Nanostructure Transparent Conducting Oxide Film PDF Download
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Author: Shimaa Ahmed Hassan
Publisher: LAP Lambert Academic Publishing
ISBN: 9783844389111
Category :
Languages : en
Pages : 132
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Book Description
The book represents a thorough study of Tin oxide doped Fluorine SnO2: F as an alternative to the well known member of transparent conductive oxide TCO family, Indium Tin Oxide (ITO) as it has some restrictions. The TCO family has a unique property of high transmission to visible light, high reflection to infrared with wavelength greater than 2 mico m. and conductive to electricity like a metal. Based on that, it has wide application in optoelectronic solar energy generation and saving devices.
Author: Shimaa Ahmed Hassan
Publisher: LAP Lambert Academic Publishing
ISBN: 9783844389111
Category :
Languages : en
Pages : 132
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Book Description
The book represents a thorough study of Tin oxide doped Fluorine SnO2: F as an alternative to the well known member of transparent conductive oxide TCO family, Indium Tin Oxide (ITO) as it has some restrictions. The TCO family has a unique property of high transmission to visible light, high reflection to infrared with wavelength greater than 2 mico m. and conductive to electricity like a metal. Based on that, it has wide application in optoelectronic solar energy generation and saving devices.
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
The embodiments described herein provide an electrochromic device. In an exemplary embodiment, the electrochromic device includes (1) a substrate and (2) a film supported by the substrate, where the film includes transparent conducting oxide (TCO) nanostructures. In a further embodiment, the electrochromic device further includes (a) an electrolyte, where the nanostructures are embedded in the electrolyte, resulting in an electrolyte, nanostructure mixture positioned above the substrate and (b) a counter electrode positioned above the mixture. In a further embodiment, the electrochromic device further includes a conductive coating deposited on the substrate between the substrate and the mixture. In a further embodiment, the electrochromic device further includes a second substrate positioned above the mixture.
Author: Falko P. Netzer
Publisher: Oxford University Press
ISBN: 0198834616
Category : Science
Languages : en
Pages : 350
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Book Description
Oxide Thin Films and Nanostructures is an interdisciplinary approach to introduce readers to the field of oxide nano-materials, that is oxides of nano-meter size and dimensions. Emphasis is put to differentiate these nanoscale oxide objects from their solid bulk oxide parents and present their properties in a pedagogic way.
Author: Marwa Abd-Ellah
Publisher:
ISBN:
Category : Nanostructured materials
Languages : en
Pages : 149
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Book Description
In Ontario, there are great incentives to invest in solar cell research through the Feed-In Tariff program, which has successfully increased the total connected capacity of solar power in Ontario to well over 215 MW. Extensive studies have been conducted on fabrication of efficient solar cells, with the most mature technology being silicon-based solar cells. However, other types of solar cells have been introduced as alternatives to silicon based solar cells due to their laborious work, energy consumption, and high cost of production. Different inorganic and organic photovoltaic systems including dye-sensitized, organic/polymer, quantum-dot, and hybrid nanocrystal/polymer hetero-junctions solar cells have been proposed to provide comparable efficiencies. Transparent conductive oxides are usually the main component in any solar system because of its role as an electrode photoanode, acting as a diffusion barrier and an open-circuit voltage attenuator. These are due to their high electrical conductivity, wide optical transmittance, and relatively ease of synthesis. As a result, a rich amount of studies on their synthesis, modification, and application as photo-catalytic electrodes, gas sensors, photonic crystals, and solar cell photoanodes exists in the literature. Their use in photovoltaics as thin film materials has since evolved into nanostructured films, as numerous studies have showed that the material morphology is an important parameter in improving solar cell performance. Many nanostructured transparent conductive oxide films have been extensively investigated for use as an n-type semiconductor in a p-n junction solar cell system or as a photoanode in a