Coordination Phenomena in Non-Aqueous Solvents: I. A Coordination Model for Non-Aqueous Solution Behavior. Ii. Sulfoxide Coordination Compounds of Transition-Metal Ions PDF Download
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Languages : en
Pages :
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Author:
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Languages : en
Pages :
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Author: Devon Walter Meek
Publisher:
ISBN:
Category :
Languages : en
Pages : 282
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Author: Victor Gutmann
Publisher: Springer Science & Business Media
ISBN: 3709181941
Category : Science
Languages : en
Pages : 181
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Book Description
Considerable attention has been focussed on non-aqueous chemistry in the last decade and this situation has arisen no doubt from a realization of the vast application of this branch of chemistry. Within this field much energetic work has been channelled into the determination of the coordination chemistry of tran sition metals in these solvent 8ystems. Elaborate experimental techniques have been developed to discover, in particular, the magnetic and spectral properties of complex compounds, and the theoretical background of such systems has been expanded to corroborate, as far as possible, the experimental results. This text has, however, a different bias from many books currently available on this branch of chemistry, and is designed to be a survey of known facts on many of the non-aqueous solvents currently in use mainly in the field of halogen chemistry, together with a discussion of these facts in the light of accepted principles. As such, it is hoped to close a gap in the literature of which many workers and advanced students in this field will be aware. The treatment is meant to be selective rather than completely comprehensive and must unevitably reflect some of the special interests of the author.
Author: John Timothy Donoghue
Publisher:
ISBN:
Category : Coordination compounds
Languages : en
Pages : 102
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Author: Viktor Gutmann
Publisher:
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Category :
Languages : en
Pages : 62
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Systematic investigations have been performed on the behavior of certain transition metal ions in solvents of different donor properties towards azide ions, chloride ions and bromide ions. Spectrophotometric, potentiometric and conductometric techniques have been used. The ionizing properties of a solvent increase with increasing donor number. The formation of complex compounds becomes more difficult in a solvent of high donor number. In a solvent of low donor number both solubilities and ionization are smaller, but coordination reactions with competitive ligands are favored. Autocomplex formation is expected when the donor properties of solvent molecules and competitive ligands are not vastly different. The influence of steric factors becomes important with small metal ions of high coordination number and with large and bulky solvent molecules. The dielectric constant of the solvent is responsible mainly for the electro lytic dissociation of ions and thus important for electrochemical considerations.
Author: Victor Gutmann
Publisher: Springer Science & Business Media
ISBN: 3709136504
Category : Science
Languages : en
Pages : 474
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Organized by Verein Österreichischer Chemiker
Author: U.S. Atomic Energy Commission. Division of Technical Information
Publisher:
ISBN:
Category : Nuclear energy
Languages : en
Pages : 1118
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Author: U.S. Atomic Energy Commission
Publisher:
ISBN:
Category : Nuclear energy
Languages : en
Pages : 144
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Book Description
Author: J. A. McCleverty
Publisher: Newnes
ISBN: 0080913164
Category : Science
Languages : en
Pages : 11845
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Book Description
Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.
Author: V. Gutmann
Publisher: Elsevier
ISBN: 1483278824
Category : Science
Languages : en
Pages : 127
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Book Description
Non-Aqueous Solutions is a collection of papers presented at the Fourth International Conference on the same subject. One paper presents the application of far- and mid-infra-red, Raman, alkali metal n.m.r. and 35C1 n.m.r. techniques to the study of electrolyte solutions in non-aqueous solvents. The paper notes that spectroscopic techniques can be very useful in the elucidation of the structure of electrolyte solutions. Both the vibrational spectroscopy and particularly the alkali metal n.m.r. are very sensitive probes of the immediate chemical environment of ions in solutions. Another paper points out that the energy change associated with the solvation of ions can be represented as the sum of two energy terms; firstly, from the dielectric polarization of the solvent molecules in the continuous dielectric medium; and secondly, due to specific ion-solvent interactions in the inner solvation shells of the ions. The energy contribution of the latter is minimal but can show comparatively large differences in various types of solvents. Another paper describes the chemistry of solutions in highly associated strong protonic acid solvents, including sulphuric acid, oleums, fluorosulfuric acid, and hydrogen fluoride. Organic chemists, analytical chemists, investigators, and scientists whose works involve physical or inorganic chemistry will find the collection truly beneficial.
