FREZCHEM2: A Chemical Thermodynamic Model for Electrolyte Solutions at subzero Temperatures

FREZCHEM2: A Chemical Thermodynamic Model for Electrolyte Solutions at subzero Temperatures PDF Author: Giles M. Marion
Publisher: DIANE Publishing
ISBN: 1428913327
Category : Electrolyte solutions
Languages : en
Pages : 44

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FREZCHEM2: A Chemical Thermodynamic Model for Electrolyte Solutions at subzero Temperatures

FREZCHEM2: A Chemical Thermodynamic Model for Electrolyte Solutions at subzero Temperatures PDF Author: Giles M. Marion
Publisher: DIANE Publishing
ISBN: 1428913327
Category : Electrolyte solutions
Languages : en
Pages : 44

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Book Description


FREZCHEM2

FREZCHEM2 PDF Author: Mikhail V. Mironenko
Publisher:
ISBN:
Category : Electrolyte solutions
Languages : en
Pages : 0

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Book Description
This report documents a Fortran version of a chemical thermodynamic model for aqueous electrolyte solutions at subzero temperatures, FREZCHEM2, which is a further development of the FREZCHEM model. The model uses thermodynamic data of Spencer-Moller- Weare that permit the calculation of chemical equilibria in the Na-K-Ca-Mg-Cl-S04-H2O system between -60 and 25 deg. C at atmospheric pressure. It applies the Gibbs energy minimization method for chemical equilibrium computation combined with Pitzer equations for activity coefficients and water activity calculation. phases.

FREZCHEM2 A Chemical Thermodynamic Model for Electrolyte Solutions at Subzero Temperatures

FREZCHEM2 A Chemical Thermodynamic Model for Electrolyte Solutions at Subzero Temperatures PDF Author: Cold Regions Research and Engineering Laboratory (U.S.)
Publisher:
ISBN:
Category : Electrolyte solutions
Languages : en
Pages : 44

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Book Description
This report documents a Fortran version of a chemical thermodynamic model for aqueous electrolyte solutions at subzero temperatures, FREZCHEM2, which is a further development of the FREZCHEM model. The model uses thermodynamic data of Spencer-Moller- Weare that permit the calculation of chemical equilibria in the Na-K-Ca-Mg-Cl-S04-H2O system between -60 and 25 deg. C at atmospheric pressure. It applies the Gibbs energy minimization method for chemical equilibrium computation combined with Pitzer equations for activity coefficients and water activity calculation. phases.

FREZCHEM: A Chemical-Thermodynamic Model for Aqueous Solutions at Subzero Temperatures

FREZCHEM: A Chemical-Thermodynamic Model for Aqueous Solutions at Subzero Temperatures PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 40

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Book Description
This report documents a FORTRAN version of the Spencer-Moller-Weare chemical thermodynamic model for aqueous electrolyte solutions at sub-zero temperatures (FREZCHEM). FREZCHEM is structured to predict the chemical composition and unfrozen water of aqueous solutions between -60 deg and +25 deg C at atmospheric pressure (0.101325 MPa). FREZCHEM includes two reaction pathways: freezing at variable temperature and fixed total water and evaporation at variable water and fixed temperature. Activity coefficients and the activity of water are calculated using the Pitzer equations, which are valid to high solution ionic strengths (approx. 20 mol k-1). Fifteen chloride and sulfate salts of sodium, potassium, calcium, and magnesium are included in the model. Predicted and experimental measurements of solute molalities and the unfrozen water fraction during sea water freezing are in good agreement. At -50 deg C, 0.3 % of sea water remains unfrozen with 99.7% of Na and 95.5% of Cl having precipitated into one of four salts. FREZCHEM should find many applications in physicochemical studies of aqueous solutions and freezing.

