Organometallic Photochemistry

Organometallic Photochemistry PDF Author: Gregory Geoggroy
Publisher: Elsevier
ISBN: 0323140904
Category : Science
Languages : en
Pages : 346

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Book Description
Organometallic Photochemistry explores the photochemical properties of transition-metal organometallic complexes, such as metal carbonyls, olefin complexes, arene complexes, and cyclopentadienyl complexes. Isocyanide complexes, hydride complexes, and alkyl complexes are also covered. This book consists of eight chapters and begins with an overview of organometallic complexes and their electronic structure, along with the principles of photochemistry. The chapters that follow are detailed reviews of photochemical studies organized according to type of organometallic. Each chapter is organized according to the central metal atom and its group in the periodic table. The chapter on metal carbonyl complexes focuses on the excited-state chemistry of compounds, such as vanadium, niobium, chromium, molybdenum, manganese, iron, cobalt, and nickel. The next chapter deals with olefin complexes, such as niobium, chromium, rhenium, rhodium, platinum, and copper. The chapters on arene, cyclopentadienyl, isocyanide, hydride, and alkyl complexes explore topics ranging from bonding and electronic structure to photoreactions, photosubstitution, redox chemistry, homolysis, and decomposition. This text is a valuable resource for photochemists and those who are interested in organometallic photochemistry.

Organometallic Photochemistry

Organometallic Photochemistry PDF Author: Gregory Geoggroy
Publisher: Elsevier
ISBN: 0323140904
Category : Science
Languages : en
Pages : 346

Get Book

Book Description
Organometallic Photochemistry explores the photochemical properties of transition-metal organometallic complexes, such as metal carbonyls, olefin complexes, arene complexes, and cyclopentadienyl complexes. Isocyanide complexes, hydride complexes, and alkyl complexes are also covered. This book consists of eight chapters and begins with an overview of organometallic complexes and their electronic structure, along with the principles of photochemistry. The chapters that follow are detailed reviews of photochemical studies organized according to type of organometallic. Each chapter is organized according to the central metal atom and its group in the periodic table. The chapter on metal carbonyl complexes focuses on the excited-state chemistry of compounds, such as vanadium, niobium, chromium, molybdenum, manganese, iron, cobalt, and nickel. The next chapter deals with olefin complexes, such as niobium, chromium, rhenium, rhodium, platinum, and copper. The chapters on arene, cyclopentadienyl, isocyanide, hydride, and alkyl complexes explore topics ranging from bonding and electronic structure to photoreactions, photosubstitution, redox chemistry, homolysis, and decomposition. This text is a valuable resource for photochemists and those who are interested in organometallic photochemistry.

Inorganic and Organometallic Photochemistry

Inorganic and Organometallic Photochemistry PDF Author: Mark S. Wrighton
Publisher:
ISBN:
Category :
Languages : en
Pages : 0

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Book Description


Organic and Inorganic Photochemistry

Organic and Inorganic Photochemistry PDF Author: V. Ramamurthy
Publisher: CRC Press
ISBN: 9780824701741
Category : Science
Languages : en
Pages : 378

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Book Description
Focusing on complex naturally-occurring and synthetic supramolecular arrays, this work describes the mechanism by which transition metal complexes bind to DNA and how the DNA scaffold modifies the photochemical and photophysical properties to bound complexes. It includes details of photoinduced electron transfer between intercalated molecules, and examines thermally and photochemically induced electron transfer in supramolecular assemblies consisting of inorganic molecular building blocks.

Inorganic and Organometallic Photochemistry

Inorganic and Organometallic Photochemistry PDF Author: Mark S. Wrighton
Publisher:
ISBN: 9780841203983
Category :
Languages : en
Pages : 231

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Book Description


Inorganic and Organometallic Photochemistry

Inorganic and Organometallic Photochemistry PDF Author: Mark S. Wrighton
Publisher:
ISBN: 9780608038650
Category :
Languages : en
Pages : 240

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Book Description


Photosensitization and Photocatalysis Using Inorganic and Organometallic Compounds

Photosensitization and Photocatalysis Using Inorganic and Organometallic Compounds PDF Author: K. Kalyanasundaram
Publisher: Springer Science & Business Media
ISBN: 9401726264
Category : Science
Languages : en
Pages : 475

