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Languages : en
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We combine different wavelengths from an intense high-order harmonics source with variable delay at the focus of a split-mirror interferometer to conduct pump-probe experiments on gas-phase molecules. We report measurements of the time resolution (
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Languages : en
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Book Description
We combine different wavelengths from an intense high-order harmonics source with variable delay at the focus of a split-mirror interferometer to conduct pump-probe experiments on gas-phase molecules. We report measurements of the time resolution (
Author: Thomas K. Allison III
Publisher:
ISBN:
Category :
Languages : en
Pages : 238
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Atoms and molecules have most of their oscillator strength in the vacuum ultraviolet (VUV) and extreme ultraviolet (XUV), between the wavelengths of 200 nm and 30 nm. However, most femtosecond spectroscopy has been restricted to the visible and infrared due to a lack of sufficiently intense VUV and XUV femtosecond light sources. This thesis discusses extensions of pump/probe spectroscopy to the VUV and XUV, and its application to the dynamics of ethylene and oxygen molecules excited at 161 nm. I begin with a detailed discussion of the short wavelength light source used in this work. The source is based on the high order harmonics of a near infrared laser and can deliver> 1010 photons per shot in femtosecond pulses, corresponding to nearly 10 MW peak power in the XUV. Measurements of the harmonic yields as a function of the generation conditions reveal the roles of phase matching and ionization gating in the high order harmonic generation process. Pump/probe measurements are conducted using a unique VUV interferometer, capable of combining two different harmonics at a focus with variable delay. Measurements of VUV multiphoton ionization allows for characterization of the source and the interferometer. In molecules, time resolved measurements of fragment ion yields reveal the femtosecond dynamics of the system. The range of wavelengths available for pump and probe allows the dynamics to be followed from photo-excitation all the way to dissociation without detection window effects. The dynamics in ethylene upon [pi] 2![pi]* excitation are protypical of larger molecules and have thus served as an important test case for advanced ab initio molecular dynamics theories. Femtosecond measurements to date, however, have been extremely lacking. In the present work, through a series of pump probe experiments using VUV and XUV pulses, time scales for the non-adiabatic relaxation of the electronic excitation, hydrogen migration across the double bond, and H2 molecule elimination are measured and compared to theory. In the simpler oxygen molecule, excitation in the Schuman-Runge continuum leads to direct dissociation along the B 3[Sigma]u- potential energy curve. The time resolved photoion spectra show that the total photoionization cross section of the molecule resembles two oxygen atoms within 50 fs after excitation.
Author: Paul Froemel
Publisher:
ISBN:
Category :
Languages : en
Pages : 38
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Author: Peter Hannaford
Publisher: Springer Science & Business Media
ISBN: 9780387232935
Category : Technology & Engineering
Languages : en
Pages : 368
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The embryonic development of femtoscience stems from advances made in the generation of ultrashort laser pulses. Beginning with mode-locking of glass lasers in the 1960s, the development of dye lasers brought the pulse width down from picoseconds to femtoseconds. The breakthrough in solid state laser pulse generation provided the current reliable table-top laser systems capable of average power of about 1 watt, and peak power density of easily watts per square centimeter, with pulse widths in the range of four to eight femtoseconds. Pulses with peak power density reaching watts per square centimeter have been achieved in laboratory settings and, more recently, pulses of sub-femtosecond duration have been successfully generated. As concepts and methodologies have evolved over the past two decades, the realm of ultrafast science has become vast and exciting and has impacted many areas of chemistry, biology and physics, and other fields such as materials science, electrical engineering, and optical communication. In molecular science the explosive growth of this research is for fundamental reasons. In femtochemistry and femtobiology chemical bonds form and break on the femtosecond time scale, and on this scale of time we can freeze the transition states at configurations never before seen. Even for n- reactive physical changes one is observing the most elementary of molecular processes. On a time scale shorter than the vibrational and rotational periods the ensemble behaves coherently as a single-molecule trajectory.
Author: Stefan Ulonska
Publisher:
ISBN:
Category :
Languages : en
Pages : 96
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Author: E. Garmire
Publisher: Springer Science & Business Media
ISBN: 1461537266
Category : Technology & Engineering
Languages : en
Pages : 431
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The Fourth USA-USSR Symposium. on The Physics of Optical Phenomena and Their Use as Probes of Matter, was held in Irvine, California, January 23-27, 1990. Participating in the Symposium were 22 scientists from the USSR and 29 from the USA. In addition, to provide an international dimension to this Symposium without, however, compromising significantly its essentially binational character, 7 non-US and non-USSR scientists were invited to take part in it. The present volume is the proceedings of that Symposium, and contains all manuscripts received prior to August 1, 1990, representing. scientific contributions presented. A few manuscripts were not received, but for completeness the corresponding abstract is printed.. Three previous USA/USSR Binational Symposia on related topics have been held, viz. "Theory of Light Scattering in Condensed Matter" (Moscow, 1975), "Light Scattering in Solids" (New York, 1979), and "Laser Optics of Condensed Matter" (Leningrad, 1987). These meetings were evaluated by the participants as highly successful and provided invaluable oppor tunities for researchers to exchange information and to initiate colla borative work which led to research visits by US physicist to Soviet laboratories, and vice versa, and which continue to the present day.
Author: Jun Ye
Publisher: Springer Science & Business Media
ISBN: 0387237917
Category : Science
Languages : en
Pages : 373
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Over the last few years, there has been a convergence between the fields of ultrafast science, nonlinear optics, optical frequency metrology, and precision laser spectroscopy. These fields have been developing largely independently since the birth of the laser, reaching remarkable levels of performance. On the ultrafast frontier, pulses of only a few cycles long have been produced, while in optical spectroscopy, the precision and resolution have reached one part in Although these two achievements appear to be completely disconnected, advances in nonlinear optics provided the essential link between them. The resulting convergence has enabled unprecedented advances in the control of the electric field of the pulses produced by femtosecond mode-locked lasers. The corresponding spectrum consists of a comb of sharp spectral lines with well-defined frequencies. These new techniques and capabilities are generally known as “femtosecond comb technology. ” They have had dramatic impact on the diverse fields of precision measurement and extreme nonlinear optical physics. The historical background for these developments is provided in the Foreword by two of the pioneers of laser spectroscopy, John Hall and Theodor Hänsch. Indeed the developments described in this book were foreshadowed by Hänsch’s early work in the 1970s when he used picosecond pulses to demonstrate the connection between the time and frequency domains in laser spectroscopy. This work complemented the advances in precision laser stabilization developed by Hall.
Author: Felix Paul Sturm
Publisher:
ISBN:
Category :
Languages : de
Pages :
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Author: Karsten König
Publisher: Walter de Gruyter GmbH & Co KG
ISBN: 3110383500
Category : Science
Languages : en
Pages : 360
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Nanostructuring of materials is a task at the heart of many modern disciplines in mechanical engineering, as well as optics, electronics, and the life sciences. This book includes an introduction to the relevant nonlinear optical processes associated with very short laser pulses for the generation of structures far below the classical optical diffraction limit of about 200 nanometers as well as coverage of state-of-the-art technical and biomedical applications. These applications include silicon and glass wafer processing, production of nanowires, laser transfection and cell reprogramming, optical cleaning, surface treatments of implants, nanowires, 3D nanoprinting, STED lithography, friction modification, and integrated optics. The book highlights also the use of modern femtosecond laser microscopes and nanoscopes as novel nanoprocessing tools.
Author: Roelof Theodoor Zinkstok
Publisher:
ISBN: 9789090226194
Category :
Languages : en
Pages : 200
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