Modern Electrochemistry

Modern Electrochemistry PDF Author: John O'M. Bockris
Publisher: Springer Science & Business Media
ISBN: 9780306250026
Category : Science
Languages : en
Pages : 876

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Book Description
7 The Electrified Interface.- 7.1 Electrification of an Interface.- 7.1.1 The Electrode-Electrolyte Interface: The Basis of Electrodics.- 7.1.2 New Forces at the Boundary of an Electrolyte.- 7.1.3 The Interphase Region Has New Properties and New Structures.- 7.1.4 An Electrode Is Like a Giant Central Ion.- 7.1.5 The Consequences of Compromise Arrangements: The Electrolyte Side of the Boundary Acquires a Charge.- 7.1.6 Both Sides of the Interface Become Electrified: The So-Called "Electrical Double Layer"--7.1.7 Double Layers Are Characteristic of All Phase Boundaries.- 7.1.8 A Look into an El.

Modern Electrochemistry 2B

Modern Electrochemistry 2B PDF Author: John O'M. Bockris
Publisher: Springer Science & Business Media
ISBN: 0306480360
Category : Science
Languages : en
Pages : 553

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Book Description
This book had its nucleus in some lectures given by one of us (J. O’M. B. ) in a course on electrochemistry to students of energy conversion at the University of Pennsyl- nia. It was there that he met a number of people trained in chemistry, physics, biology, metallurgy, and materials science, all of whom wanted to know something about electrochemistry. The concept of writing a book about electrochemistry which could be understood by people with very varied backgrounds was thereby engendered. The lectures were recorded and written up by Dr. Klaus Muller as a 293-page manuscript. At a later stage, A. K. N. R. joined the effort; it was decided to make a fresh start and to write a much more comprehensive text. Of methods for direct energy conversion, the electrochemical one is the most advanced and seems the most likely to become of considerable practical importance. Thus, conversion to electrochemically powered transportation systems appears to be an important step by means of which the difficulties of air pollution and the effects of an increasing concentration in the atmosphere of carbon dioxide may be met. Cor- sion is recognized as having an electrochemical basis. The synthesis of nylon now contains an important electrochemical stage. Some central biological mechanisms have been shown to take place by means of electrochemical reactions. A number of American organizations have recently recommended greatly increased activity in training and research in electrochemistry at universities in the United States.

Modern Electrochemistry

Modern Electrochemistry PDF Author: John O'M. Bockris
Publisher: Springer Science & Business Media
ISBN: 9780306250026
Category : Science
Languages : en
Pages : 876

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Book Description
7 The Electrified Interface.- 7.1 Electrification of an Interface.- 7.1.1 The Electrode-Electrolyte Interface: The Basis of Electrodics.- 7.1.2 New Forces at the Boundary of an Electrolyte.- 7.1.3 The Interphase Region Has New Properties and New Structures.- 7.1.4 An Electrode Is Like a Giant Central Ion.- 7.1.5 The Consequences of Compromise Arrangements: The Electrolyte Side of the Boundary Acquires a Charge.- 7.1.6 Both Sides of the Interface Become Electrified: The So-Called "Electrical Double Layer"--7.1.7 Double Layers Are Characteristic of All Phase Boundaries.- 7.1.8 A Look into an El.

Modern Electrochemistry 2A

Modern Electrochemistry 2A PDF Author: John O'M. Bockris
Publisher: Springer Science & Business Media
ISBN: 0306476053
Category : Science
Languages : en
Pages : 812

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Book Description
This book had its nucleus in some lectures given by one of us (J. O’M. B. ) in a course on electrochemistry to students of energy conversion at the University of Pennsyl- nia. It was there that he met a number of people trained in chemistry, physics, biology, metallurgy, and materials science, all of whom wanted to know something about electrochemistry. The concept of writing a book about electrochemistry which could be understood by people with very varied backgrounds was thereby engendered. The lectures were recorded and written up by Dr. Klaus Muller as a 293-page manuscript. At a later stage, A. K. N. R. joined the effort; it was decided to make a fresh start and to write a much more comprehensive text. Of methods for direct energy conversion, the electrochemical one is the most advanced and seems the most likely to become of considerable practical importance. Thus, conversion to electrochemically powered transportation systems appears to be an important step by means of which the difficulties of air pollution and the effects of an increasing concentration in the atmosphere of carbon dioxide may be met. Cor- sion is recognized as having an electrochemical basis. The synthesis of nylon now contains an important electrochemical stage. Some central biological mechanisms have been shown to take place by means of electrochemical reactions. A number of American organizations have recently recommended greatly increased activity in training and research in electrochemistry at universities in the United States.

