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Author: Jason Tolentino
Publisher:
ISBN: 9781339124421
Category :
Languages : en
Pages :
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Book Description
Colloidal quantum dot (CQD) solids represent a class of materials that allows one to control the optical and electronic properties due to their unique size-dependent properties with special electronic and optoelectronic device applications. Unfortunately, integration of these materials into high performing devices such as transistors and solar cells have been challenging due to: 1) uncontrolled environmental stability 2) lack of accurate control over charge carrier type and mobility 3) poor device operational stability and 4) limited experimental methods to probe the density of states in these materials in order to understand fundamental electronic and optical properties. In this thesis, we demonstrate the ability to stabilize and improve the environmental stability of these materials with amorphous Al2O3 (a-alumina). More importantly, we can accurately engineer the carrier type and mobility by varying the thickness of the alumina. Through a combination of small, compact inorganic ligands and the ability to passivate surface electronic traps, air-stable, high electron mobility PbSe QD field-effect transistors (FET) are obtained. We then show that we can also improve transistor device operational stability through an in-vacuo ligand exchange with H2S gas introduced in an atomic layer deposition (ALD) chamber. We find that this method is universal when volatile ligands are used. Possible mechanisms for device instability will be discussed such as proton migration and trap passivation. Using an optimized film preparation, this work will be the first demonstration of a QD FET with an electron mobility greater than 10 cm2 V-1 s-1 that is also operationally stable. Finally, we introduce a unique transmission spectroscopy technique of field-effect transistors to electrostatically probe induced charge carriers in PbSe QD films. With this technique we resolve occupation of quantized states of the quantum dots rather than the matrix or interfacial states. This platform is used to test fundamental transport models as it relates to disordered semiconductors such as QDs. From this technique, we can draw important conclusions about charge transport at room temperature. This novel experimental method can be extended to other experimental setups such as photoluminescence and photoconductivity in order to understand how to rationally improve the electronic properties of QD films.
Author: Jason Tolentino
Publisher:
ISBN: 9781339124421
Category :
Languages : en
Pages :
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Book Description
Colloidal quantum dot (CQD) solids represent a class of materials that allows one to control the optical and electronic properties due to their unique size-dependent properties with special electronic and optoelectronic device applications. Unfortunately, integration of these materials into high performing devices such as transistors and solar cells have been challenging due to: 1) uncontrolled environmental stability 2) lack of accurate control over charge carrier type and mobility 3) poor device operational stability and 4) limited experimental methods to probe the density of states in these materials in order to understand fundamental electronic and optical properties. In this thesis, we demonstrate the ability to stabilize and improve the environmental stability of these materials with amorphous Al2O3 (a-alumina). More importantly, we can accurately engineer the carrier type and mobility by varying the thickness of the alumina. Through a combination of small, compact inorganic ligands and the ability to passivate surface electronic traps, air-stable, high electron mobility PbSe QD field-effect transistors (FET) are obtained. We then show that we can also improve transistor device operational stability through an in-vacuo ligand exchange with H2S gas introduced in an atomic layer deposition (ALD) chamber. We find that this method is universal when volatile ligands are used. Possible mechanisms for device instability will be discussed such as proton migration and trap passivation. Using an optimized film preparation, this work will be the first demonstration of a QD FET with an electron mobility greater than 10 cm2 V-1 s-1 that is also operationally stable. Finally, we introduce a unique transmission spectroscopy technique of field-effect transistors to electrostatically probe induced charge carriers in PbSe QD films. With this technique we resolve occupation of quantized states of the quantum dots rather than the matrix or interfacial states. This platform is used to test fundamental transport models as it relates to disordered semiconductors such as QDs. From this technique, we can draw important conclusions about charge transport at room temperature. This novel experimental method can be extended to other experimental setups such as photoluminescence and photoconductivity in order to understand how to rationally improve the electronic properties of QD films.
Author: Jiang Wu
Publisher: Springer Science & Business Media
ISBN: 1461481309
Category : Technology & Engineering
Languages : en
Pages : 383
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Book Description
A quantum dot molecule (QDM) is composed of two or more closely spaced quantum dots or “artificial atoms.” In recent years, QDMs have received much attention as an emerging new artificial quantum system. The interesting and unique coupling and energy transfer processes between the “artificial atoms” could substantially extend the range of possible applications of quantum nanostructures. This book reviews recent advances in the exciting and rapidly growing field of QDMs via contributions from some of the most prominent researchers in this scientific community. The book explores many interesting topics such as the epitaxial growth of QDMs, spectroscopic characterization, and QDM transistors, and bridges between the fundamental physics of novel materials and device applications for future information technology. Both theoretical and experimental approaches are considered. Quantum Dot Molecules can be recommended for electrical engineering and materials science department courses on the science and design of advanced and future electronic and optoelectronic devices.
