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Author: Sadhan Adhikari
Publisher: Academic Press
ISBN: 0323140718
Category : Technology & Engineering
Languages : en
Pages : 509
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Book Description
Dynamical Collision Theory and Its Applications reviews some of the powerful methods that have evolved for calculating the predictions of dynamical collision theory. Topics range from scattering theory to potential scattering, three- and four-particle scattering, multiparticle scattering, many-particle Lippmann-Schwinger equations, and the connected-kernel approach. This book is comprised of nine chapters; the first of which introduces the reader to the quantum theory of scattering. This topic is followed by a discussion on two-particle potential scattering and various methods for calculating off-shell two-body amplitudes as well as approximating them by finite-rank forms. The next chapters focus on the interpretation and applicability of the multichannel, multiparticle Lippmann-Schwinger equations, along with the known N-particle connected-kernel integral equations and their physical predictions. Descriptions of contemporary field-theoretical and relativistic approaches, such as the Dirac phenomenology for intermediate energy nucleon-nucleus scattering, are included. The singularity structure of multiparticle amplitudes and the associated dispersion-relation techniques are also considered. This book concludes by describing the relationship between the conventional (optical potentials, multiple-scattering theories, and the coupled-reaction channel and resonating-group methods) and the few-body approaches. This text is primarily intended for chemists, physicists, and graduate students interested in general scattering theory; intermediate and low-energy hadron and nuclear physics; atomic and molecular physics; statistical mechanics; and physical and quantum chemistry. There are a number of topics in this book that will be interesting to both mathematicians and particle physicists, as well as advanced graduate students in courses that involve collision theory.
Author: Sadhan Adhikari
Publisher: Academic Press
ISBN: 0323140718
Category : Technology & Engineering
Languages : en
Pages : 509
Get Book
Book Description
Dynamical Collision Theory and Its Applications reviews some of the powerful methods that have evolved for calculating the predictions of dynamical collision theory. Topics range from scattering theory to potential scattering, three- and four-particle scattering, multiparticle scattering, many-particle Lippmann-Schwinger equations, and the connected-kernel approach. This book is comprised of nine chapters; the first of which introduces the reader to the quantum theory of scattering. This topic is followed by a discussion on two-particle potential scattering and various methods for calculating off-shell two-body amplitudes as well as approximating them by finite-rank forms. The next chapters focus on the interpretation and applicability of the multichannel, multiparticle Lippmann-Schwinger equations, along with the known N-particle connected-kernel integral equations and their physical predictions. Descriptions of contemporary field-theoretical and relativistic approaches, such as the Dirac phenomenology for intermediate energy nucleon-nucleus scattering, are included. The singularity structure of multiparticle amplitudes and the associated dispersion-relation techniques are also considered. This book concludes by describing the relationship between the conventional (optical potentials, multiple-scattering theories, and the coupled-reaction channel and resonating-group methods) and the few-body approaches. This text is primarily intended for chemists, physicists, and graduate students interested in general scattering theory; intermediate and low-energy hadron and nuclear physics; atomic and molecular physics; statistical mechanics; and physical and quantum chemistry. There are a number of topics in this book that will be interesting to both mathematicians and particle physicists, as well as advanced graduate students in courses that involve collision theory.
