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Author: B. E. Conway
Publisher: Springer Science & Business Media
ISBN: 0387258388
Category : Science
Languages : en
Pages : 556
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Book Description
This volume comprises six chapters on aspects of fundamental and applied electrochemical science that will be of interest both to researchers in the basic areas of the subject and to those involved in aspects of electrochemical technologies. Chapter 1 is the first part of a 2-part, major contribution by Joachim Maier on Solid State Electrochemistry: Thermodynamics and Kinetics of Charge Carriers in Solids. Part 2 will follow in volume 39 to be published in year 2005. This contribution reviews modern concepts of the equilibria involving charge carriers in solids in terms of concentrations of defects in solids and at grain-boundaries, including doping effects. Complementarily, kinetics of charge transfer and ion transfer are treated in some detail in relation to conductance, kinetics of surface processes and electrode-kinetics involving solid-state processes. This chapter will be of major interest to electrochemists and physicists in the semiconductor field and that involving ionic solids. In the second chapter, Appleby presents a detailed discussion and review in modern terms of a central aspect of electrochemistry: Electron Transfer Reactions With and Without Ion Transfer. Electron transfer is the most fundamental aspect of most processes at electrode interfaces and is also involved intimately with the homogeneous chemistry of redox reactions in solutions.
Author: B. E. Conway
Publisher: Springer Science & Business Media
ISBN: 0387258388
Category : Science
Languages : en
Pages : 556
Get Book Here
Book Description
This volume comprises six chapters on aspects of fundamental and applied electrochemical science that will be of interest both to researchers in the basic areas of the subject and to those involved in aspects of electrochemical technologies. Chapter 1 is the first part of a 2-part, major contribution by Joachim Maier on Solid State Electrochemistry: Thermodynamics and Kinetics of Charge Carriers in Solids. Part 2 will follow in volume 39 to be published in year 2005. This contribution reviews modern concepts of the equilibria involving charge carriers in solids in terms of concentrations of defects in solids and at grain-boundaries, including doping effects. Complementarily, kinetics of charge transfer and ion transfer are treated in some detail in relation to conductance, kinetics of surface processes and electrode-kinetics involving solid-state processes. This chapter will be of major interest to electrochemists and physicists in the semiconductor field and that involving ionic solids. In the second chapter, Appleby presents a detailed discussion and review in modern terms of a central aspect of electrochemistry: Electron Transfer Reactions With and Without Ion Transfer. Electron transfer is the most fundamental aspect of most processes at electrode interfaces and is also involved intimately with the homogeneous chemistry of redox reactions in solutions.
Author: John O'M. Bockris
Publisher: Springer Science & Business Media
ISBN: 1461533767
Category : Science
Languages : en
Pages : 558
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Book Description
Covering both the theoretical and applied aspects of electrochemistry, this well-known monograph series presents a review of the latest advances in the field.
Author: Constantinos G. Vayenas
Publisher: Springer Science & Business Media
ISBN: 0387317015
Category : Science
Languages : en
Pages : 296
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Book Description
This volume of Modern Aspects covers a wide spread of topics presented in an authoritative, informative and instructive manner by some internationally renowned specialists. Professors Politzer and Dr. Murray provide a comprehensive description of the various theoretical treatments of solute-solvent interactions, including ion-solvent interactions. Both continuum and discrete molecular models for the solvent molecules are discussed, including Monte Carlo and molecular dynamics simulations. The advantages and drawbacks of the resulting models and computational approaches are discussed and the impressive progress made in predicting the properties of molecular and ionic solutions is surveyed. The fundamental and applied electrochemistry of the silicon/electrolyte interface is presented in an authoritative review by Dr. Gregory Zhang, with emphasis in the preparation of porous silicon, a material of significant technological interest, via anodic dissolution of monocrystalline Si. The chapter shows eloquently how fundamental electrokinetic principles can be utilized to obtain the desired product morphology. Markov chains theory provides a powerful tool for modeling several important processes in electrochemistry and electrochemical engineering, including electrode kinetics, anodic deposit formation and deposit dissolution processes, electrolyzer and electrochemical reactors performance and even reliability of warning devices and repair of failed cells. The way this can be done using the elegant Markov chains theory is described in lucid manner by Professor Thomas Fahidy in a concise chapter which gives to the reader only the absolutely necessary mathematics and is rich in practical examples.
Author: Ralph E. White
Publisher: Springer Science & Business Media
ISBN: 0306469170
Category : Science
Languages : en
Pages : 654
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Book Description
Recognized experts present incisive analysis of both fundamental and applied problems in this continuation of a highly acclaimed series. Topics discussed include: A review of the literature on the potential-of-zero charge by Trasatti and Lust. A thorough review and discussion of nonequilibrium fluctuations in corrosion processes. A wide-ranging discussion of conducting polymers, electrochemistry, and biomimicking processes. Microwave (photo)electrochemistry, from its origins to today's research opportunities, including its relation to electrochemistry. New fluorine cell design, from model development through preliminary engineering modeling, laboratory tests, and pilot plant tests. A comprehensive account of the major and rapidly developing field of the electrochemistry of electronically conducting polymers and their applications. These authoritative studies will be invaluable for researchers in engineering, electrochemistry, analytical chemistry, materials science, physical chemistry, and corrosion science.
