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Author: Ionel Haiduc
Publisher: Sunway University Press
ISBN: 9675492325
Category : Science
Languages : en
Pages : 213
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Book Description
Inverse Coordination Chemistry: A Novel Chemical Concept features and discusses the interesting array of inverse coordination complexes, from those with monoatomic or polyatomic centres to those with organic molecules as centres. While traditional coordination complexes consist of a metal atom at the centre surrounded by inorganic ligands, inverse coordination complexes show a reversed topology: a central non-metal atom surrounded by metallic ligands. Illustrative and concisely written, this book is a timely and comprehensive introduction to this exciting but largely overlooked field of inverse coordination in inorganic chemistry. This book serves as an invaluable resource for chemists, educators, and students.
Author: Ionel Haiduc
Publisher: Sunway University Press
ISBN: 9675492325
Category : Science
Languages : en
Pages : 213
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Book Description
Inverse Coordination Chemistry: A Novel Chemical Concept features and discusses the interesting array of inverse coordination complexes, from those with monoatomic or polyatomic centres to those with organic molecules as centres. While traditional coordination complexes consist of a metal atom at the centre surrounded by inorganic ligands, inverse coordination complexes show a reversed topology: a central non-metal atom surrounded by metallic ligands. Illustrative and concisely written, this book is a timely and comprehensive introduction to this exciting but largely overlooked field of inverse coordination in inorganic chemistry. This book serves as an invaluable resource for chemists, educators, and students.
Author: Ionel Haiduc
Publisher: Sunway University Press
ISBN: 9789675492181
Category : Science
Languages : en
Pages : 112
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Book Description
Presents the fascinating array of inverse coordination complexes, from monoatomic centres to those with organic molecules as centres, in a systematic manner with colour illustrative examples. This book is a timely and comprehensive introduction to this largely overlooked field of inverse coordination in inorganic chemistry. Inverse Coordination Chemistry features and discusses the interesting array of inverse coordination complexes, from those with monoatomic or polyatomic centres to those with organic molecules as centres. While traditional coordination complexes consist of a metal atom at the centre surrounded by inorganic ligands, inverse coordination complexes show a reversed topology: a central non-metal atom surrounded by metallic ligands. Concisely written, this book is a timely and comprehensive introduction to this exciting but largely overlooked field of inverse coordination in inorganic chemistry. This book serves as an invaluable resource for chemists, educators, and students.
Author: J. A. McCleverty
Publisher: Newnes
ISBN: 0080913164
Category : Science
Languages : en
Pages : 11845
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Book Description
Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.
Author: John K. Gibson
Publisher: John Wiley & Sons
ISBN: 1119115523
Category : Science
Languages : en
Pages : 534
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Book Description
A review of contemporary actinide research that focuses on new advances in experiment and theory, and the interplay between these two realms Experimental and Theoretical Approaches to Actinide Chemistry offers a comprehensive review of the key aspects of actinide research. Written by noted experts in the field, the text includes information on new advances in experiment and theory and reveals the interplay between these two realms. The authors offer a multidisciplinary and multimodal approach to the nature of actinide chemistry, and explore the interplay between multiple experiments and theory, as well as between basic and applied actinide chemistry. The text covers the basic science used in contemporary studies of the actinide systems, from basic synthesis to state-of-the-art spectroscopic and computational techniques. The authors provide contemporary overviews of each topic area presented and describe the current and anticipated experimental approaches for the field, as well as the current and future computational chemistry and materials techniques. In addition, the authors explore the combination of experiment and theory. This important resource: Provides an essential resource the reviews the key aspects of contemporary actinide research Includes information on new advances in experiment and theory, and the interplay between the two Covers the basic science used in contemporary studies of the actinide systems, from basic synthesis to state-of-the-art spectroscopic and computational techniques Focuses on the interplay between multiple experiments and theory, as well as between basic and applied actinide chemistry Written for academics, students, professionals and researchers, this vital text contains a thorough review of the key aspects of actinide research and explores the most recent advances in experiment and theory.