An Introduction to Electrochemistry

An Introduction to Electrochemistry PDF Author: Samuel Glasstone
Publisher: Read Books Ltd
ISBN: 1446545466
Category : Science
Languages : en
Pages : 586

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Book Description
The object of this book is to provide an introduction to electro chemistry in its present state of development. An attempt has been made to explain the fundamentals of the subject as it stands today, de voting little or no space to the consideration of theories and arguments that have been discarded or greatly modified. In this way it is hoped that the reader will acquire the modern point of view in electrochemistry without being burdened by much that is obsolete. In the opinion of the writer, there have been four developments in the past two decades that have had an important influence on electrochemistry. They are the ac tivity concept, the interionic attraction theory, the proton-transfer theory of acids and bases, and the consideration of electrode reactions as rate processes. These ideas have been incorporated into the structure of the book, with consequent simplification and clarification in the treatment of many aspects of electrochemistry. This book differs from the au thors earlier work, The Electrochem istry of Solutions in being less comprehensive and in giving less detail. While the latter is primarily a work of reference, the present book is more suited to the needs of students of physical chemistry, and to those of chemists, physicists and physiologists whose work brings them in con tact with a variety of electrochemical problems. As the title implies, the book should also serve as an introductory text for those who in tend to specialize in either the theoretical or practical applications of electrochemistry. In spite of some lack of detail, the main aspects of the subject have been covered, it is hoped impartially and adequately. There has been some tendency in recent electrochemical texts to pay scant attention to the phenomena at active electrodes, such as ovcrvoltage, passivity, cor rosion, deposition of metals, and so on. These topics, vihich are of importance in applied electrochemistry, are treated here at Mich length as seems reasonable. In addition, in view of tho growing interest in electrophoresis, and its general acceptance as a branch of electrochem istry, a chapter on clectrokinetic phenomena has boon included. No claim is made to anything approaching completeness in the matter of references to the scientific literature. Such reformers as arc given arc generally to the more recent publications, to review articles, and to papers that may, for one reason or another, have some special interest. References are also frequently included to indicate the sources from which data have been obtained for many of the diagrams and tables. Since no effort was made to be exhaustive in this connection, it was felt that an author index would be misleading...

Electrochemical Methods

Electrochemical Methods PDF Author: Allen J. Bard
Publisher: Wiley Global Education
ISBN: 1118312805
Category : Science
Languages : de
Pages : 862

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Book Description
Das führende Werk auf seinem Gebiet - jetzt durchgängig auf den neuesten Stand gebracht! Die theoretischen Grundlagen der Elektrochemie, erweitert um die aktuellsten Erkenntnisse in der Theorie des Elektronentransfers, werden hier ebenso besprochen wie alle wichtigen Anwendungen, darunter modernste Verfahren (Ultramikroelektroden, modifizierte Elektroden, LCEC, Impedanzspektrometrie, neue Varianten der Pulsvoltammetrie und andere). In erster Linie als Lehrbuch gedacht, läßt sich das Werk aber auch hervorragend zum Selbststudium und zur Auffrischung des Wissensstandes verwenden. Lediglich elementare Grundkenntnisse der physikalischen Chemie werden vorausgesetzt.

Modern Aspects of Electrochemistry 42

Modern Aspects of Electrochemistry 42 PDF Author: Constantinos G. Vayenas
Publisher: Springer Science & Business Media
ISBN: 0387494898
Category : Science
Languages : en
Pages : 434

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Book Description
This volume analyzes and summarizes recent developments in several key interfacial electrochemical systems in the areas of fuel cell electrocatatalysis, electrosynthesis and electrodeposition. The six Chapters are written by internationally recognized experts in these areas and address both fundamental and practical aspects of several existing or emerging key electrochemical technologies. The Chapter by R. Adzic, N. Marinkovic and M. Vukmirovic provides a lucid and authoritative treatment of the electrochemistry and electrocatalysis of Ruthenium, a key element for the devel- ment of efficient electrodes for polymer electrolyte (PEM) fuel cells. Starting from fundamental surface science studies and interfacial considerations, this up-to-date review by some of the pioneers in this field, provides a deep insight in the complex catalytic-electrocatalytic phenomena occurring at the interfaces of PEM fuel cell electrodes and a comprehensive treatment of recent developments in this extremely important field. Several recent breakthroughs in the design of solid oxide fuel cell (SOFC) anodes and cathodes are described in the Chapter of H. Uchida and M. Watanabe. The authors, who have pioneered several of these developments, provide a lucid presentation d- cribing how careful fundamental investigations of interfacial electrocatalytic anode and cathode phenomena lead to novel electrode compositions and microstructures and to significant practical advances of SOFC anode and cathode stability and enhanced electrocatalysis.