Author: Peng Yu
Publisher: Springer Nature
ISBN: 3030358135
Category : Technology & Engineering
Languages : en
Pages : 329
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Book Description
This book captures cutting-edge research in semiconductor quantum dot devices, discussing preparation methods and properties, and providing a comprehensive overview of their optoelectronic applications. Quantum dots (QDs), with particle sizes in the nanometer range, have unique electronic and optical properties. They have the potential to open an avenue for next-generation optoelectronic methods and devices, such as lasers, biomarker assays, field effect transistors, LEDs, photodetectors, and solar concentrators. By bringing together leaders in the various application areas, this book is both a comprehensive introduction to different kinds of QDs with unique physical properties as well as their preparation routes, and a platform for knowledge sharing and dissemination of the latest advances in a novel area of nanotechnology.
Author: Gerasimos Konstantatos
Publisher: Cambridge University Press
ISBN: 0521198267
Category : Science
Languages : en
Pages : 329
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Book Description
Captures the most up-to-date research in the field, written in an accessible style by the world's leading experts.
Author: Victor I. Klimov
Publisher: CRC Press
ISBN: 1420079271
Category : Technology & Engineering
Languages : en
Pages : 485
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Book Description
A review of recent advancements in colloidal nanocrystals and quantum-confined nanostructures, Nanocrystal Quantum Dots is the second edition of Semiconductor and Metal Nanocrystals: Synthesis and Electronic and Optical Properties, originally published in 2003. This new title reflects the book’s altered focus on semiconductor nanocrystals. Gathering contributions from leading researchers, this book contains new chapters on carrier multiplication (generation of multiexcitons by single photons), doping of semiconductor nanocrystals, and applications of nanocrystals in biology. Other updates include: New insights regarding the underlying mechanisms supporting colloidal nanocrystal growth A revised general overview of multiexciton phenomena, including spectral and dynamical signatures of multiexcitons in transient absorption and photoluminescence Analysis of nanocrystal-specific features of multiexciton recombination A review of the status of new field of carrier multiplication Expanded coverage of theory, covering the regime of high-charge densities New results on quantum dots of lead chalcogenides, with a focus studies of carrier multiplication and the latest results regarding Schottky junction solar cells Presents useful examples to illustrate applications of nanocrystals in biological labeling, imaging, and diagnostics The book also includes a review of recent progress made in biological applications of colloidal nanocrystals, as well as a comparative analysis of the advantages and limitations of techniques for preparing biocompatible quantum dots. The authors summarize the latest developments in the synthesis and understanding of magnetically doped semiconductor nanocrystals, and they present a detailed discussion of issues related to the synthesis, magneto-optics, and photoluminescence of doped colloidal nanocrystals as well. A valuable addition to the pantheon of literature in the field of nanoscience, this book presents pioneering research from experts whose work has led to the numerous advances of the past several years.
Author: Sangjin Lee (Ph. D.)
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
Colloidal quantum dots (CQDs) have attracted much attention due to their distinctive optical properties such as wide spectral responses and tunable absorption spectra with simple size control. These properties, together with the advantages of solution processing and superior robustness to organic materials, have motivated the recent investigation of CQD-based solar cells, which have seen rapid growth in power conversion efficiency in just the last 10 years, to a current record of over 10%. However, in order to continue to push the efficiencies higher, a better understanding of the charge transport phenomena in CQD films is needed. While the carrier transport mechanisms between isolated molecules have been explored theoretically and the device-scale mobility of CQD layers has been characterized using experimental measurements such as time-of-flight analysis and field-effect-transistor measurements, a systematic study of the connection between these two distinct scales is required in order to provide crucial information regarding how CQD layers with higher charge carrier mobility can be achieved. While a few strategies such as ligand exchanges, band-like transport, and trap-state-mediated transport have been suggested to enhance the charge carrier mobility, inhomogeneity in CQD solids has been considered a source of the mobility degradation because the electronic properties in individual CQDs may have dispersions introduced in the synthesis and/or in the deposition process, leading to the deviations of the localized energy states from the regular positions or the average energy levels. Here, we suggest that control over such design factors in CQD solids can provide important pathways for improvements in device efficiencies as well as the charge carrier mobility. In particular, we have focused on the polydispersity in CQDs, which normally lies in the range of 5-15%. The effect of size-dispersion in CQD solids on the charge carrier mobility was computed using charge hopping transport models. The experimental film deposition processes were replicated using a molecular dynamics simulation where the equilibrium positions of CQDs with a given radii distribution were determined under a granular potential. The radii and positions of the CQDs were then used in the charge hopping transport simulator where the carrier mobility was estimated. We observed large decreases (up to 70%) in electron mobility for typical experimental polydispersity (about 10%) in CQD films. These large degradations in hopping charge transport were investigated using transport vector analysis with which we suggested that the site energy differences raised the portion of the off-axis rate of charge transport to the electric field direction. Furthermore, we have shown that controlling the size distribution remarkably impacts the charge carrier mobility and we suggested that tailored and potentially experimentally achievable re-arrangement of the CQD size ensemble can mediate the mobility drops even in highly dispersive cases, and presents an avenue towards improved charge transport. We then studied the degradation in CQD solar cells with respect to the polydispersity and how these enhanced charge transport from re-design of CQD solids can boost the photovoltaic performances. In addition, we estimated the potential in the binary CQD solids in terms of their improved charge transport and efficient light absorption. Combined with the accurate size-dependent optical absorption model for CQDs, our hopping model confirmed that the inclusion of smaller CQDs could enhance both the charge transport and the solar light absorption, leading to the enhanced average charge generation rates and solar cell performance.