dye-sensitized solar cell (DSSC). Thus far these applications have proven challenging in terms of achieving high device efficiencies, particularly by taking advantage of their inherently higher surface area-to-volume ratio, better photon harvesting, and enhanced interparticle charge transport with shorter diffusion lengths across the device structure. With a large direct band gap (3.37 eV), a large exciton binding energy (60 m eV), and high electron mobility (120 cm2 V-1 s-1), zinc oxide (ZnO) is considered an excellent candidate as an (n-type) transparent semiconducting material at room temperature for photovoltaic application. In the present work, two different ZnO nanostructural morphologies are prepared by controlling the electrolyte conductivity using a direct, catalyst- and seed-layer free electrodeposition method. The effect of deposition time and temperature on the growth of the high-specific-surface-area ZnO nanotubes electrodeposited is studied. Furthermore, the morphology, crystallinity, and chemical composition of the resulting ZnO nanotubes and nanorods are fully characterized with a proposed model of their growth mechanism. These one-dimensional ZnO nanostructures are then employed as an n-type semiconductor, along with a p-type Cu2O thin film, to fabricate an inorganic p-n junction solar cell. As an important step to improve device performance, the electrical and optical properties of the p-type Cu2O film are optimized by simple annealing. Two different device structures, consisting of the electrodeposited ZnO nanorods and nanotubes grown on the top of a thick n-type ZnO seed layer (500 nm) covered by an optimized (2.5[mu]m) p-type Cu2O layer (in order to provide the full built-in potential across the junction area), are fabricated. The relations of structural morphology (i.e. nanotube vs nanorod) and characteristic solar cell parameters are investigated. The new device architecture is found to offer minimum leakage path and reduced recombination loss expected in a typical nanostructure-based solar cell. A photon-to-electron conversion efficiency (PCE) of 0.8 % is obtained for ZnO nanotubes compared to other traditional one-dimensional nanostructures (i.e. nanorods or nanowires) that is due to the increased junction area and the better charge collection. These results illustrate the advantage of single-step electrodeposition of ZnO nanotubes, which provide a larger interfacial area and a much lower defect density than previously reported nanotubes obtained by etching ZnO nanorods. Taking advantage of their higher electron dynamics than the classical TiO2, ZnO and SnO2 are employed as photoanode materials to fabricate an organic DSSC system. To further improve the optical absorption, the effects of surface modification using gold nanoparticles to ZnO nanotubes are investigated. Different gold electrolyte concentrations are used to manipulate the plasmonic nanoparticle size while deposition time is used to control the aerial density. These studies lead to a significant increase in the PCE for DSSC based on ZnO nanotubes with gold nanoparticle modification (6%) when compared to that with pristine ZnO nanotubes (4.7%). Surface decoration with plasmonic gold nanoparticles therefore provides an efficient approach to creating not only high surface area for superior loading of dye molecules but also enhanced absorption specifically in the visible range by taking advantage of their surface plasmon resonance effect. Hierarchical one-dimensional SnO2 nanostructures are also employed as photoanode material for DSSC application. With a band gap of 3.8 eV, low UV degradation characteristic and generally high thermal and chemical stability, SnO2 is also an excellent photoanode alternative to TiO2. Almost 10-fold enhancement of PCE (3.6%) when compared with pristine SnO2 nanobelts with (0.48%) is obtained for these hierarchical SnO2 nanostructures. This significant improvement is in part due to better dye loading of highly branched nanostructures. Additional surface passivation has also been performed on the as-deposited hierarchical SnO2 nanostructures by dip-coating with an MgO passivation layer of appropriately optimized thickness. Such an insulating layer is found to effectively reduce the recombination loss process caused by the higher electron mobility of SnO2 photoanode nanostructures. This MgO-passivation treatment further enhances the PCE to (4.14%). The present work therefore shows that one-dimensional ZnO and SnO2 nanostructures provide a viable, powerful platform for developing the next-generation photovoltaic devices. This study further demonstrates the novel techniques used to significantly enhance the PCEs for both inorganic p-n junction solar cell and organic DSSC.
