Electrophilic Coordination Chemistry of Group 9 and 10 Perfluoroalkyl Phosphine Transition Metal Complexes PDF Download
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Author: Justin M. Hoerter
Publisher:
ISBN:
Category : Complex compounds
Languages : en
Pages : 158
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Author: Justin M. Hoerter
Publisher:
ISBN:
Category : Complex compounds
Languages : en
Pages : 158
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Author: Maravanji S. Balakrishna
Publisher: Elsevier
ISBN: 0128156945
Category : Science
Languages : en
Pages : 445
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Book Description
Copper(I) Complexes of Phosphines, Functionalized Phosphines and Phosphorus Heterocycles is a comprehensive guide to one of the most widely used and extensively studied metals: copper. The numerous practical applications of copper compounds are discussed, including homogeneous and heterogeneous catalysis and their use as fungicides, pesticides, pigments for paints, resins and glasses, and in high-temperature superconductors. The remarkable structural flexibility of simple copper(I) complexes, such as cuprous halides is covered, including numerous structural motifs that, when combined with different ligand systems, exhibit linear, trigonal planar or tetrahedral geometries. This work is an essential reference for inorganic and coordination chemists, as well as researchers working on catalysis, anticancer reagents, luminescence, fluorescence and photophysical aspects. Discusses the properties of copper and similarities to noble metals, such as their corrosion resistance, high thermal and electrical conductivity and rich coordination chemistry Includes the copper(I) coordination chemistry of tertiary phosphines, bisphosphines and phosphines containing other donor atoms and their potential application in catalysis, biosystems and photochemical areas Features a discussion of the rich photochemistry exhibited by some mixed-ligand copper(I) complexes (phosphines with heteroaromatic ligands) which can exhibit coprophilic interactions, photoluminescence and thermochromic properties
Author: Aziza Ahmida
Publisher:
ISBN:
Category :
Languages : en
Pages : 162
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Author: J. A. McCleverty
Publisher: Newnes
ISBN: 0080913164
Category : Science
Languages : en
Pages : 11845
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Book Description
Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.
Author: Charles Andrew McAuliffe
Publisher: Elsevier Science & Technology
ISBN:
Category : Complex compounds
Languages : en
Pages : 568
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Author: Paul S. Pregosin
Publisher:
ISBN:
Category : Complex compounds
Languages : en
Pages : 156
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Author:
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 768
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Author: Aziza Ahmida
Publisher:
ISBN:
Category :
Languages : en
Pages : 162
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Author: R. B. King
Publisher:
ISBN:
Category :
Languages : en
Pages : 33
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Book Description
The base-catalyzed addition of phosphorus-hydrogen and arsenic-hydrogen bonds to the carbon-carbon multiple bonds in vinylphosphines and ethynylphosphines provides a useful new method for the synthesis of novel polytertiary phosphines and phosphine-arsines. Using this method the authors have prepared in large quantities and studied the coordination chemistry of the tritertiary phosphine ((C6H5)2PCH2CH2)2PC6H5, the two isomeric tetratertiary phosphines (C6H5)2PCH2CH2P(C6H5)CH2CH2P(C6H5)CH2CH2P(C6H5)2 and ((C6H5)2PCH2CH2)3P, and the hexatertiary phosphine ((C6H5)2PCH2CH2)2PCH2CH2P(CH2CH2P(C6H5)2)2. This preparative method also provides convenient syntheses of the mixed phosphine-arsines as (C6H5)2PCH2CH2As(C6H5)2. A similar base-catalyzed addition of (C6H5)2EH (E = P or As) to vinyl isocyanide gives the novel isocyanide derivatives (C6H5)2ECH2CH2NC (E = P or As). However, base-catalyzed addition of C6H5PH2 to vinyl isocyanide results in 1,4-addition to give the new phosphorus-carbon-nitrogen heterocycle 1-phenyl-4,5-dihydro-3-azaphosphole. This report also describes transition metal complexes of the ligands (C6H5)2PCCC6H5, (C6H5)2PCH2CCCH2P(C6H5)2, ((CH3)2N)3E (E = P or As), and (p-(CH3)2NC6H4)nP(C6H5)(3-n) (n =1, 2, and 3). (Author).
Author: Stephen Johnson (Leeds Ph.D., Chemistry, 1976.)
Publisher:
ISBN:
Category :
Languages : en
Pages : 382
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