Author: Costas G. Vayenas
Publisher: Springer Science & Business Media
ISBN: 0306479273
Category : Science
Languages : en
Pages : 321
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Book Description
This volume of Modern Aspects contains a remarkable spread of topics covered in an authoritative manner by some internationally renowned specialists. In a seminal chapter Drs. Babu, Oldfield and Wieckowski demonstrate eloquently the strength of electrochemical nuclear magnetic resonance (EC-NMR) to study in situ both sides of the electrochemical interface via the simultaneous use of and This powerful non-invasive technique brings new insights to both fundamental and practical key aspects of electrocatalysis, including the design of better anodes for PEM fuel cells. The recent impressive advances in the use of rigorous ab initio quantum chemical calculations in electrochemistry are described in a remarkable chapter by Marc Koper, one of the leading protagonists in this fascinating area. This lucid chapter is addressed to all electrochemists, including those with very little prior exposure to quantum chemistry, and demonstrates the usefulness of ab initio calculations, including density functional theory (DFT) methods, to understand several key aspects of fuel cell electrocatalysis at the molecular level. The most important macroscopic and statistical thermodynamic models developed to describe adsorption phenomena on electrodes are presented critically in a concise and authoritative chapter by Panos Nikitas. The reader is guided through the seminal contributions of Frumkin, Butler, Bockris, Guidelli and others, to the current state of the art adsorption isotherms, which are both rigorous, and in good agreement with experiment.
Author: J. O'M. Bockris
Publisher: Springer Science & Business Media
ISBN: 1461574528
Category : Science
Languages : en
Pages : 335
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Book Description
The first chapter in the present volume takes up a well-known theme in modern context: the ideas concerning non-Stokesian mechanisms of ion transport. We are happy that one of the great pioneers of modern electrochemistry, T. Erdey-Gniz, in collaboration with S. Lengyel, has consented to write this article for us. Along with it is a solution-oriented article in spectroscopic vein, namely, that by A. Covington and K. E. Newman on the analysis of solution constituents by means of nuclear magnetic resonance studies. Progress in the electrochemistry of the double layer has perked up, and the advances have been triggered from critical experiments, one showing that fluoride ions are specifically adsorbed, and the other showing that the position of maximum disorder of the water molecules occurs at a charge opposite to that needed for interpreta tions of capacitance humps in terms of water molecules. M. A. Habib, who has contributed to the theory in this area, reviews the con sequences of these changes in information. The rise in the price of energy toward a situation in which sources other than the fossil fuels become economical implies much for the fuel cell and electrocatalysis. It has long been known that electrocatalysis in real situations was more than a consideration of exchange current densities, and a gap remains in the formulation of the theory of supports for such catalysts, although Boudart has stressed so much the vital nature of them. P. Stonehart and K. A. Kinoshita describe progress in this area.
Author: Constantinos G. Vayenas
Publisher: Springer Science & Business Media
ISBN: 0387494898
Category : Science
Languages : en
Pages : 434
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Book Description
This volume analyzes and summarizes recent developments in several key interfacial electrochemical systems in the areas of fuel cell electrocatatalysis, electrosynthesis and electrodeposition. The six Chapters are written by internationally recognized experts in these areas and address both fundamental and practical aspects of several existing or emerging key electrochemical technologies. The Chapter by R. Adzic, N. Marinkovic and M. Vukmirovic provides a lucid and authoritative treatment of the electrochemistry and electrocatalysis of Ruthenium, a key element for the devel- ment of efficient electrodes for polymer electrolyte (PEM) fuel cells. Starting from fundamental surface science studies and interfacial considerations, this up-to-date review by some of the pioneers in this field, provides a deep insight in the complex catalytic-electrocatalytic phenomena occurring at the interfaces of PEM fuel cell electrodes and a comprehensive treatment of recent developments in this extremely important field. Several recent breakthroughs in the design of solid oxide fuel cell (SOFC) anodes and cathodes are described in the Chapter of H. Uchida and M. Watanabe. The authors, who have pioneered several of these developments, provide a lucid presentation d- cribing how careful fundamental investigations of interfacial electrocatalytic anode and cathode phenomena lead to novel electrode compositions and microstructures and to significant practical advances of SOFC anode and cathode stability and enhanced electrocatalysis.
Author: Richard C. Alkire
Publisher: John Wiley & Sons
ISBN: 3527605398
Category : Science
Languages : en
Pages : 389
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Book Description
From reviews of the previous volumes: 'This is an essential book for researchers in electrochemistry; it covers areas of both fundamental and practical importance, with reviews of high quality. The material is very well presented and the choice of topics reflects a balanced editorial policy that is welcomed.' The Analyst 'All the contributions in this volume are well up to the standard of this excellent series and will be of great value to electrochemists... The editors again deserve to be congratulated on this fine collection of reviews.' Journal of Electroanalytical Chemistry and Interfacial Chemistry '...competently and clearly written.' Berichte der Bunsen- Gesellschaft für Physikalische Chemie
Author: National Library of Medicine (U.S.)
Publisher:
ISBN:
Category : Medicine
Languages : en
Pages : 1516
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Book Description
A keyword listing of serial titles currently received by the National Library of Medicine.
Author: Stojan S. Djokić
Publisher: Springer Science & Business Media
ISBN: 1461423805
Category : Science
Languages : en
Pages : 412
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Book Description
This new volume of Modern Aspects of Electrochemistry reviews different methods for the production of metal powders including mechanical, chemical and electrochemical powders. Electrochemically produced metal powders are of high purity and they are extremely active during sintering. These powders find a wide-range of applications in automotive, aerospace, energy device and electronics industries.
