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Author: Vahid Hasannaeimi
Publisher:
ISBN:
Category :
Languages : en
Pages : 133
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Book Description
In this dissertation, nano-manufacturing of amorphous alloys for electro-catalytic applications is reported and the role of chemistry and active surface area on catalytic behavior is discussed. The catalytic activity of recently developed platinum and palladium-based metallic glasses was studied using cyclic voltammetry and localized electrochemical techniques. The synergistic effect between platinum and palladium was shown for amorphous alloys containing both these elements. The mechanism for superior catalytic behavior was investigated through electronic structure and surface chemical state of the alloys. A correlation between the work function and catalytic performance of the amorphous alloys with widely varying chemistries was established. To address the high cost associated with the noble-metal containing catalysts, the performance of non-noble Ni-P amorphous catalyst was evaluated for electro-catalysis. A facile pulsed electrodeposition approach was used for the nano-manufacturing of these amorphous catalysts. This nano-manufacturing route allowed the synthesis of fully amorphous nano-wires at room temperature for alloys with little or no noble-metal content. A wide range of nano-wires with varying aspect ratios from 25 to 120 was synthesized using commercially obtained anodic aluminum oxide (AAO) nano-molds. Cyclic voltammetry and chrono-amperometry demonstrated superior performance in terms of electrocatalytic activity and stability of the metallic glass nano-wires towards electro-oxidation of methanol. The mechanism for amorphization during pulsed electrodeposition is discussed and compared with the conventional approach of rapid quenching of the liquid melt.
Author: Vahid Hasannaeimi
Publisher:
ISBN:
Category :
Languages : en
Pages : 133
Get Book Here
Book Description
In this dissertation, nano-manufacturing of amorphous alloys for electro-catalytic applications is reported and the role of chemistry and active surface area on catalytic behavior is discussed. The catalytic activity of recently developed platinum and palladium-based metallic glasses was studied using cyclic voltammetry and localized electrochemical techniques. The synergistic effect between platinum and palladium was shown for amorphous alloys containing both these elements. The mechanism for superior catalytic behavior was investigated through electronic structure and surface chemical state of the alloys. A correlation between the work function and catalytic performance of the amorphous alloys with widely varying chemistries was established. To address the high cost associated with the noble-metal containing catalysts, the performance of non-noble Ni-P amorphous catalyst was evaluated for electro-catalysis. A facile pulsed electrodeposition approach was used for the nano-manufacturing of these amorphous catalysts. This nano-manufacturing route allowed the synthesis of fully amorphous nano-wires at room temperature for alloys with little or no noble-metal content. A wide range of nano-wires with varying aspect ratios from 25 to 120 was synthesized using commercially obtained anodic aluminum oxide (AAO) nano-molds. Cyclic voltammetry and chrono-amperometry demonstrated superior performance in terms of electrocatalytic activity and stability of the metallic glass nano-wires towards electro-oxidation of methanol. The mechanism for amorphization during pulsed electrodeposition is discussed and compared with the conventional approach of rapid quenching of the liquid melt.
Author: Lin Guo
Publisher: John Wiley & Sons
ISBN: 3527826351
Category : Technology & Engineering
Languages : en
Pages : 434
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Book Description
A valuable overview covering important fundamental and applicative aspects of amorphous nanomaterials! Amorphous nanomaterials are very important in non-crystalline solids, which have emerged as a new category of advanced materials. Compared to the crystalline counterpart, amorphous nanomaterials with isotropic nature always exhibit fast ion diffusion, relieved strain, and higher reactivity, enabling such materials to exhibit high performance in mechanics and catalysis, as well as other interesting properties. Amorphous Nanomaterials: Preparation, Characterization, and Applications covers the fundamental concept, synthesis, characterization, properties, and applications of nanoscaled amorphous materials. It starts with the introduction of amorphous materials, then gives a global view of the history, structure, and growth mechanism of amorphous nanomaterials. Subsequently, some powerful techniques to characterize amorphous materials, such as X-ray absorption fine structure spectroscopy, spherical aberration electron microscope, in-situ-Transmission Electron Microscope, Electron Energy Loss Spectroscopy, and some other defect characterization technologies are included. Furthermore, the emerging innovative methods to fabricate well-defined, regularshaped amorphous nanomaterials, including zero-, one-, two-, and three-dimensional amorphous nanomaterials are systematically introduced. The fascinating properties and applications related to amorphous nanomaterials including the applications in electrocatalysis, batteries, supercapacitors, photocatalysis, mechanics, etc., are presented. It will greatly help the researchers to find professional answers related to amorphous materials. Great topic: amorphous nanomaterials are a very large and important field in both academia and industry Comprehensive: in-depth discussion of various important aspects, from both a fundamental and an applied point of view, on the chemistry, physics and technological importance of the amorphous nanomaterials are presented Vitally needed: the understanding of the fundamentals of amorphous nanomaterials is a prerequisite for devising new applications of such materials Highly relevant: amorphous nanomaterials have found specific applications in chemistry, catalysis, physics, sensing, batteries, supercapacitors, and engineering Amorphous Nanomaterials is a vital resource for materials scientists, inorganic and physical chemists, solid state chemists, physicists, catalytic and analytical chemists, as well as organic chemists.
