New Sol-gel Synthetic Route to Transition and Main-group Metal Oxide Aerogels Using Inorganic Salt Precursors PDF Download
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Languages : en
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Book Description
We have developed a new sol-gel route to synthesize several transition and main-group metal oxide aerogels. The approach is straightforward, inexpensive, versatile, and it produces monolithic microporous materials with high surface areas. Specifically, we report the use of epoxides as gelation agents for the sol-gel synthesis of chromia aerogels and xerogels from simple Cr(III) inorganic salts. The dependence of both gel formation and its rate was studied by varying the solvent used, the Cr(III) precursor salt, the epoxide/Cr(III) ratio, as well as the type of epoxide employed. All of these variables were shown to affect the rate of gel formation and provide a convenient control of this parameter. Dried chromia aerogels were characterized by high-resolution transmission electron microscopy (HRTEM) and nitrogen adsorption/desorption analyses, results of which will be presented. Our studies have shown that rigid monolithic gels can be prepared from many different metal ions salts, provided the formal oxidation state of the metal ion is greater than or equal to +3. Conversely, when di-valent transition metal salts are used precipitated solids are the products.
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
We have developed a new sol-gel route to synthesize several transition and main-group metal oxide aerogels. The approach is straightforward, inexpensive, versatile, and it produces monolithic microporous materials with high surface areas. Specifically, we report the use of epoxides as gelation agents for the sol-gel synthesis of chromia aerogels and xerogels from simple Cr(III) inorganic salts. The dependence of both gel formation and its rate was studied by varying the solvent used, the Cr(III) precursor salt, the epoxide/Cr(III) ratio, as well as the type of epoxide employed. All of these variables were shown to affect the rate of gel formation and provide a convenient control of this parameter. Dried chromia aerogels were characterized by high-resolution transmission electron microscopy (HRTEM) and nitrogen adsorption/desorption analyses, results of which will be presented. Our studies have shown that rigid monolithic gels can be prepared from many different metal ions salts, provided the formal oxidation state of the metal ion is greater than or equal to +3. Conversely, when di-valent transition metal salts are used precipitated solids are the products.
Author: David Levy
Publisher: John Wiley & Sons
ISBN: 352767084X
Category : Technology & Engineering
Languages : en
Pages : 1616
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Book Description
This comprehensive three-volume handbook brings together a review of the current state together with the latest developments in sol-gel technology to put forward new ideas. The first volume, dedicated to synthesis and shaping, gives an in-depth overview of the wet-chemical processes that constitute the core of the sol-gel method and presents the various pathways for the successful synthesis of inorganic and hybrid organic-inorganic materials, bio- and bio-inspired materials, powders, particles and fibers as well as sol-gel derived thin films, coatings and surfaces. The second volume deals with the mechanical, optical, electrical and magnetic properties of sol-gel derived materials and the methods for their characterization such as diffraction methods and nuclear magnetic resonance, infrared and Raman spectroscopies. The third volume concentrates on the various applications in the fields of membrane science, catalysis, energy research, biomaterials science, biomedicine, photonics and electronics.
Author: Michel Andre Aegerter
Publisher: Springer Science & Business Media
ISBN: 1441975896
Category : Technology & Engineering
Languages : en
Pages : 929
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Book Description
Aerogels are the lightest solids known. Up to 1000 times lighter than glass and with a density as low as only four times that of air, they show very high thermal, electrical and acoustic insulation values and hold many entries in Guinness World Records. Originally based on silica, R&D efforts have extended this class of materials to non-silicate inorganic oxides, natural and synthetic organic polymers, carbon, metal and ceramic materials, etc. Composite systems involving polymer-crosslinked aerogels and interpenetrating hybrid networks have been developed and exhibit remarkable mechanical strength and flexibility. Even more exotic aerogels based on clays, chalcogenides, phosphides, quantum dots, and biopolymers such as chitosan are opening new applications for the construction, transportation, energy, defense and healthcare industries. Applications in electronics, chemistry, mechanics, engineering, energy production and storage, sensors, medicine, nanotechnology, military and aerospace, oil and gas recovery, thermal insulation and household uses are being developed with an estimated annual market growth rate of around 70% until 2015. The Aerogels Handbook summarizes state-of-the-art developments and processing of inorganic, organic, and composite aerogels, including the most important methods of synthesis, characterization as well as their typical applications and their possible market impact. Readers will find an exhaustive overview of all aerogel materials known today, their fabrication, upscaling aspects, physical and chemical properties, and most recent advances towards applications and commercial products, some of which are commercially available today. Key Features: •Edited and written by recognized worldwide leaders in the field •Appeals to a broad audience of materials scientists, chemists, and engineers in academic research and industrial R&D •Covers inorganic, organic, and composite aerogels •Describes military, aerospace, building industry, household, environmental, energy, and biomedical applications among others
