Mechanistic Insights Into Late Transition Metal-Catalyzed Olefin Hydrosilylation and Synthesis of New N-Heterocyclic Carbene and Dinuclear Complexes PDF Download
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Author: Korbinian Riener
Publisher:
ISBN: 9783843926225
Category :
Languages : en
Pages :
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Author: Korbinian Riener
Publisher:
ISBN: 9783843926225
Category :
Languages : en
Pages :
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Book Description
Author: Frank Glorius
Publisher: Springer
ISBN: 3540369309
Category : Science
Languages : en
Pages : 240
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Book Description
In this book leading experts have surveyed major areas of application of NHC metal complexes in catalysis. The authors have placed a special focus on nickel- and palladium-catalyzed reactions, on applications in metathesis reactions, on oxidation reactions and on the use of chiral NHC-based catalysts. This compilation is rounded out by an introductory chapter and a chapter dealing with synthetic routes to NHC metal complexes.
Author: Anna Candace Badaj
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author: Walter Kaminsky
Publisher: Wiley-VCH
ISBN: 9783527317424
Category : Technology & Engineering
Languages : en
Pages : 0
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With an enormous velocity, olefin polymerization has expanded to one of the most significant fields in polymers since the first industrial use about 50 years ago. In 2005, 100 million tons of polyolefins were produced - the biggest part was catalyzed by metallorganic compounds. The Hamburg Macromolecular Symposium 2005 with the title "Olefin Polymerization" involved topics such as new catalysts and cocatalysts, kinetics, mechanism and polymer reaction engineering, synthesis of special polymers, and characterization of polyolefins. The conference combined scientists from different disciplines to discuss latest research results of polymers and to offer each other the possibility of cooperation. This is reflected in this volume, which contains invited lectures and selected posters presented at the symposium.
Author: Steven Nolan
Publisher: Thieme
ISBN: 3132414034
Category : Science
Languages : en
Pages : 816
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Book Description
The field of N-heterocyclic carbenes, whether in transition-metal catalysis or organocatalysis, is rapidly evolving towards applications, but is also still very active on the catalyst development front. Significant advances have been made over the past two decades and the development of these reactions has dramatically improved the efficiency of organic synthesis. N-Heterocyclic carbene based catalysts are now widely applied in the area of synthesis of both natural products and therapeutic agents. "Science of Synthesis: N-Heterocyclic Carbenes in Catalytic Organic Synthesis" presents the most commonly used and significant metal- or non-metal-catalyzed reactions for modern organic synthesis. The basic principles and current state-of-the-art of the methods are covered. Scope, limitations, and mechanism of these reactions are discussed and key experimental procedures are included. Typical examples of target synthesis are often provided to show the utility and inspire further applications.
Author: Balaram Raya
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Organic reactions catalyzed by metal complexes are an effective way to improve atom economy and environmental friendliness for many synthetic transformations. Among the various synthetic transformations, hydrosilylation reaction has huge industrial applications for manufacturing consumer goods. The alkylsilanes from alkene hydrosilylation are widely used as raw materials in manufacturing silicon rubbers, molding implants and adhesive. The hydrosilylation reactions can also produce various organosilicon reagents, which are used in fine chemical synthesis for stereospecific oxidation and cross coupling reaction. Over the long decades, numerous reports on metal-catalyzed hydrosilylations include the use of platinum, palladium, rhodium, ruthenium, iridium, lanthanides and actinides, early transition metals, iron, cobalt to a limited extent nickel. This work has shown that readily accessible (iPrPDI)CoCl2 reacts with 2 equivalents NaEt3BH at -78 oC in toluene to generate a catalyst that effects highlyselective anti-Markovnikov hydrosilylation of the terminal double bond in alkene, 1,3- and 1,4-dienes. Primary and secondary silanes such as PhSiH3, Ph2SiH2 and PhSi(Me)H2 react with a broad spectrum of dienes without affecting the configuration of the other double bond. A slight modification of the reaction conditions using a less reactive silane (OEt)2Si(Me)H leads to unprecedented and highly selective reduction of the terminal double bond with no contamination from the silane or reduction products of the more substituted double bond. The major limitation for cobalt catalyzed hydrosilylation reaction using redox active PDI ligand is its terminal selectivity. However, this active catalyst did not work for 1,1-disubstituted alkenes. In this connection, we also observed efficient cobalt catalyst system for hydrosilylation of 1,1-disubstituted alkenes using chelating phosphine ligand at room temperature, which is able to do hydrosilylation for numerous substrates such as alkene, vinyl arene, conjugated diene, 1,4-skipped diene and 1,1-disubstituted alkenes. Carbocyclizations of a,¿-p-systems are extremely important and useful reactions for the synthesis of a variety of carbocyclic and heterocyclic compounds. Although metal catalyzed cyclization has been long known, controlling the selectivity (chemo- and regio-) remains an important challenge in this field. Nickel complexes have been known to be specifically effective for cyclic homo-and co-oligomerization of alkenes, alkynes and dienes. During the past few years, through an approach that relied mostly on mechanistic insights and systematic examination of ligand effects, RajanBabu group has discovered a number of protocols for Ni(II)-catalyzed heterodimerization reactions of vinylarenes, selected 1,3-dienes and strained olefins. Substitution of one of the phenyl groups of triphenylphosphine with a 2-benzyloxy-(e.g., L18), 2-benzyloxy-methyl-(L19) or 2-benzyloxyethyl-(L20) phenyl moiety results in a set of simple ligands, which exhibit strikingly different behavior in various nickel (II)-catalyzed olefin dimerization reactions including related cycloisomerization of 1,6-dienes. Nickel(II)-catalyzed cycloisomerization of 1,6-dienes into methylenecyclopentanes, a reaction mechanistically related to the other heterodimerization reactions, is also uniquely affected by nickel(II) complexes of L18, but not of L19 or L20. In an attempt to prepare authentic samples of the methylenecyclohexane products, nickel(II) complexes of N-heterocyclic carbene ligands were examined. In contrast to the phosphine, which gives the methylenecyclopentanes, methylenecyclohexanes are the major products in the N-heterocyclic carbine ligated nickel (II)-mediated reaction. This dissertation discusses the ligand effect on hydrofuctionalization of alkenes using nickel or cobalt metal complexes.