Author: Bangwei Zhang
Publisher: Elsevier
ISBN: 0128027061
Category : Technology & Engineering
Languages : en
Pages : 774
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Book Description
Amorphous and Nano Alloys Electroless Depositions: Technology, Theory, Structure and Property describes the whole development and the most important subjects (technology, theory, structure and property) up to date of electroless plating (EP). The author concentrates on the fundamental scientific and academic problems (principle, mechanism and theory) in EP today.Based on the history of EP, this valuable reference describes lots of new EP processes, including electroless Fe based alloy system deposits, formation and theoretical description of electroless alloys, microscopic theory of electroless plating deposits, microscopic structures and surface morphology of electroless deposits, and weldability property of electroless deposits. - Focus on the fundamental scientific and academic problems (principles, mechanisms and theory) in electroless plating - The book gives a very good overview of the research and development in this field and each chapter is fully referenced - Detailed analysis and review of the current data, logically structured for ease of use
Author: Lin Guo
Publisher: John Wiley & Sons
ISBN: 352734747X
Category : Technology & Engineering
Languages : en
Pages : 434
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Book Description
A valuable overview covering important fundamental and applicative aspects of amorphous nanomaterials! Amorphous nanomaterials are very important in non-crystalline solids, which have emerged as a new category of advanced materials. Compared to the crystalline counterpart, amorphous nanomaterials with isotropic nature always exhibit fast ion diffusion, relieved strain, and higher reactivity, enabling such materials to exhibit high performance in mechanics and catalysis, as well as other interesting properties. Amorphous Nanomaterials: Preparation, Characterization, and Applications covers the fundamental concept, synthesis, characterization, properties, and applications of nanoscaled amorphous materials. It starts with the introduction of amorphous materials, then gives a global view of the history, structure, and growth mechanism of amorphous nanomaterials. Subsequently, some powerful techniques to characterize amorphous materials, such as X-ray absorption fine structure spectroscopy, spherical aberration electron microscope, in-situ-Transmission Electron Microscope, Electron Energy Loss Spectroscopy, and some other defect characterization technologies are included. Furthermore, the emerging innovative methods to fabricate well-defined, regularshaped amorphous nanomaterials, including zero-, one-, two-, and three-dimensional amorphous nanomaterials are systematically introduced. The fascinating properties and applications related to amorphous nanomaterials including the applications in electrocatalysis, batteries, supercapacitors, photocatalysis, mechanics, etc., are presented. It will greatly help the researchers to find professional answers related to amorphous materials. Great topic: amorphous nanomaterials are a very large and important field in both academia and industry Comprehensive: in-depth discussion of various important aspects, from both a fundamental and an applied point of view, on the chemistry, physics and technological importance of the amorphous nanomaterials are presented Vitally needed: the understanding of the fundamentals of amorphous nanomaterials is a prerequisite for devising new applications of such materials Highly relevant: amorphous nanomaterials have found specific applications in chemistry, catalysis, physics, sensing, batteries, supercapacitors, and engineering Amorphous Nanomaterials is a vital resource for materials scientists, inorganic and physical chemists, solid state chemists, physicists, catalytic and analytical chemists, as well as organic chemists.
Author: A.M. Glezer
Publisher: CRC Press
ISBN: 135138354X
Category : Science
Languages : en
Pages : 600
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Book Description
Amorphous-nanocrystalline alloys are a relatively new class of materials born from the rapid development of new technologies and different methods of producing amorphous and nanocrystalline powders and films, compacting, melt quenching, megaplastic deformation, implantation, laser, plasma, and other high-energy methods. This book considers methods of producing these materials (melt quenching, controlled crystallization, deformation effect, and pulse treatments (photon, laser and ultrasound), spraying thin films, and ion implantation). Theoretical and experimental studies describe plastic deformation mechanisms and physico-mechanical properties. Practical applications are also presented.