Author: Gianfranco Pacchioni
Publisher: John Wiley & Sons
ISBN: 3527640193
Category : Technology & Engineering
Languages : en
Pages : 368
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Book Description
A wealth of information in one accessible book. Written by international experts from multidisciplinary fields, this in-depth exploration of oxide ultrathin films covers all aspects of these systems, starting with preparation and characterization, and going on to geometrical and electronic structure, as well as applications in current and future systems and devices. From the Contents: Synthesis and Preparation of Oxide Ultrathin Films Characterization Tools of Oxide Ultrathin Films Ordered Oxide Nanostructures on Metal Surfaces Unusual Properties of Oxides and Other Insulators in the Ultrathin Limit Silica and High-K Dielectrics Thin Films in Microelectronics Oxide Passive Films and Corrosion Protection Oxide Films as Catalytic Materials and as Models of Real Catalysts Oxide Films in Spintronics Oxide Ultrathin Films in Solid Oxide Fuel Cells Transparent Conducting and Chromogenic Oxide Films as Solar Energy Materials Oxide Ultrathin Films in Sensor Applications Ferroelectricity in Ultrathin Film Capacitors Titania Thin Films in Biocompatible Materials and Medical Implants Oxide Nanowires for New Chemical Sensor Devices
Author: Alejandro G. Roca
Publisher: Springer Nature
ISBN: 3030740730
Category : Technology & Engineering
Languages : en
Pages : 289
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Book Description
This book provides a general overview and current state of the art of different types of metal oxide nanomaterials, either in nanoparticles or thin film structure. It covers from the development and optimization of different nanofabrication/synthesis techniques for nanostructures which are currently the attention of the research community, the study of the structure and interactions by different characterization techniques of heterostructured materials and the final impact in different applications such as nanotherapy, data storage, super magnets, high-frequency devices. The book’s 13 chapters provide deep insight into the intriguing science of oxide materials and include contributions on novel technologies to fabricate nanomaterials with a broad range of functional properties (semiconducting, magnetic, ferroelectric, thermoelectric, optical, flexible and mechanical). This book is intended to the experts for consolidation of their knowledge but also for students who aim to learn and get basics of nanostructured metal oxides in diverse forms.
![P-type Transparent Semiconducting Delafossite CuAlO[subscript]2+x Thin Film PDF](https://books.google.com/books/content/images/frontcover/7u7XOAAACAAJ?fife=w80-h100)
Author: Arghya N. Banerjee
Publisher:
ISBN: 9781606920329
Category : Aluminum-copper alloys
Languages : en
Pages : 0
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Book Description
Copper based delafossite transparent semiconducting oxide thin films have recently gained tremendous interest in the field of optoelectronic technology, after the discovery of p-type conductivity in a transparent thin film of copper aluminium oxide (CuAlO2). Most of the well-known and widely used transparent conducting oxide thin films such as ZnO, SnO2, ITO etc. and their doped versions are n-type material, but corresponding p-type transparent conducting oxides were surprisingly missing for a long time until the fabrication of above-mentioned p-CuAlO2 thin film have been published (Nature 1997, 389, 939). This has opened up a new field in opto-electronics device technology, the so-called "Transparent Electronics", where a combination of the two types of transparent conducting oxides in the form of a p-n junction could lead to a 'functional' window, which transmits visible portion of solar radiation yet generates electricity by the absorption of UV part of it. Non-stoichiometric and doped versions of various new types of p-type transparent conducting oxides with improved optical and electrical properties have been synthesised in the last few years in this direction. Wide range of deposition techniques have been adopted to prepare the films. But fabrication of device quality films by cost-effective deposition techniques such as sputtering, chemical vapour deposition, wet-chemical dip-coating technique etc. are the need of the hour for large-scale production of these films for diverse device applications. Here the authors have discussed the fabrication and opto-electrical characterisation of p-CuAlO2+x thin films by cost-effective and scalable deposition routes such as sputtering and wet-chemical dip-coating technique. The authors have also discussed briefly some of the new developments in the field of p-type transparent conducting oxide thin film technology and an up-to-date and comprehensive description of different Cu-based p-type transparent conducting oxide thin films is presented. Also the origin of p-type conductivity in these transparent oxides has been dealt with considerable attention. Fabrication of all-transparent junctions is also discussed which is most important in the development of 'Transparent Electronics'. Field emission properties of thin films are currently of much interest due to the potential application in field emission displays (FEDs), which are considered to be strong candidate for low-power panel applications. The low-threshold field emission properties of wide-bandgap CuAlO2 thin films have been investigated for its potential applications in FED technology. The films showed considerable low turn-on field. This finding might open up a new direction in the field-emission technology, and a new group of materials (such as, different transparent conducting oxides) might become a promising candidate for low-threshold field emitter. Also, recently, the research on nanostructured materials generates great interest in the scientific community and offers tremendous opportunities in the field of science and technology. Here, the authors have also discussed in brief, the formation of nanocrystalline p-CuAlO2 films, which may open up an extremely important and interesting field of research for the fabrication of all-transparent nano-active devices. This will not only give a new dimension in the field of 'Transparent Electronics', but new avenues may open up in the nanoparticle research keeping an eye on its tremendous applications in optoelectronics technology.