Author: Joshua Jongwoo Choi
Publisher:
ISBN:
Category :
Languages : en
Pages : 251
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Book Description
Nanocrystal quantum dots exhibit size-dependent optoelectronic properties and provide intriguing scientific and technological opportunities. Most proposed technologies based nanocrystals depend on macroscopic functional assemblies of nanocrystals in which the nanocrystals interact with each other to give rise to new collective properties - also called as artificial solids. As in the analogous atomic crystals, the optoelectronic properties of artificial solids are governed by (1) the energy levels of nanocrystals, (2) electronic coupling between nanocrystals, and (3) the symmetry of the nanocrystal superlattice. These issues add many levels of complexity to the design of artificial solids and, for the successful development of nanocrystal based technologies, it is crucial to gain deep understanding on the structure-property relationship of nanocrystals on multiple length scales. In this dissertation, I will present studies that show insights into the three governing factors of the optoelectronic properties of artificial solids mentioned above. (1) Nanocrystal energy levels: a direct correlation between interfacial energy level offsets between lead chalcogenide nanocrystals and ZnO layers with photovoltaic device performance is presented. Based on obtained insights on the size dependent photovoltaic properties of lead chalcogenide nanocrystals, first demonstration of solution processed nanocrystal tandem solar cells was achieved. (2) Inter-nanocrystal electronic coupling: rates of photogenerated exciton dissociation in nanocrystal assemblies as a function of inter-nanocrystal spacing are probed. The results show that excitons dissociate via tunneling induced delocalization among neighboring nanocrystals. Based on insights obtained from this work, drastically improved performance of solution processed nanocrystal infrared light emitting diodes is demonstrated. (3) Nanocrystal superlattice symmetry: interaction between ligand molecules on the surface of nanocrystals play critical roles in self-assembly process. Differences in the coverage of surface ligands bound to nanocrystals can be exploited to tune the shape of nanocrystal interaction potential during the self-assembly. Denser ligand coverage causes nanocrystals to interact as spheres and face-centered cubic structure is formed. In contrast, sparse ligand coverage amplifies the aspherical shape of the core crystallite and can cause non-close packed structures such as body-centered cubic.
Author: Peter Michler
Publisher: Springer
ISBN: 9783540874454
Category : Technology & Engineering
Languages : en
Pages : 390
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Book Description
This book reviews recent advances in the field of semiconductor quantum dots via contributions from prominent researchers in the scientific community. Special focus is given to optical, quantum optical, and spin properties of single quantum dots.
Author: Gerasimos Konstantatos
Publisher:
ISBN: 9781107459984
Category : Photovoltaic cells
Languages : en
Pages : 314
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Book Description
"Capturing the most up-to-date research in colloidal quantum dot (CQD) devices, this book is written in an accessible style by the world's leading experts. The application of CQDs in solar cells, photodetectors and light-emitting diodes (LEDs) has developed rapidly over recent years, promising to transform the future of clean energy, communications, and displays. This complete guide to the field provides researchers, students and practitioners alike with everything they need to understand these developments, and begin contributing to future applications. Introductory chapters summarise the fundamental physics and chemistry, whilst later chapters review the developments that have propelled the field forwards, systematically working through key device advances. The science of CQD films is explained through the latest physical models of semiconductor transport, trapping, and recombination, whilst the engineering of organic and inorganic multilayered materials is shown to have enabled major advances in the brightness and efficiency of CQD LEDs"--
Author: Julia Schornbaum
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
