Exciton Dynamics in Molecular Crystals and Aggregates

Exciton Dynamics in Molecular Crystals and Aggregates PDF Author:
Publisher: Springer
ISBN: 3540390685
Category : Science
Languages : en
Pages : 233

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Book Description

Exciton Dynamics in Molecular Crystals and Aggregates

Exciton Dynamics in Molecular Crystals and Aggregates PDF Author:
Publisher: Springer
ISBN: 3540390685
Category : Science
Languages : en
Pages : 233

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Book Description


Exciton Dynamics in Molecular Crystals and Aggregates

Exciton Dynamics in Molecular Crystals and Aggregates PDF Author:
Publisher: Springer
ISBN: 9783662157749
Category : Science
Languages : en
Pages : 228

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Book Description


Excitations in Organic Solids

Excitations in Organic Solids PDF Author: Vladimir M. Agranovich
Publisher: OUP Oxford
ISBN: 0191552917
Category : Science
Languages : en
Pages : 512

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Book Description
During the last decade our expertise in nanotechnology has advanced considerably. The possibility of incorporating in the same nanostructure different organic and inorganic materials has opened up a promising field of research, and has greatly increased the interest in the study of properties of excitations in organic materials. In this book not only the fundamentals of Frenkel exciton and polariton theory are described, but also the electronic excitations and electronic energy transfers in quantum wells, quantum wires and quantum dots, at surfaces, at interfaces, in thin films, in multilayers, and in microcavities. Among the new topics in the book are those devoted to the optics of hybrid Frenkel-Wannier-Mott excitons in nanostructures, polaritons in organic microcavities including hybrid organic-inorganic microcavities, new concepts for organic light emitting devices, the mixing of Frenkel and charge-transfer excitons in organic quasi one-dimensional crystals, excitons and polaritons in one and two-dimensional crystals, surface electronic excitations, optical biphonons, and Fermi resonances by polaritons. All new phenomena described in the book are illustrated by available experimental observations. The book will be useful for scientists working in the field of photophysics and photochemistry of organic solids (for example, organic light-emitting devices and solar cells), and for students who are entering this field. It is partly based on a book by the author written in 1968 - "Theory of Excitons" - in Russian. However the new book includes only 5 chapters from this version, all of which have been updated. The 10 new chapters contain discussions of new phenomena, their theory and their experimental observations.

Unconventional Photoactive Solids

Unconventional Photoactive Solids PDF Author: Harvey Scher
Publisher: Springer Science & Business Media
ISBN: 1461307279
Category : Science
Languages : en
Pages : 253

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Book Description
The papers in this volume were presented at the Second International Conference on Unconventional Photoactive Solids held at the R&D Center of BP America September 9-12, 1985. It was part of an on-going series of conferences with the main aim of stressing the Interrelationship of solid state physics and solid state chemistry. The choice of topics covered a broad range of light-Induced solid state phenomena with particular emphasis on novel materials and/or novel phenomena. Organic solids, in particular, were emphasized as they are a natural meeting point of solid state physics and chemistry. A general trend In solid state physics Is to more complex materials (e.g. nonequilibrium glassy films, complicated unit cells, extended molecular building blocks, etc.). This trend necessitates the closer interaction between physicists and chemists. This conference reflects this trend quite dramatically. It is a new grouping together of a mix of materials, people and experimental approaches. A typical new theme pulling together this new mix can be seen in Part I. Fractals in Disordered Media. A variety of disordered media give rise to unusual temporal patterns of diffusion and reactions. The more familiar spatial patterns of self-similarity are discussed in the first article by M.F. Barnsley. Another topic pulling together a diverse group of scientists is covered in Part II. Spectral Hole-Burning. A number of leaders in this field are represented In these three papers.

Photosynthetic Excitons

Photosynthetic Excitons PDF Author: Herbert van Amerongen
Publisher: World Scientific
ISBN: 9814496855
Category : Science
Languages : en
Pages : 604