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Book Description
Photosensitization and photocatalysis refer to processes by which permanent chemical transformations are induced on substrates (organic/inorganic) by radiation to which the substrates themselves are transparent. Such transformations can be highly specific, very efficient, and occur under mild conditions. Herein lies the power of photochemical methods for possible applications in the field of conversion and storage of solar energy. This book provides a recent survey of the progress in this important area in catalysis, with an emphasis on inorganic complexes and organometallic compounds as the key light aborbers. The book is organized in three parts: fundamentals, followed by applications. Discussions cover a wide variety of photosensitized or photocatalyzed reactions: decomposition of water, reduction of CO2 and CO; spectral sensitization in photoelectrochemical cells; transformations (oxidation, reduction, isomerization, hydrogenation, dehydrogenation, carbonylation, etc.) of organics such as alkanes, alkenes, alcohols, etc. In view of the variety of systems (sensitizers, substrates) and the topics covered, the volume is unique in the field of photochemistry and will appeal to academic and industrial researchers in various subdisciplines of chemistry, material science and catalysis.

Inorganic and Organometallic Transition Metal Complexes with Biological Molecules and Living Cells

Inorganic and Organometallic Transition Metal Complexes with Biological Molecules and Living Cells PDF Author: Kenneth Kam-Wing Lo
Publisher: Academic Press
ISBN: 012803887X
Category : Science
Languages : en
Pages : 406

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Book Description
Inorganic and Organometallic Transition Metal Complexes with Biological Molecules and Living Cells provides a complete overview of this important research area that is perfect for both newcomers and expert researchers in the field. Through concise chapters written and edited by esteemed experts, this book brings together a comprehensive treatment of the area previously only available through scattered, lengthy review articles in the literature. Advanced topics of research are covered, with particular focus on recent advances in the biological applications of transition metal complexes, including inorganic medicine, enzyme inhibitors, antiparasital agents, and biological imaging reagents. Geared toward researchers and students who seek an introductory overview of the field, as well as researchers working in advanced areas Focuses on the interactions of inorganic and organometallic transition metal complexes with biological molecules and live cells Foscuses on the fundamentals and their potential therapeutic and diagnostic applications Covers recent biological applications of transition metal complexes, such as anticancer drugs, enzyme inhibitors, bioconjugation agents, chemical biology tools, and bioimaging reagents

Reaction Mechanisms of Inorganic and Organometallic Systems

Reaction Mechanisms of Inorganic and Organometallic Systems PDF Author: Robert B. Jordan
Publisher: Oxford University Press
ISBN: 019971973X
Category : Science
Languages : en
Pages : 532

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Book Description
This third edition retains the general level and scope of earlier editions, but has been substantially updated with over 900 new references covering the literature through 2005, and 140 more pages of text than the previous edition. In addition to the general updating of materials, there is new or greatly expanded coverage of topics such as Curtin-Hammett conditions, pressure effects, metal hydrides and asymmetric hydrogenation catalysts, the inverted electron-transfer region, intervalence electron transfer, photochemistry of metal carbonyls, methyl transferase and nitric oxide synthase. The new chapter on heterogeneous systems introduces the basic background to this industrially important area. The emphasis is on inorganic examples of gas/liquid and gas/liquid/solid systems and methods of determining heterogeneity.

Inorganic and Organometallic Photochemistry:

Inorganic and Organometallic Photochemistry: PDF Author: Mark S. Wrighton
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 231

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Book Description


Elements of Inorganic Photochemistry

Elements of Inorganic Photochemistry PDF Author: G. J. Ferraudi
Publisher: Wiley-Interscience
ISBN:
Category : Science
Languages : en
Pages : 280

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Book Description
This monograph/reference focuses on those subjects that are considered essential to an understanding of inorganic photochemistry. Graduate students with a background in physical chemistry will find that the quantum mechanical treatments related to the principles of spectroscopy and chemical dynamics are readily accessible. And professionals will find that the tabulated data, equations, and general information makes this book an essential complement to the journal literature required in the daily planning of photochemical work. Chapters cover the nature of light and the uncertainty principle, detection of intermediates, elements of inorganic spectroscopy, kinetics of photoluminescence, photoredox reactions, ligand field photochemistry, and elements of organometallic photochemistry. Extensive appendixes cover physical constants and conversion factors for photochemical work, character tables for symmetry groups, vibrational motions, description of the chemical bonding in coordination complexes, charge transfer transitions, and Born cycles related to charge transfer processes.