Scientific
ISBN: 9814493643
Category : Science
Languages : en
Pages : 287
Book Description
Boltzmann's formula S = In[W(E)] defines the microcanonical ensemble. The usual textbooks on statistical mechanics start with the microensemble but rather quickly switch to the canonical ensemble introduced by Gibbs. This has the main advantage of easier analytical calculations, but there is a price to pay — for example, phase transitions can only be defined in the thermodynamic limit of infinite system size. The question how phase transitions show up from systems with, say, 100 particles with an increasing number towards the bulk can only be answered when one finds a way to define and classify phase transitions in small systems. This is all possible within Boltzmann's original definition of the microcanonical ensemble.Starting from Boltzmann's formula, the book formulates the microcanonical thermodynamics entirely within the frame of mechanics. This way the thermodynamic limit is avoided and the formalism applies to small as well to other nonextensive systems like gravitational ones. Phase transitions of first order, continuous transitions, critical lines and multicritical points can be unambiguously defined by the curvature of the entropy S(E,N). Special attention is given to the fragmentation of nuclei and atomic clusters as a peculiar phase transition of small systems controlled, among others, by angular momentum.The dependence of the liquid-gas transition of small atomic clusters under prescribed pressure is treated. Thus the analogue to the bulk transition can be studied. The book also describes the microcanonical statistics of the collapse of a self-gravitating system under large angular momentum.