Author: Michel A. Aegerter
Publisher: Springer Nature
ISBN: 3030273229
Category : Technology & Engineering
Languages : en
Pages : 1778
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Book Description
This indispensable handbook provides comprehensive coverage of the current state-of-the-art in inorganic, organic, and composite aerogels – from synthesis and characterization to cutting-edge applications and their potential market impact. Built upon Springer’s successful Aerogels Handbook published in 2011, this handbook features extensive revisions and timely updates, reflecting the changes in this fast-growing field. Aerogels are the lightest solids known to man. Up to 1000 times lighter than glass and with a density only four times that of air, they possess extraordinarily high thermal, electrical, and acoustic insulation properties, and boast numerous entries in Guinness World Records. Originally based on silica, R&D efforts have extended this class of materials to incorporate non-silicate inorganic oxides, natural and synthetic organic polymers, carbon, metal, and ceramic materials. Composite systems involving polymer-crosslinked aerogels and interpenetrating hybrid networks have been developed and exhibit remarkable mechanical strength and flexibility. Even more exotic aerogels based on clays, chalcogenides, phosphides, quantum dots, and biopolymers such as chitosan are opening new applications for the construction, transportation, energy, defense and healthcare industries. Applications in electronics, chemistry, mechanics, engineering, energy production and storage, sensors, medicine, nanotechnology, military and aerospace, oil and gas recovery, thermal insulation, and household uses are being developed. Readers of this fully updated and expanded edition will find an exhaustive source for all aerogel materials known today, their fabrication, upscaling aspects, physical and chemical properties, and the most recent advances towards applications and commercial use. This key reference is essential reading for a combined audience of graduate students, academic researchers, and industry professionals.
Author: Lisa Klein
Publisher: Springer Nature
ISBN: 3319321013
Category : Technology & Engineering
Languages : en
Pages : 3755
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Book Description
This completely updated and expanded second edition stands as a comprehensive knowledgebase on both the fundamentals and applications of this important materials processing method. The diverse, international team of contributing authors of this reference clarify in extensive detail properties and applications of sol-gel science and technology as it pertains to the production of substances, active and non-active, including optical, electronic, chemical, sensor, bio- and structural materials. Essential to a wide range of manufacturing industries, the compilation divides into the three complementary sections: Sol-Gel Processing, devoted to general aspects of processing and recently developed materials such as organic-inorganic hybrids, photonic crystals, ferroelectric coatings, and photocatalysts; Characterization of Sol-Gel Materials and Products, presenting contributions that highlight the notion that useful materials are only produced when characterization is tied to processing, such as determination of structure by NMR, in-situ characterization of the sol-gel reaction process, determination of microstructure of oxide gels, characterization of porous structure of gels by the surface measurements, and characterization of organic-inorganic hybrid; and Applications of Sol-Gel Technology, covering applications such as the sol-gel method used in processing of bulk silica glasses, bulk porous gels prepared by sol-gel method, application of sol-gel method to fabrication of glass and ceramic fibers, reflective and antireflective coating films, application of sol-gel method to formation of photocatalytic coating films, and application of sol-gel method to bioactive coating films. The comprehensive scope and integrated treatment of topics make this reference volume ideal for R&D scientists and engineers across a wide range of disciplines and professional interests.
Author: David Levy
Publisher: John Wiley & Sons
ISBN: 3527334866
Category : Technology & Engineering
Languages : en
Pages : 1604
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Book Description
This comprehensive three-volume handbook brings together a review of the current state together with the latest developments in sol-gel technology to put forward new ideas. The first volume, dedicated to synthesis and shaping, gives an in-depth overview of the wet-chemical processes that constitute the core of the sol-gel method and presents the various pathways for the successful synthesis of inorganic and hybrid organic-inorganic materials, bio- and bio-inspired materials, powders, particles and fibers as well as sol-gel derived thin films, coatings and surfaces. The second volume deals with the mechanical, optical, electrical and magnetic properties of sol-gel derived materials and the methods for their characterization such as diffraction methods and nuclear magnetic resonance, infrared and Raman spectroscopies. The third volume concentrates on the various applications in the fields of membrane science, catalysis, energy research, biomaterials science, biomedicine, photonics and electronics.