Author: Mandeep Dalal
Publisher: Dalal Institute
ISBN: 8193872002
Category : Science
Languages : en
Pages : 482
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Book Description
An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory; dπ -pπ bonds; Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions; Trends in stepwise constants; Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand; Chelate effect and its thermodynamic origin; Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes; Mechanisms for ligand replacement reactions; Formation of complexes from aquo ions; Ligand displacement reactions in octahedral complexes- acid hydrolysis, base hydrolysis; Racemization of tris chelate complexes; Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes; The trans effect; Theories of trans effect; Mechanism of electron transfer reactions – types; outer sphere electron transfer mechanism and inner sphere electron transfer mechanism; Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory; Molecular orbital theory: octahedral, tetrahedral or square planar complexes; π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals; Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states); Calculation of Dq, B and β parameters; Effect of distortion on the d-orbital energy levels; Structural evidence from electronic spectrum; John-Tellar effect; Spectrochemical and nephalauxetic series; Charge transfer spectra; Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry; Guoy’s method for determination of magnetic susceptibility; Calculation of magnetic moments; Magnetic properties of free ions; Orbital contribution, effect of ligand-field; Application of magneto-chemistry in structure determination; Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes; Wade’s rules; Carboranes; Metal carbonyl clusters - low nuclearity carbonyl clusters; Total electron count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls: structure and bonding; Vibrational spectra of metal carbonyls for bonding and structure elucidation; Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Author:
Publisher: Newnes
ISBN: 0080965296
Category : Science
Languages : en
Pages : 7694
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Book Description
Comprehensive Inorganic Chemistry II, Nine Volume Set reviews and examines topics of relevance to today’s inorganic chemists. Covering more interdisciplinary and high impact areas, Comprehensive Inorganic Chemistry II includes biological inorganic chemistry, solid state chemistry, materials chemistry, and nanoscience. The work is designed to follow on, with a different viewpoint and format, from our 1973 work, Comprehensive Inorganic Chemistry, edited by Bailar, Emeléus, Nyholm, and Trotman-Dickenson, which has received over 2,000 citations. The new work will also complement other recent Elsevier works in this area, Comprehensive Coordination Chemistry and Comprehensive Organometallic Chemistry, to form a trio of works covering the whole of modern inorganic chemistry. Chapters are designed to provide a valuable, long-standing scientific resource for both advanced students new to an area and researchers who need further background or answers to a particular problem on the elements, their compounds, or applications. Chapters are written by teams of leading experts, under the guidance of the Volume Editors and the Editors-in-Chief. The articles are written at a level that allows undergraduate students to understand the material, while providing active researchers with a ready reference resource for information in the field. The chapters will not provide basic data on the elements, which is available from many sources (and the original work), but instead concentrate on applications of the elements and their compounds. Provides a comprehensive review which serves to put many advances in perspective and allows the reader to make connections to related fields, such as: biological inorganic chemistry, materials chemistry, solid state chemistry and nanoscience Inorganic chemistry is rapidly developing, which brings about the need for a reference resource such as this that summarise recent developments and simultaneously provide background information Forms the new definitive source for researchers interested in elements and their applications; completely replacing the highly cited first edition, which published in 1973
Author: International Union of Pure and Applied Chemistry
Publisher: Royal Society of Chemistry
ISBN: 0854044388
Category : Science
Languages : en
Pages : 379
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Book Description
The 'Red Book' is the definitive guide for scientists requiring internationally approved inorganic nomenclature in a legal or regulatory environment.
Author: Geoffrey A. Lawrance
Publisher: John Wiley & Sons
ISBN: 1118681401
Category : Science
Languages : en
Pages : 307
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Book Description
At the heart of coordination chemistry lies the coordinate bond, in its simplest sense arising from donation of a pair of electrons from a donor atom to an empty orbital on a central metalloid or metal. Metals overwhelmingly exist as their cations, but these are rarely met ‘naked’ – they are clothed in an array of other atoms, molecules or ions that involve coordinate covalent bonds (hence the name coordination compounds). These metal ion complexes are ubiquitous in nature, and are central to an array of natural and synthetic reactions. Written in a highly readable, descriptive and accessible style Introduction to Coordination Chemistry describes properties of coordination compounds such as colour, magnetism and reactivity as well as the logic in their assembly and nomenclature. It is illustrated with many examples of the importance of coordination chemistry in real life, and includes extensive references and a bibliography. Introduction to Coordination Chemistry is a comprehensive and insightful discussion of one of the primary fields of study in Inorganic Chemistry for both undergraduate and non-specialist readers.
Author: Ponnadurai Ramasami
Publisher: Springer
ISBN: 3319317598
Category : Science
Languages : en
Pages : 375
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Book Description
Twenty-three carefully selected, peer-reviewed contributions from the International Conference on Pure and Applied Chemistry (ICPAC 2014) are featured in this edited book of proceedings. ICPAC 2014, a biennial meeting, was held in Mauritius in June 2014. The theme of the conference was “Crystallizing Ideas: The Role of Chemistry” and it matched the declaration of the year 2014 as the International Year of Crystallography. ICPAC 2014 was attended by 150 participants from 30 countries. The chapters in this book reflect a wide range of fundamental and applied research in chemistry and interdisciplinary subjects. Crystallizing Ideas - The Role of Chemistry is written for graduates, postgraduates, researchers in industry and academia who have an interest in the fields ranging from fundamental to applied chemistry.
Author: Wai-Kee Li
Publisher: OUP Oxford
ISBN: 0191527149
Category : Science
Languages : en
Pages : 848
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Book Description
This book is a revised and updated English edition of a textbook that has grown out of several years of teaching. The term "inorganic" is used in a broad sense as the book covers the structural chemistry of representative elements (including carbon) in the periodic table, organometallics, coordination polymers, host-guest systems and supramolecular assemblies. Part I of the book reviews the basic bonding theories, including a chapter on computational chemistry. Part II introduces point groups and space groups and their chemical applications. Part III comprises a succinct account of the structural chemistry of the elements in the periodic table. It presents structure and bonding, generalizations of structural trends, crystallographic data, as well as highlights from the recent literature.
