Matrix Isolation and Photochemistry of Transition Metal Carbonyl Complexes PDF Download
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Author: Gosse Boxhoorn
Publisher:
ISBN:
Category : Carbonyl compounds
Languages : en
Pages : 163
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Book Description
Author: Gosse Boxhoorn
Publisher:
ISBN:
Category : Carbonyl compounds
Languages : en
Pages : 163
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Book Description
Author: Gosse Boxhoorn
Publisher:
ISBN:
Category :
Languages : en
Pages : 186
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Author: R. B. Hitam
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author: David John Taylor
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author: Terry Richard Fletcher
Publisher:
ISBN:
Category :
Languages : en
Pages : 546
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Author: Zhenglong Xiao
Publisher:
ISBN:
Category :
Languages : en
Pages : 225
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Author: Carol Lynn Reichel
Publisher:
ISBN:
Category : Metal carbonyls
Languages : en
Pages : 614
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Author: Helmut Werner
Publisher: Springer Science & Business Media
ISBN: 0387098488
Category : Science
Languages : en
Pages : 361
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Book Description
Since the discovery of ferrocene and the sandwich-type complexes, the development of organometallic chemistry took its course like an avalanche and became one of the scientific success stories of the second half of the twentieth century. Based on this development, the traditional boundaries between inorganic and organic chemistry gradually disappeared and a rebirth of the nowadays highly important field of homogeneous catalysis occurred. It is fair to say that despite the fact that the key discovery, which sparked it all off, was made more than 50 years ago, organometallic chemistry remains a young and lively discipline.
Author: E. Kochanski
Publisher: Springer Science & Business Media
ISBN: 9401126984
Category : Science
Languages : en
Pages : 448
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Book Description
The scope of this paper is to recall fundamental notions of the molecular spectroscopy and dynamics, necessary for discussion of photophysical and photochemical processes in condensed phases. We will thus treat in a more detailed way the specific features which are important for molecular systems strongly interacting with their environment. Other aspects such as the time evolution of isolated molecules, single-level excitation and state-to-state chemistry, important for the gas-phase photophysics are omitted. We start (Sec.2) with a brief description of radiative processes (light absorption and emission) in molecules. In the quantum-mechanical treatment of this problem, the appropriate basis is that of so-called zero-order states, corresponding to the traditional scheme of electronic states (singlets, doublets, triplets etc.) and vibrational levels belonging to each state. The important point will be deduction of selection rules for most radiative transitions. At this stage all molecular states are considered as stationary states. In order to treat the breakdown of simple selection rules and non-radiative transitions between individual molecular states, it is necessary to take into account the mechanisms coupling the zero-order states (Sec.3). We will first focus on intramolecular coupling effects and then discuss the solvent effects on intramolecular relaxation processes. The problem of the non-radiative transfer of the electronic energy between different molecules - closely related to that of the energy dissipation within a single molecule will be treated in Sec.4.
Author: A. Barnes
Publisher: Springer Science & Business Media
ISBN: 9400985401
Category : Science
Languages : en
Pages : 602
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Book Description
The matrix isolation (MI) method has now been used for nearly thirty years. During this period it has been actively developed and the range of problems tackled greatly extended. Originally it was used for studies of transient species involv ing vibrational, electronic and ESR spectroscopy. Nowadays the study of transient species forms a comparatively small part of HI work since it has been amply demonstrated that very fruitful information can be obtained of the structure and interactions of stable molecules and their aggregates. In addition to the s~ectroscopic methods mentioned above the MI technique is nowadays a standard method in research based on vibrational relaxation, luminescence, Mossbauer, magnetic circular dichroism, pulsed NMR and photoelectron spectroscopy. The matrix isolation technique affords considerable advantages over more conventional methods in most applications of spectroscopy. Areas where the technique has been widely applied, or shows great potential, include: metal atom chemistry, and its relation to surface chemistry, high temperature inorganic species, transition metal complexes, interstellar species, free radicals and unstable molecules, conformational studies, molecular com plexes, and intermolecular forces.