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Book Description
Excitons are considered as the basic concept used by describing the spectral properties of photosynthetic pigment-protein complexes and excitation dynamics in photosynthetic light-harvesting antenna and reaction centers. Following the recently obtained structures of a variety of photosynthetic pigment-protein complexes from plants and bacteria our interest in understanding the relation between structure, function and spectroscopy has strongly increased. These data demonstrate a short interpigment distance (of the order of 1 nm or even smaller) and/or a highly symmetric (ring-like) arrangement of pigment molecules in peripheral light-harvesting complexes of photosynthetic bacteria. Books which were devoted to the exciton problem so far mainly considered the spectral properties of molecular crystals. However, the small size of these pigment aggregates in the pigment-protein complexes as well as the role of the protein, which is responsible for the structural arrangement of the complex, clearly will have a dramatic influence on the pigment spectra and exciton dynamics. All these aspects of the problem are considered in this book. Exciton theory is mainly considered for small molecular aggregates (dimers, ring-like structures etc.). Together with the theoretical description of the classical conceptual approach, which mainly deals with polarization properties of the absorption and fluorescence spectra, the nonlinear femtosecond spectroscopy which is widely used for investigations now is also discussed. A large part of the book demonstrates the excitonic effects in a multitude of photosynthetic pigment-protein complexes and how we can understand these properties on the basis of the exciton concept. Contents:Introduction: Structural Organization, Spectral Properties and Excitation Energy Transfer in PhotosynthesisThe Exciton ConceptSome Optical Properties of the Excitonically Coupled DimerMixing with Higher Excited StatesSpectral Shapes: Homogeneous and Inhomogeneous BroadeningSpectroscopy of Excitons in Molecular Crystals and AggregatesExcitonic Interactions in Photosynthetic Systems: Spectroscopic EvidenceExciton DynamicsExciton Dynamics in Different Antenna Complexes. Coherence and IncoherenceMigration of Localized Excitations: Förster Excitation Energy Transfer and Trapping by Reaction CentersExciton Energy Transfer and Trapping. ExperimentsNonlinear Annihilation of Excitons. TheoryNonlinear Annihilation of Excitons. ExperimentalNonlinear Spectroscopy Readership: Students and researchers in biophysics, condensed matter/solid state physics, atomic & molecular physics and biochemistry. keywords:Photosynthesis;Excitons;Biophysics;Excitation Energy Transfer and Trapping;Spectroscopy;Picosecond Spectroscopy;Femtosecond Spectroscopy;Polarized Spectroscopy;Exciton Dynamics;Optical Properties of Photosythetic Complexes;Homogeneous and Inhomogeneous;Broadening;Coherence and Incoherence;Nonlinear Annihilation of Excitons;Nonlinear Spectroscopy;Light Harvesting “… this is a unique book … The price is quite reasonable, and the book should not only be on the shelves of institutional libraries, but also in many private libraries and offices, where it will serve as a standard reference work for many years to come.” Photosynthesis Research

Large-Scale Molecular Systems

Large-Scale Molecular Systems PDF Author: Werner Gans
Publisher: Springer Science & Business Media
ISBN: 1468459406
Category : Science
Languages : en
Pages : 588

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Book Description
This NATO Advanced Study Institute centered on large-scale molecular systems: Quantum mechanics, although providing a general framework for the description of matter, is not easily applicable to many concrete systems of interest; classical statistical methods, on the other hand, allow only a partial picture of the behaviour of large systems. The aim of the ASI was to present both aspects of the subject matter and to foster interaction between the scientists working in these important areas of theoretical physics and theoretical chemistry. The quantum-mechanical part was mostly based on the operator-algebraic formulation of quantum mechanics and comprised quantum statistics of infinite systems with special em phasis on macroscopic observables, equilibrium conditions, irreversibility on the one hand, symmetry breaking for molecules in the radiation field and macroscopic quantum phenomena in the theory of superconductivity (BCS-theory) on the other hand. In addition, phase-space methods for many-body systems were also presented. Statistical physics was the main topic in the other lectures of the School; much emphasis was put on the statistical features of macros copic ("large") systems, the lectures dealt with mass and energy transport im polymers, in gels and in microemulsions, with aggregation and growth phenomena, with relaxation in complex, correlated systems, with conduction and optical properties of polymers, and with the means of describing disordered systems, above all fractals and related hierarchical models.

Energy Transfer Processes in Condensed Matter

Energy Transfer Processes in Condensed Matter PDF Author: Baldassare Dibartolo
Publisher: Springer Science & Business Media
ISBN: 1461324076
Category : Science
Languages : en
Pages : 712

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Book Description
This book presents an account of the NATO Advanced Study Institute on "Energy Transfer Processes in Condensed Matter", held in Erice, Italy, from June 16 to June 30, 1983. This meeting was organized by the International School of Atomic and Molecular Spectroscopy of the "Ettore Majorana" Centre for Scientific Culture. The objective of the Institute was to present a comprehensive treatment of the basic mechanisms by which electronic excitation energy, initially localized in a particular constituent or region of a condensed material, transfers itself to the other parts of the system. Energy transfer processes are important to such varied .fields as spectroscopy, lasers, phosphor technology, artificial solar energy conversion, and photobiology. This meeting was the first encounter of this sort entirely dedicated to this important topic. A total of 65 participants came from 47 laboratories and 16 nations (Belgium, Czechoslovakia, F.R. of Germany, France, Greece, India, Ireland, Israel, Italy, The Netherlands, Poland, Portugal, Switzerland, Turkey, United Kingdom, and the United States of A America). The secretaries of the course were: Ms. Aliki Karipidou for the scientific aspects and Mr. Massimo Minella for the admini strative aspects of the meeting.

