Matrix Isolation-infrared and Mass Spectrometric Studies of High-temperature Molecules PDF Download
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Author: S. Dickinson
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Category :
Languages : en
Pages :
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Author: S. Dickinson
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Category :
Languages : en
Pages :
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Author: Trevor Neil Day
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Category :
Languages : en
Pages :
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Author: S. Dickinson
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Category : Nuclear reactors
Languages : en
Pages :
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Author: A. Barnes
Publisher: Springer Science & Business Media
ISBN: 9400985401
Category : Science
Languages : en
Pages : 602
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The matrix isolation (MI) method has now been used for nearly thirty years. During this period it has been actively developed and the range of problems tackled greatly extended. Originally it was used for studies of transient species involv ing vibrational, electronic and ESR spectroscopy. Nowadays the study of transient species forms a comparatively small part of HI work since it has been amply demonstrated that very fruitful information can be obtained of the structure and interactions of stable molecules and their aggregates. In addition to the s~ectroscopic methods mentioned above the MI technique is nowadays a standard method in research based on vibrational relaxation, luminescence, Mossbauer, magnetic circular dichroism, pulsed NMR and photoelectron spectroscopy. The matrix isolation technique affords considerable advantages over more conventional methods in most applications of spectroscopy. Areas where the technique has been widely applied, or shows great potential, include: metal atom chemistry, and its relation to surface chemistry, high temperature inorganic species, transition metal complexes, interstellar species, free radicals and unstable molecules, conformational studies, molecular com plexes, and intermolecular forces.
Author: Paul David Gregory
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Languages : en
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Category : Power resources
Languages : en
Pages : 852
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Author: Donald T. Hawkins
Publisher: Springer Science & Business Media
ISBN: 1468461478
Category : Science
Languages : en
Pages : 250
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Coverage For some time, we have contemplated a comprehensive review of the structures and force fields of the binary fluorides. This bibliography of 1498 references marks the first step of that effort. We are pub lishing this material now rather than waiting until the review is complete some two years hence because we believe that the information already accumulated will be of immediate use to a broad spectrum of researchers. Anyone ambitious enough to read through all the articles on binary fluorides will find that the struc tures and force fields of many of these molecules are at present unknown. For example, it has not been clearly established to which point group(s) the lanthanide trifluorides should be assigned. There remain interesting problems relating to the role of Jahn-Teller and pseudo-Jahn-Teller distortions in some of the transition metal fluorides such as VF , MoF , ReF , and ReF , to name only a few. One s s 6 7 also finds fascinating examples of large-amplitude motions, or pseudorotations, as they are often called, in such molecules as XeF 6, I F 7, and PF 5' For those binary fluorides whose equilibrium geometries are precisely known, there still exists the problem of accurately determining the harmonic force field. In a few cases, most notably the Group VA trifluorides, there has been some attempt made at extracting the cubic and quartic contributions to the force field.
Author: John W. Hastie
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Category : Gases at high temperatures
Languages : en
Pages : 836
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Category : Military research
Languages : en
Pages : 572
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Category : Weights and measures
Languages : en
Pages : 668
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