Molecular Electronic-Structure Theory

Molecular Electronic-Structure Theory PDF Author: Trygve Helgaker
Publisher: John Wiley & Sons
ISBN: 1119019559
Category : Science
Languages : en
Pages : 949

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Book Description
Ab initio quantum chemistry has emerged as an important tool in chemical research and is appliced to a wide variety of problems in chemistry and molecular physics. Recent developments of computational methods have enabled previously intractable chemical problems to be solved using rigorous quantum-mechanical methods. This is the first comprehensive, up-to-date and technical work to cover all the important aspects of modern molecular electronic-structure theory. Topics covered in the book include: * Second quantization with spin adaptation * Gaussian basis sets and molecular-integral evaluation * Hartree-Fock theory * Configuration-interaction and multi-configurational self-consistent theory * Coupled-cluster theory for ground and excited states * Perturbation theory for single- and multi-configurational states * Linear-scaling techniques and the fast multipole method * Explicity correlated wave functions * Basis-set convergence and extrapolation * Calibration and benchmarking of computational methods, with applications to moelcular equilibrium structure, atomization energies and reaction enthalpies. Molecular Electronic-Structure Theory makes extensive use of numerical examples, designed to illustrate the strengths and weaknesses of each method treated. In addition, statements about the usefulness and deficiencies of the various methods are supported by actual examples, not just model calculations. Problems and exercises are provided at the end of each chapter, complete with hints and solutions. This book is a must for researchers in the field of quantum chemistry as well as for nonspecialists who wish to acquire a thorough understanding of ab initio molecular electronic-structure theory and its applications to problems in chemistry and physics. It is also highly recommended for the teaching of graduates and advanced undergraduates.

Quantities, Units and Symbols in Physical Chemistry

Quantities, Units and Symbols in Physical Chemistry PDF Author: International Union of Pure and Applied Chemistry. Physical and Biophysical Chemistry Division
Publisher: Royal Society of Chemistry
ISBN: 0854044337
Category : Reference
Languages : en
Pages : 240

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Book Description
Prepared by the IUPAC Physical Chemistry Division this definitive manual, now in its third edition, is designed to improve the exchange of scientific information among the readers in different disciplines and across different nations. This book has been systematically brought up to date and new sections added to reflect the increasing volume of scientific literature and terminology and expressions being used. The Third Edition reflects the experience of the contributors with the previous editions and the comments and feedback have been integrated into this essential resource. This edition has been compiled in machine-readable form and will be available online.

Electrochemical Materials Science

Electrochemical Materials Science PDF Author: John Bockris
Publisher: Springer Science & Business Media
ISBN: 1475748256
Category : Science
Languages : en
Pages : 579

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Book Description
It is now time for a comprehensive treatise to look at the whole field of electrochemistry. The present treatise was conceived in 1974, and the earliest invitations to authors for contributions were made in 1975. The completion of the early been delayed by various factors. volumes has There has been no attempt to make each article emphasize the most recent situation at the expense of an overall statement of the modern view. This treatise is not a collection of articles from Recent Advances in Electrochemistry or Modern Aspects of Electrochemistry. It is an attempt at making a mature statement about the present position in the vast area of what is best looked at as a new interdisciplinary field. Texas A & M University J. O'M. Bockris University of Ottawa B. E. Conway Case Western Reserve University Ernest Yeager Texas A & M University Ralph E. White Preface to Volume 4 The science of degradation of materials involves a vast area of science and technology, the economic importance of which rivals that of any other clearly defined area affecting the standard of life. The basis of the corrosion process is the electrochemical charge-transfer reaction, and the center of the subject of the degradation of materials is electrochemical material science.

Modern Electrochemistry

Modern Electrochemistry PDF Author: John O'Mara Bockris
Publisher:
ISBN:
Category :
Languages : en
Pages : 0

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Book Description