Author: 楊濟源
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Author: Fryderyk Lyzwa
Publisher: Springer Nature
ISBN: 3031118669
Category : Technology & Engineering
Languages : en
Pages : 158

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This PhD thesis reports on investigations of several oxide-based materials using advanced infrared and Raman spectroscopy techniques and in combination with external stimuli such as high magnetic or electric field, sptial confinement in thin film heterostructures and the radiation with UV light. This leads to new results in the fields of superconductivity, electronic polarization states and nanoscale phenomena. Among these, the observation of anomalous polar moments is of great relevance for understanding the electric-field-induced metal-to-insulator transistion; and the demonstration that confocal Raman spectroscopy of backfolded acoustic photons in metal-oxide multilayers can be used as a powerful characterization tool for monitoring their interface properties and layer thickness is an important technical development for the engineering of such functional oxide heterostructures.

Author: Vasilios N. Stavrou
Publisher: BoD – Books on Demand
ISBN: 1789846269
Category : Science
Languages : en
Pages : 176

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The field of low-dimensional structures has been experiencing rapid development in both theoretical and experimental research. Phonons in Low Dimensional Structures is a collection of chapters related to the properties of solid-state structures dependent on lattice vibrations. The book is divided into two parts. In the first part, research topics such as interface phonons and polaron states, carrier-phonon non-equilibrium dynamics, directional projection of elastic waves in parallel array of N elastically coupled waveguides, collective dynamics for longitudinal and transverse phonon modes, and elastic properties for bulk metallic glasses are related to semiconductor devices and metallic glasses devices. The second part of the book contains, among others, topics related to superconductor, phononic crystal carbon nanotube devices such as phonon dispersion calculations using density functional theory for a range of superconducting materials, phononic crystal-based MEMS resonators, absorption of acoustic phonons in the hyper-sound regime in fluorine-modified carbon nanotubes and single-walled nanotubes, phonon transport in carbon nanotubes, quantization of phonon thermal conductance, and phonon Anderson localization.

Author: Yakun Yuan
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Complex oxides present a fertile ground states of spin, lattice, orbital, and charge degree of freedom. The competition and interaction among different degrees of freedom provide a fascinating playground for fundamental scientific research as well as exploring applications in modern technologies. The scope of materials research has gone beyond understanding materials behaviors in ground states, and has extended to engineering new properties into materials and exploring possible hidden phases. There are static and dynamic approaches can be utilized to drive a material away from its ground state. Statically, by engineering complex oxides into heterostructures, the strain epitaxy effect can significantly alter the properties of the epitaxially grown films. In addition, tilt epitaxy promises an even more powerful route to directly control materials properties through a ubiquitous distortion in complex oxides. However, the characterization of tilt epitaxy is still challenging. The dynamic approach based on the idea of mode-selective pumping using ultrafast optical pulses, which can transiently drive a material away from its ground state by exciting a particular degree of freedom. Combining with delayed probe pulses, the dynamic trajectories of materials can be mapped out at femtosecond temporal resolution. Chapter 2 adopts the static approach following the scheme of tilt epitaxy. This chapter explores the paradigm of tilt epitaxy in thin films and demonstrates the non-destructively characterizing such epitaxy in three-dimensions for low symmetry complex tilt systems composed of light anions. More specifically, this chapter demonstrates that the interfacial tilt epitaxy can transform ultrathin calcium titanate, a non-polar earth-abundant mineral, into high-temperature polar oxides that last above 900 K. The comprehensive picture of octahedral tilts and polar distortions is revealed by reconstructing the three-dimensional electron density maps across film-substrate interfaces with atomic resolution using coherent Bragg rod analysis. The results are complemented with aberration-corrected transmission electron microscopy, film superstructure reflections, and are in excellent agreement with density functional theory. The study could serve as a broader template for non-destructive, three-dimensional atomic resolution probing of complex low symmetry functional interfaces. Chapter 3 turns to dynamic modulation the ground state of Ca3Ru2O7, which exhibits a rich phase diagram including two magnetic transitions (TN=56 K and TC=48 K) with the appearance of an insulating-like pseudogap (at TC). In addition, there is a crossover back to metallic behavior at T*=30 K, the origin of which is still under debate. This chapter applies ultrafast optical pump optical probe spectroscopy to investigate quasi-particle dynamics as a function of temperature in this enigmatic quantum material. Two dynamical processes are identified, both of which are influenced by the onset of the pseudogap. This includes electron-phonon relaxation and, below TC, the onset of a phonon bottleneck hindering the relaxation of quasiparticles across the pseudogap. A gap-modified two-temperature model is introduced to describe the temperature dependence of electron-phonon thermalization, and use the Rothwarf-Taylor to model the phonon bottleneck. In conjunction with density functional theory, the experimental results synergistically reveal the origin of the T-dependent pseudogap. Further, the data and analysis indicate that T* emerges as a natural consequence of T-dependent gapping out of carriers, and does not correspond to a separate electronic transition. The results highlight the value of low fluence ultrafast optics as a sensitive probe of low energy electronic structure, thermodynamic parameters, and transport properties of quantum materials. Chapter 4 serves as a comprehensive technical review of coherent Bragg rods analysis. This chapter starts with a mathematical description of the COBRA method and related iteration algorithms. Technical details being discussed includes: experimental data processing, symmetry application, convergence discussion, choice of boundary condition, sample thickness, and error analysis. The newly developed MATLAB routines for COBRA is introduced in appendix. Chapter 5 is a summary of the thesis and contains possible future directions.

Author:
Publisher:
ISBN:
Category : Chemistry
Languages : en
Pages : 2540

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Author:
Publisher:
ISBN:
Category : Solid state physics
Languages : en
Pages : 778

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Author:
Publisher:
ISBN:
Category : Aeronautics
Languages : en
Pages : 292

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Author:
Publisher:
ISBN:
Category : Physics
Languages : en
Pages : 1058

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Author:
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ISBN:
Category : Nuclear energy
Languages : en
Pages : 998

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Author: H. Ibach
Publisher: Academic Press
ISBN: 1483259455
Category : Science
Languages : en
Pages : 379

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Electron Energy Loss Spectroscopy and Surface Vibrations is devoted to electron energy loss spectroscopy as a probe of the crystal surface. Electrons with energy in the range of a few electron volts sample only a few atomic layers. As they approach or exit from the crystal, they interact with the vibrational modes of the crystal surface, or possibly with other elementary excitations localized there. The energy spectrum of electrons back-reflected from the surface is thus a rich source of information on its dynamics. The book opens with a detailed analysis of the physics that controls the operation of the monochromator, which is the core of the experimental apparatus. Separate chapters follow on the interaction of electrons with vibrational modes of the surface region and with other elementary excitations in the vicinity; the lattice dynamics of clean and adsorbate-covered surfaces, with emphasis on those features of particular relevance to surface vibrational spectroscopy; and selected applications vibration spectroscopy in surface physics and chemistry.