Author: Qingbin Zheng
Publisher: Springer
ISBN: 1493927698
Category : Technology & Engineering
Languages : en
Pages : 231
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Book Description
This book provides a systematic presentation of the principles and practices behind the synthesis and functionalization of graphene and grapheme oxide (GO), as well as the fabrication techniques for transparent conductors from these materials. Transparent conductors are used in a wide variety of photoelectronic and photovoltaic devices, such as liquid crystal displays (LCDs), solar cells, optical communication devices, and solid-state lighting. Thin films made from indium tin oxide (ITO) have thus far been the dominant source of transparent conductors, and now account for 50% of indium consumption. However, the price of Indium has increased 1000% in the last 10 years. Graphene, a two-dimensional monolayer of sp2-bonded carbon atoms, has attracted significant interest because of its unique transport properties. Because of their high optical transmittance and electrical conductivity, thin film electrodes made from graphene nanosheets have been considered an ideal candidate to replace expensive ITO films. Graphene for Transparent Conductors offers a systematic presentation of the principles, theories and technical practices behind the structure–property relationship of the thin films, which are the key to the successful development of high-performance transparent conductors. At the same time, the unique perspectives provided in the applications of graphene and GO as transparent conductors will serve as a general guide to the design and fabrication of thin film materials for specific applications.
Author: David Levy
Publisher: John Wiley & Sons
ISBN: 3527804617
Category : Technology & Engineering
Languages : en
Pages : 501
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Book Description
Der Herausgeber ist ein bekannter Pionier des Fachgebiets mit über 30 Jahren Erfahrung. Dieses Handbuch bietet einen umfassenden Überblick über transparente leitfähige Materialien und legt dabei den Schwerpunkt auf praktische Anwendungen. Nach einer Einführung in die Materialien und jüngsten Entwicklungen werden die Synthese und Charakterisierung sowie Beschichtungsverfahren erläutert, die für die Energiegewinnung und bei lichtemittierenden Anwendungen häufig zum Einsatz kommen. Zukünftige technologische Fortschritte werden am Ende des Buches erörtert. Dieses umfassende und aktuelle interdisziplinäre Fachbuch deckt das komplette Spektrum ab, von der Chemie und den Materialwissenschaften zum Ingenieurswesen, von Lehre und Forschung bis zur Industrie, von den grundlegenden Herausforderungen hin zu direkt verfügbaren Anwendungen.
Author: Fabian I. Ezema
Publisher: Springer Nature
ISBN: 3030684628
Category : Technology & Engineering
Languages : en
Pages : 926
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Book Description
This book guides beginners in the areas of thin film preparation, characterization, and device making, while providing insight into these areas for experts. As chemically deposited metal oxides are currently gaining attention in development of devices such as solar cells, supercapacitors, batteries, sensors, etc., the book illustrates how the chemical deposition route is emerging as a relatively inexpensive, simple, and convenient solution for large area deposition. The advancement in the nanostructured materials for the development of devices is fully discussed.