Author: Mandeep Dalal
Publisher: Dalal Institute
ISBN: 8193872010
Category : Science
Languages : en
Pages : 432
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Book Description
An advanced-level textbook of physical chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Physical Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Quantum Mechanics – I: Postulates of quantum mechanics; Derivation of Schrodinger wave equation; Max-Born interpretation of wave functions; The Heisenberg’s uncertainty principle; Quantum mechanical operators and their commutation relations; Hermitian operators (elementary ideas, quantum mechanical operator for linear momentum, angular momentum and energy as Hermition operator); The average value of the square of Hermitian operators; Commuting operators and uncertainty principle(x & p; E & t); Schrodinger wave equation for a particle in one dimensional box; Evaluation of average position, average momentum and determination of uncertainty in position and momentum and hence Heisenberg’s uncertainty principle; Pictorial representation of the wave equation of a particle in one dimensional box and its influence on the kinetic energy of the particle in each successive quantum level; Lowest energy of the particle. Chapter 2. Thermodynamics – I: Brief resume of first and second Law of thermodynamics; Entropy changes in reversible and irreversible processes; Variation of entropy with temperature, pressure and volume; Entropy concept as a measure of unavailable energy and criteria for the spontaneity of reaction; Free energy, enthalpy functions and their significance, criteria for spontaneity of a process; Partial molar quantities (free energy, volume, heat concept); Gibb’s-Duhem equation. Chapter 3. Chemical Dynamics – I: Effect of temperature on reaction rates; Rate law for opposing reactions of Ist order and IInd order; Rate law for consecutive & parallel reactions of Ist order reactions; Collision theory of reaction rates and its limitations; Steric factor; Activated complex theory; Ionic reactions: single and double sphere models; Influence of solvent and ionic strength; The comparison of collision and activated complex theory. Chapter 4. Electrochemistry – I: Ion-Ion Interactions: The Debye-Huckel theory of ion- ion interactions; Potential and excess charge density as a function of distance from the central ion; Debye Huckel reciprocal length; Ionic cloud and its contribution to the total potential; Debye - Huckel limiting law of activity coefficients and its limitations; Ion-size effect on potential; Ion-size parameter and the theoretical mean-activity coefficient in the case of ionic clouds with finite-sized ions; Debye - Huckel-Onsager treatment for aqueous solutions and its limitations; Debye-Huckel-Onsager theory for non-aqueous solutions; The solvent effect on the mobality at infinite dilution; Equivalent conductivity (Λ) vs. concentration c 1/2 as a function of the solvent; Effect of ion association upon conductivity (Debye- Huckel - Bjerrum equation). Chapter 5. Quantum Mechanics – II: Schrodinger wave equation for a particle in a three dimensional box; The concept of degeneracy among energy levels for a particle in three dimensional box; Schrodinger wave equation for a linear harmonic oscillator & its solution by polynomial method; Zero point energy of a particle possessing harmonic motion and its consequence; Schrodinger wave equation for three dimensional Rigid rotator; Energy of rigid rotator; Space quantization; Schrodinger wave equation for hydrogen atom, separation of variable in polar spherical coordinates and its solution; Principle, azimuthal and magnetic quantum numbers and the magnitude of their values; Probability distribution function; Radial distribution function; Shape of atomic orbitals (s,p & d). Chapter 6. Thermodynamics – II: Classius-Clayperon equation; Law of mass action and its thermodynamic derivation; Third law of thermodynamics (Nernest heat theorem, determination of absolute entropy, unattainability of absolute zero) and its limitation; Phase diagram for two completely miscible components systems; Eutectic systems, Calculation of eutectic point; Systems forming solid compounds Ax By with congruent and incongruent melting points; Phase diagram and thermodynamic treatment of solid solutions. Chapter 7. Chemical Dynamics – II: Chain reactions: hydrogen-bromine reaction, pyrolysis of acetaldehyde, decomposition of ethane; Photochemical reactions (hydrogen - bromine & hydrogen -chlorine reactions); General treatment of chain reactions (ortho-para hydrogen conversion and hydrogen - bromine reactions); Apparent activation energy of chain reactions, Chain length; Rice-Herzfeld mechanism of organic molecules decomposition(acetaldehyde); Branching chain reactions and explosions ( H2-O2 reaction); Kinetics of (one intermediate) enzymatic reaction : Michaelis-Menton treatment; Evaluation of Michaelis 's constant for enzyme-substrate binding by Lineweaver-Burk plot and Eadie-Hofstae methods; Competitive and non-competitive inhibition. Chapter 8. Electrochemistry – II: Ion Transport in Solutions: Ionic movement under the influence of an electric field; Mobility of ions; Ionic drift velocity and its relation with current density; Einstein relation between the absolute mobility and diffusion coefficient; The Stokes- Einstein relation; The Nernst -Einstein equation; Walden’s rule; The Rate-process approach to ionic migration; The Rate process equation for equivalent conductivity; Total driving force for ionic transport, Nernst - Planck Flux equation; Ionic drift and diffusion potential; the Onsager phenomenological equations; The basic equation for the diffusion; Planck-Henderson equation for the diffusion potential.
Author: George C. Schatz
Publisher: Courier Corporation
ISBN: 0486136728
Category : Science
Languages : en
Pages : 384
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Book Description
Advanced graduate-level text looks at symmetry, rotations, and angular momentum addition; occupation number representations; and scattering theory. Uses concepts to develop basic theories of chemical reaction rates. Problems and answers.