FREZCHEM

FREZCHEM PDF Author: Giles M. Marion
Publisher:
ISBN:
Category : Computer simulation
Languages : en
Pages : 35

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Handbook of Aqueous Electrolyte Thermodynamics

Handbook of Aqueous Electrolyte Thermodynamics PDF Author: Joseph F. Zemaitis, Jr.
Publisher: John Wiley & Sons
ISBN: 0816903506
Category : Technology & Engineering
Languages : en
Pages : 883

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Book Description
Expertise in electrolyte systems has become increasingly important in traditional CPI operations, as well as in oil/gas exploration and production. This book is the source for predicting electrolyte systems behavior, an indispensable "do-it-yourself" guide, with a blueprint for formulating predictive mathematical electrolyte models, recommended tabular values to use in these models, and annotated bibliographies. The final chapter is a general recipe for formulating complete predictive models for electrolytes, along with a series of worked illustrative examples. It can serve as a useful research and application tool for the practicing process engineer, and as a textbook for the chemical engineering student.

Handbook of Aqueous Electrolyte Thermodynamics

Handbook of Aqueous Electrolyte Thermodynamics PDF Author: Joseph F. Zemaitis, Jr.
Publisher: John Wiley & Sons
ISBN: 0470938404
Category : Technology & Engineering
Languages : en
Pages : 876

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Book Description
Expertise in electrolyte systems has become increasingly important in traditional CPI operations, as well as in oil/gas exploration and production. This book is the source for predicting electrolyte systems behavior, an indispensable "do-it-yourself" guide, with a blueprint for formulating predictive mathematical electrolyte models, recommended tabular values to use in these models, and annotated bibliographies. The final chapter is a general recipe for formulating complete predictive models for electrolytes, along with a series of worked illustrative examples. It can serve as a useful research and application tool for the practicing process engineer, and as a textbook for the chemical engineering student.

Molecular Thermodynamics of Electrolyte Solutions

Molecular Thermodynamics of Electrolyte Solutions PDF Author: Lloyd L. Lee
Publisher: World Scientific
ISBN: 9812814183
Category : Science
Languages : en
Pages : 264

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Book Description
The introductory textbook provides an update on electrolyte thermodynamics with a molecular perspective. It is eminently suited as an introduction to the solution thermodynamics of ionic mixtures at the undergraduate and graduate level. It is also invaluable for the understanding and design in the engineering of natural gas treating and adsorption refrigeration with electrolytes.

The Quaternary Period in the United States

The Quaternary Period in the United States PDF Author: A.R. Gillespie
Publisher: Elsevier
ISBN: 0080474098
Category : Science
Languages : en
Pages : 595

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Book Description
This book reviews advances in understanding of the past ca. two million years of Earth history - the Quaternary Period - in the United States. It begins with sections on ice and water - as glaciers, permafrost, oceans, rivers, lakes, and aquifers. Six chapters are devoted to the high-latitude Pleistocene ice sheets, to mountain glaciations of the western United States, and to permafrost studies. Other chapters discuss ice-age lakes, caves, sea-level fluctuations, and riverine landscapes. With a chapter on landscape evolution models, the book turns to essays on geologic processes. Two chapters discuss soils and their responses to climate, and wind-blown sediments. Two more describe volcanoes and earthquakes, and the use of Quaternary geology to understand the hazards they pose. The next part of the book is on plants and animals. Five chapters consider the Quaternary history of vegetation in the United States. Other chapters treat forcing functions and vegetation response at different spatial and temporal scales, the role of fire as a catalyst of vegetation change during rapid climate shifts, and the use of tree rings in inferring age and past hydroclimatic conditions. Three chapters address vertebrate paleontology and the extinctions of large mammals at the end of the last glaciation, beetle assemblages and the inferences they permit about past conditions, and the peopling of North America. A final chapter addresses the numerical modeling of Quaternary climates, and the role paleoclimatic studies and climatic modeling has in predicting future response of the Earth's climate system to the changes we have wrought.

Cryosols

Cryosols PDF Author: John Kimble
Publisher: Springer Science & Business Media
ISBN: 3662064294
Category : Nature
Languages : en
Pages : 748

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Book Description
Cryosols – permafrost – occupy a unique part of the earth and have properties greatly different from other soils. They also occur where the greatest impact of global warming is predicted. This is the first book bring together the leading researchers in the area of permafrost soils to produce a review of the geography, cryogenic soil forming processes, ecological processes, classification and use of soils that are affected by permafrost.