Molecular Dynamics of Electron Transfer Processes Between Iron and Ruthenium Centers Coordinated by Proteins and Classical Ligands PDF Download
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Author: John Roberts Walton
Publisher:
ISBN:
Category : Chemical kinetics
Languages : en
Pages : 438
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Author: John Roberts Walton
Publisher:
ISBN:
Category : Chemical kinetics
Languages : en
Pages : 438
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Book Description
Author:
Publisher:
ISBN:
Category : Chemical kinetics
Languages : en
Pages : 396
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Author:
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ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 598
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Author: University Microfilms International
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Category : Dissertations, Academic
Languages : en
Pages : 858
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Author:
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ISBN:
Category : Dissertation abstracts
Languages : en
Pages : 776
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Author: American Chemical Society. Committee on Professional Training
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Category : Biochemistry
Languages : en
Pages : 1932
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Faculties, publications and doctoral theses in departments or divisions of chemistry, chemical engineering, biochemistry and pharmaceutical and/or medicinal chemistry at universities in the United States and Canada.
Author:
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Category : Dissertations, Academic
Languages : en
Pages : 818
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Vols. for 1973- include the following subject areas: Biological sciences, Agriculture, Chemistry, Environmental sciences, Health sciences, Engineering, Mathematics and statistics, Earth sciences, Physics, Education, Psychology, Sociology, Anthropology, History, Law & political science, Business & economics, Geography & regional planning, Language & literature, Fine arts, Library & information science, Mass communications, Music, Philosophy and Religion.
Author:
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Category : Dissertations, Academic
Languages : en
Pages : 844
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Author: Peter Henry Dinolfo
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Category :
Languages : en
Pages :
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The primary focus of this thesis is the examination of intramolecular electron transfer processes in mixed valence compounds. Rhenium based supramolecular coordination chemistry has been used create a number of highly symmetrical structures that contain cofacially arranged, redox active ligands. When reduced by an odd number of electrons, the molecules belong to an unusual class of mixed valence compounds where the ligands are the degenerate redox centers, i.e. Ligand-Centered Mixed Valency. Inter-ligand electronic communication in these systems is controlled by direct donor/acceptor orbital overlap rather than by superexchange through the molecular framework. As shown by X-ray crystallography and semiempirical modeling, the spectroscopically determined electronic coupling strengths are consistent with geometrical configurational differences between the cofacial ligand pairs. In a number of cases, electroabsorbance (Stark) spectroscopy has been employed to directly evaluate the adiabatic charge transfer distances. Depending the geometrical arrangement of the redox active ligand pairs, the degree of electronic communication can be tuned from non-interacting (Robin-Day Class I), to fully delocalized (Class III).
Author: Egor Vladimirov
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ISBN:
Category :
Languages : en
Pages : 148
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