Author: R H J Hannink
Publisher: Taylor & Francis US
ISBN: 9781855739338
Category : Technology & Engineering
Languages : en
Pages : 380
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Book Description
Annotation Nanotechnology is an area of science and technology where dimensions and tolerances in the range of 0.1 nm to 100nm play a critical role. Nanotechnology has opened up new worlds of opportunity. It encompasses precision engineering as well as electronics, electromechanical systems and mainstream biomedical applications in areas as diverse as gene therapy, drug delivery and novel drug discovery techniques. Nanostructured materials present exciting opportunities for manipulating structure and properties on the nanometer scale. The ability to engineer novel structures at the molecular level has led to unprecedented opportunities for materials design. This new book provides detailed insights into the synthesis/structure and property relationships of nanostructured materials. A valuable book for materials scientists, mechanical and electronic engineers and medical researchers. CONTENTS Special properties resulting from nanodimensionality; Nanoparticle technologies; Control of molecular assemblies; Functional organic inorganic nanocomposites; Molecular modelling of nanomorphology in polymers; Nanodimensionality and ionic transport; Multi scale simulation of nanionic polymer systems; Nanoengineering in metallic systems; Characterisation of nanometallic systems with NMR; Mechanical behaviour of metallic nanolaminates; Mechanics of nanocomposite structures; Preparation, properties and performance of Nanocrystalline ceramics; Novel properties from nanoceramics; Hydrogen storage in nanostructured materials; Nanofabrication.
Author: Mei Yan
Publisher: Springer Science & Business Media
ISBN: 4431549315
Category : Science
Languages : en
Pages : 134
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Book Description
In this thesis, the focus is on the study of new catalytic properties of unsupported nanoporous metals in heterogeneous organic reactions under liquid-phase conditions. The author was the first to fabricate nanoporous copper with tunable nanoporosity and apply it for organic reactions. The catalyst can be reused up to ten times without loss of catalytic activity. In addition, the author developed the highly selective semihydrogenation of alkynes using nanoporous gold as a catalyst for the first time, affording Z-alkenes in 100% selectivity, which cannot be realized by traditional catalysts. All of the results described here will help readers to develop new catalytic performance of nanoporous metals for organic reactions.
Author: Justin S J Hargreaves
Publisher: Royal Society of Chemistry
ISBN: 1788014839
Category : Science
Languages : en
Pages : 204
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Book Description
Many important industrial chemical processes rely heavily on catalysis and so researchers are always on the lookout for alternative catalytic materials that may improve existing processes or lead to new ones. Families of alternative catalytic materials currently being investigated include the carbides, nitrides and phosphides as well as amorphous boron catalysts. The addition of carbon, nitrogen or phosphorous to transition metals and the creation of boron-transition metal alloys leads to catalytic materials that have interesting properties, with applications in a range of different reactions, including electrocatalysis. This book provides a comprehensive account of the preparation, characterisation and application of these catalytic materials. It is an important reference for researchers and industrialists working in heterogeneous catalysis and materials chemistry.
Author: Bing Zhou
Publisher: Springer Science & Business Media
ISBN: 9780306483233
Category : Science
Languages : en
Pages : 416
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Book Description
This book is mainly based on the first and second symposia on Nanotechnology in Catalysis held in 2001 and 2002, but it also includes several contributions not presented in the symposia to round out the scope of the subject. The contents are the most up to date developments made by researchers all over the world in the catalysis field in this fascinating nanotechnology era. It reflects some of the frontier areas of nanoscience and nanotechnology in fabricating and characterizing catalysts and carrying out studies to prove their superior selectivity and activity. The field of application of nanotechnology for the development of catalysts for green chemistry is likely to grow rapidly during the next decade. This book hopes to contribute to the evolution of nanotechnology in that direction.
Author: Richard W. Siegel
Publisher: Springer Science & Business Media
ISBN: 9401591857
Category : Technology & Engineering
Languages : en
Pages : 354
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Book Description
Timely information on scientific and engineering developments occurring in laboratories around the world provides critical input to maintaining the economic and technological strength of the United States. Moreover, sharing this information quickly with other countries can greatly enhance the productivity of scientists and engineers. These are some of the reasons why the National Science Foundation (NSF) has been involved in funding science and technology assessments comparing the United States and foreign countries since the early 1980s. A substantial number of these studies have been conducted by the World Technology Evaluation Center (WTEC) managed by Loyola College through a cooperative agreement with NSF. The National Science and Technology Council (NSTC), Committee on Technology's Interagency Working Group on NanoScience, Engineering and Technology (CT/IWGN) worked with WTEC to develop the scope of this Nanostucture Science and Technology report in an effort to develop a baseline of understanding for how to strategically make Federal nanoscale R&D investments in the coming years. The purpose of the NSTC/WTEC activity is to assess R&D efforts in other countries in specific areas of technology, to compare these efforts and their results to U. S. research in the same areas, and to identify opportunities for international collaboration in precompetitive research. Many U. S. organizations support substantial data gathering and analysis efforts focusing on nations such as Japan. But often the results of these studies are not widely available. At the same time, government and privately sponsored studies that are in the public domain tend to be "input" studies.