Electronic Excitations in Organic Based Nanostructures

Electronic Excitations in Organic Based Nanostructures PDF Author:
Publisher: Elsevier
ISBN: 9780080519210
Category : Technology & Engineering
Languages : en
Pages : 508

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Book Description
The first book devoted to a systematic consideration of electronic excitations and electronic energy transfer in organic crystalline multilayers and organics based nanostructures(quantum wells, quantum wires, quantum dots, microcavities). The ingenious combination of organic with inorganic materials in one and the same hybrid structure is shown to give qualitatively new opto-electronic phenomena, potentially important for applications in nonlinear optics, light emitting devices, photovoltaic cells, lasers and so on. The book will be useful not only for physicists but also for chemists and biologists.To help the nonspecialist reader, three Chapters which contain a tutorial and updated introduction to the physics of electronic excitations in organic and inorganic solids have been included. * hybrid Frenkel-Wannier-Mott excitons * microcavities with crystalline and disordered organics * electronic excitation at donor-acceptor interfaces * cold photoconductivity at donor-acceptor interface * cummulative photovoltage * Feorster transfer energy in microcavity * New concepts for LEDs

Dynamics of Molecular Excitons

Dynamics of Molecular Excitons PDF Author: Seogjoo J. Jang
Publisher: Elsevier
ISBN: 0081023367
Category : Science
Languages : en
Pages : 242

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Book Description
Dynamics of Molecular Excitons provides a comprehensive, but concise description of major theories on the dynamics of molecular excitons, intended to serve as a self-contained resource on the topic. Designed to help those new to this area gain proficiency in this field, experts will also find the book useful in developing a deeper understanding of the subject. The starting point of the book is the standard microscopic definition of molecular Hamiltonians presented in commonly accepted modern quantum mechanical notations. Major assumptions and approximations involved in constructing Frenkel-type exciton Hamiltonians, which are well established, but are often hidden under arcane notations and approximations of old publications, are presented in detail. This will help quantum chemists understand the major assumptions involved in the definition of commonly used exciton models. Rate theories of exciton dynamics, such as Förster and Dexter theories and their modern generalizations, are presented in a unified and detailed manner. In addition, important aspects that are often neglected, such as local field effect and the role of fluctuating environments, are discussed. Various quantum dynamics methods allowing coherent dynamics of excitons are presented in a systematic manner in the context of quantum master equations or path integral formalisms. The author also provides a detailed theoretical explanation for the major spectroscopic techniques probing exciton dynamics, including modern two-dimensional electronic spectroscopy, with a critical assessment of the implications of these spectroscopic measurements. Finally, the book includes a brief overview of major applications including an explanation of organic photovoltaic materials and natural light harvesting complexes. Covers major theories of exciton dynamics in a consciously concise and easily readable way Bridges the gap between quantum dynamics working with phenomenological exciton Hamiltonian and quantum chemistry construct reliable models amenable for dynamics calculations from ab initio calculations Explores modern nonlinear electronic spectroscopy techniques to probe exciton dynamics, showing how it is applied

Advances in Spectroscopy: Molecules to Materials

Advances in Spectroscopy: Molecules to Materials PDF Author: Dheeraj Kumar Singh
Publisher: Springer Nature
ISBN: 9811502021
Category : Science
Languages : en
Pages : 454

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Book Description
This book presents and discusses recent developments in the broad field of spectroscopy, providing the reader with an updated overview. The main objective is to introduce them to recent innovations and current trends in spectroscopy applied to molecules and materials. The book also brings together experimentalists and theoreticians to highlight the multidimensional aspects of spectroscopy and discuss the latest issues. Accordingly, it provides insights not only into the general goals of spectroscopy, but also into how the various spectroscopic techniques represent a toolbox that can be used to gain a more detailed understanding of molecular systems and complex chemical problems. Besides technical aspects, basic theoretical interpretations of spectroscopic results are also presented. The spectroscopy techniques discussed include UV-visible absorption spectroscopy, Raman spectroscopy, IR absorption spectroscopy, fluorescence spectroscopy, and time-resolved spectroscopy. In turn, basic tools like lasers and theoretical modeling approaches are also presented. Lastly, applications for the characterization of fundamental properties of molecules (environmental aspects, biomolecules, pharmaceutical drugs, hazardous molecules, etc.) and materials (nanomaterials, nuclear chemistry materials, biomaterials, etc.) are discussed. Given its scope, the book offers a valuable resource for researchers from various branches of science, and presents new techniques that can be applied to their specific problems.