Author: Marvin L. Goldberger
Publisher: Courier Corporation
ISBN: 0486435075
Category : Science
Languages : en
Pages : 930
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Book Description
A systematic description of the basic principles of collision theory, this graduate-level text presents a detailed examination of scattering processes and formal scattering theory, the two-body problem with central forces, scattering by noncentral forces, lifetime and decay of virtual states, an introduction to dispersion theory, and more. 1964 edition.
Author: Petr Carsky
Publisher: CRC Press
ISBN: 1439839115
Category : Science
Languages : en
Pages : 311
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Book Description
Since the turn of the 21st century, the field of electron molecule collisions has undergone a renaissance. The importance of such collisions in applications from radiation chemistry to astrochemistry has flowered, and their role in industrial processes such as plasma technology and lighting are vital to the advancement of next generation devices. F
Author: Takeshi Kodama
Publisher: World Scientific
ISBN: 9814551627
Category :
Languages : en
Pages : 422
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Book Description
This book contains invited review papers and short notes presented at the International Conference on Physics, Chemistry and Application of Nanostructures (Nanomeeting 2003).
Author: Steven Karataglidis
Publisher: Springer
ISBN: 3030210707
Category : Science
Languages : en
Pages : 253
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Book Description
This book highlights a major advance in low-energy scattering theory: the Multi-Channel Algebraic Scattering (MCAS) theory, which represents an attempt to unify structure and reaction theory. It solves the Lippmann–Schwinger equations for low-energy nucleon-nucleus and alpha-nucleus scattering in momentum space, allowing both the bound and scattering states in the compound nucleus formed to be described. Results of various cases are presented and discussed.
Author: Sigfrido Boffi
Publisher: World Scientific
ISBN: 981454793X
Category :
Languages : en
Pages : 666
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Book Description
This book focuses on the latest theoretical and experimental results and future perspectives regarding electromagnetic and hadronic physics at intermediate energies. Nucleon form factors and spin structure functions, deep-inelastic scattering, excited baryons and mesons, and correlations in nuclei are discussed. Many new results and the scientific programmes of the different laboratories in Europe and North America are also presented. A special section is devoted to relativistic approaches to hadrons and nuclei at intermediate energies.
Author: Danilo Babusci
Publisher: World Scientific
ISBN: 9811201595
Category : Science
Languages : en
Pages : 478
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Book Description
The book covers different aspects of mathematical methods for Physics. It is designed for graduate courses but a part of it can also be used by undergraduate students. The leitmotiv of the book is the search for a common mathematical framework for a wide class of apparently disparate physical phenomena. An important role, within this respect, is provided by a nonconventional formulation of special functions and polynomials. The proposed methods simplify the understanding of the relevant technicalities and yield a unifying view to their applications in Physics as well as other branches of science.The chapters are not organized through the mathematical study of specific problems in Physics, rather they are suggested by the formalism itself. For example, it is shown how the matrix formalism is useful to treat ray Optics, atomic systems evolution, QED, QCD and Feynman diagrams. The methods presented here are simple but rigorous. They allow a fairly substantive tool of analysis for a variety of topics and are useful for beginners as well as the more experienced researchers.
Author: Bernard Becker
Publisher: Springer Science & Business Media
ISBN: 3709193524
Category : Science
Languages : en
Pages : 503
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Book Description
It is apparent from the history of science, that few-body problems have an interdis ciplinary character. Newton, after solving the two-body problem so brilliantly, tried his hand at the Sun-Earth-Moon system. Here he failed in two respects: neither was he able to compute the motion of the moon accurately, nor did he understand the reason for that. It took a long time to understand the fundamental importance of Newton's failure, and only Poincare realised what was the fundamental difficulty in Newtons programme. Nowadays, the term deterministic chaos is associated with this problem. The deep insights of Poincare were neglected by the founding fathers of Quantum Physics. Thus history was repeated by Bohr and his students. After quantising the hydrogen atom, they soon found that the textbook case of a three-body problem in atomic physics, the 3He-atom, did not yield to the Bohr-Sommerfeld quantisation methods. Only these days do people realise what precisely were the difficulties connected to this semi classical way of treating quantum systems. Our field, as we know it today, began in principle in the early 1950's, when Watson sketched the outlines of three-body scattering theory. Mathematical rigour was achieved by Faddeev and thereafter, at the beginning of the 1960's, the quantum three-body prob lem, at least as far as short-range forces were concerned, w&s tamed. In the years that followed, through the work of others, who first applied Faddeev's methods, but later added new techniques, the three-and four-body problems became fully housebroken.