Author: Steven Nolan
Publisher: Thieme
ISBN: 3132013315
Category : Science
Languages : en
Pages : 807
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Book Description
The field of N-heterocyclic carbenes, whether in transition-metal catalysis or organocatalysis, is rapidly evolving towards applications, but is also still very active on the catalyst development front. Significant advances have been made over the past two decades and the development of these reactions has dramatically improved the efficiency of organic synthesis. N-Heterocyclic carbene based catalysts are now widely applied in the area of synthesis of both natural products and therapeutic agents. Science of Synthesis: N-Heterocyclic Carbenes in Catalytic Organic Synthesis presents the most commonly used and significant metal- or non-metal-catalyzed reactions for modern organic synthesis. The basic principles and current state-of-the-art of the methods are covered. Scope, limitations, and mechanism of these reactions are discussed and key experimental procedures are included. Typical examples of target synthesis are often provided to show the utility and inspire further applications.
Author: Zhibin Guan
Publisher: Springer Science & Business Media
ISBN: 3540877509
Category : Science
Languages : en
Pages : 262
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Book Description
Polyolefin is a major industry that is important for our economy and impacts every aspect of our lives. The discovery of new transition metal-based catalysts is one of the driving forces for the further advancement of this field. Whereas the classical heterogeneous Ziegler-Natta catalysts and homogeneous early transition metal metallocene catalysts remain the workhorses of the polyolefin industry, in roughly the last decade, tremendous progress has been made in developing non-metallocene-based olefin polymerization catalysts. Particularly, the discovery of late transition metal-based olefin polymerization catalysts heralds a new era for this field. These late transition metal complexes not only exhibit high activities rivaling their early metal counterparts, but more importantly they offer unique properties for polymer architectural control and copolymerization with polar olefins. In this book, the most recent major breakthroughs in the development of new olefin polymerization catalysts, including early metal metallocene and non-metallocene complexes and late transition metal complexes, are discussed by leading experts. The authors highlight the most important discoveries in catalysts and their applications in designing new polyolefin-based functional materials.
Author: Montserrat Diéguez
Publisher: John Wiley & Sons
ISBN: 3527804072
Category : Technology & Engineering
Languages : en
Pages : 431
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Book Description
An important reference for researchers in the field of metal-enzyme hybrid catalysis Artificial Metalloenzymes and MetalloDNAzymes in Catalysis offers a comprehensive review of the most current strategies, developed over recent decades, for the design, synthesis, and optimization of these hybrid catalysts as well as material about their application. The contributors—noted experts in the field—present information on the preparation, characterization, and optimization of artificial metalloenzymes in a timely and authoritative manner. The authors present a thorough examination of this interesting new platform for catalysis that combines the excellent selective recognition/binding properties of enzymes with transition metal catalysts. The text includes information on the various applications of metal-enzyme hybrid catalysts for novel reactions, offers insights into the latest advances in the field, and contains an informative perspective on the future: Explores the development of artificial metalloenzymes, the modern and strongly evolving research field on the verge of industrial application Contains a comprehensive reference to the research area of metal-enzyme hybrid catalysis that has experienced tremendous growth in recent years Includes contributions from leading researchers in the field Shows how this new catalysis combines the selective recognition/binding properties of enzymes with transition metal catalysts Written for catalytic chemists, bioinorganic chemists, biochemists, and organic chemists, Artificial Metalloenzymes and MetalloDNAzymes in Catalysis offers a unique reference to the fundamentals, concepts, applications, and the most recent developments for more efficient and sustainable synthesis.
Author: Jianping Yang
Publisher:
ISBN: 9789179117740
Category :
Languages : en
Pages :
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