Author: Meldin Mathew
Publisher: John Wiley & Sons
ISBN: 1119717655
Category : Technology & Engineering
Languages : en
Pages : 548
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Book Description
Explore the energy storage applications of a wide variety of aerogels made from different materials In Aerogels for Energy Saving and Storage, an expert team of researchers delivers a one-stop resource covering the state-of-the-art in aerogels for energy applications. The book covers their morphology, properties, and processability and serves as a valuable resource for researchers and professionals working in materials science and environmentally friendly energy and power technology. The authors offer a comprehensive review of highly efficient energy applications of aerogels that bridges the gap between engineering, science, and chemistry and advances the field of materials development. They provide a Life Cycle Assessment of aerogels in energy systems, as well as discussions of their impact on the environment. Aerogel synthesis, characterization, fabrication, morphology, properties, energy-related applications, and simulations are all explored, and likely future research directions are provided. Readers will also find: A thorough introduction to aerogels in energy, including state-of-the-art advancements and challenges newly encountered Comprehensive explorations of chitin-based and cellulose-derived aerogels, as well as lignin-, clay-, and carbon nanotube-based aerogels Practical discussions of organic, natural, and inorganic aerogels, with further analyses of the lifecycle of aerogels In-depth examinations of the theory, modeling, and simulation of aerogels Perfect for chemical and environmental engineers, Aerogels for Energy Saving and Storage will also earn a place in the libraries of chemistry and materials science researchers in academia and industry.
Author: Sneha Bhagyaraj
Publisher: Woodhead Publishing
ISBN: 0081019769
Category : Technology & Engineering
Languages : en
Pages : 314
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Book Description
Synthesis of Inorganic Nanomaterials: Advances and Key Technologies discusses the latest advancements in the synthesis of various types of nanomaterials. The book's main objective is to provide a comprehensive review regarding the latest advances in synthesis protocols that includes up-to-date data records on the synthesis of all kinds of inorganic nanostructures using various physical and chemical methods. The synthesis of all important nanomaterials, such as carbon nanostructures, Core-shell Quantum dots, Metal and metal oxide nanostructures, Nanoferrites, polymer nanostructures, nanofibers, and smart nanomaterials are discussed, making this a one-stop reference resource on research accomplishments in this area. Leading researchers from industry, academia, government and private research institutions across the globe have contributed to the book. Academics, researchers, scientists, engineers and students working in the field of polymer nanocomposites will benefit from its solutions for material problems. - Provides an up-to-date data record on the synthesis of all kinds of organic and inorganic nanostructures using various physical and chemical methods - Presents the latest advances in synthesis protocols - Includes the latest techniques used in the physical and chemical characterization of nanomaterials - Covers the characterization of all the important materials groups, such as carbon nanostructures, core-shell quantum dots, metal and metal oxide nanostructures, Nano ferrites, polymer nanostructures and nanofibers
Author: Inamuddin
Publisher: Materials Research Forum LLC
ISBN: 164490098X
Category : Technology & Engineering
Languages : en
Pages : 282
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Book Description
This book focuses on aerogels and their applications in such areas as energy storage, thermal storage, catalysis, water splitting and environmental remediation. The materials covered include nanocellulose-, porous-, silica-, hybrid silica-, carbon-, graphene- and magnetic aerogels. Ways of modulating the pore structure of aerogels are presented, as well as surface modifications and the application of coatings. Future perspectives focus on functional foods, thickeners, stabilizers, and scaffolding in tissue repair. Keywords: Aerogels, Nanocellulose Aerogels, Non-Silicate Aerogels, Organic Aerogels, Composite Hybrid Aerogels, Carbon-based and Graphene-based Aerogels, Biogels, Hybrid Silica-based Aerogels, Energy Storage, Thermal Storage, Catalysis, Water Splitting, Environmental Remediation, Absorbents, Gas Filters, Packaging Materials, Electrical Devices, Thermal Insulations, Fire Retardants, Pharmaceutical and Biomedical Applications, Functional Foods, Thickeners, Stabilizers, Scaffolding in Tissue Repair.
Author: Paulo Mendonça
Publisher: Springer Nature
ISBN: 3031434781
Category : Science
Languages : en
Pages : 190
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Book Description
This book showcases the latest trends and innovations in the field of Green Building, covering topics from research and design to innovative practices and challenges. It is a compilation of communication papers presented at the 2023 International Conference on Green Building (ICoGB 2023), a leading annual event that focuses on sharing and discussing developments in this field. Green Building principles constitute key aspects to achieve the sustainable development goals. This conference is dedicated to providing a platform for researchers, scientists, engineers, and scholars to exchange and share their experiences, new ideas, and research and to discuss the challenges encountered as well as the solutions adopted. ICoGB 2023 was organized in Malmo, Sweden, during May 19–21, 2023. The target audience are all professionals in the building design and construction fields, such as architects, engineers, scholars, researchers, builders, promoters, among others.
