Design, Synthesis and Characterization of new Supramolecular Architectures

Design, Synthesis and Characterization of new Supramolecular Architectures PDF Author: Massimo Baroncini
Publisher: Springer Science & Business Media
ISBN: 3642192858
Category : Science
Languages : en
Pages : 101

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Book Description
This thesis focuses on the bottom-up design, construction and operation of supramolecular systems capable of behaving as devices and machines on the molecular scale, which is a topic of great interest in nanoscience and a fascinating challenge in nanotechnology. In particular, the systems investigated here include: polyviologen dendrimers capable of behaving as hosts and chargestoring devices; molecular machines based on pseudorotaxanes/rotaxanes and operated by photoinduced proton transfer, or photoisomerization reactions; and a simple unimolecular multiplexer/demultiplexer. The systems have been characterized using a variety of techniques including absorption and emission spectra, laser flash photolysis, NMR spectroscopy, electrochemical experiments, stopped flow measurements. This research addresses a large number of open problems in the nanosciences, dealing with a wide range of the most advanced applications of supramolecular systems.

Design, Synthesis and Characterization of new Supramolecular Architectures

Design, Synthesis and Characterization of new Supramolecular Architectures PDF Author: Massimo Baroncini
Publisher: Springer Science & Business Media
ISBN: 3642192858
Category : Science
Languages : en
Pages : 101

Get Book Here

Book Description
This thesis focuses on the bottom-up design, construction and operation of supramolecular systems capable of behaving as devices and machines on the molecular scale, which is a topic of great interest in nanoscience and a fascinating challenge in nanotechnology. In particular, the systems investigated here include: polyviologen dendrimers capable of behaving as hosts and chargestoring devices; molecular machines based on pseudorotaxanes/rotaxanes and operated by photoinduced proton transfer, or photoisomerization reactions; and a simple unimolecular multiplexer/demultiplexer. The systems have been characterized using a variety of techniques including absorption and emission spectra, laser flash photolysis, NMR spectroscopy, electrochemical experiments, stopped flow measurements. This research addresses a large number of open problems in the nanosciences, dealing with a wide range of the most advanced applications of supramolecular systems.

Supramolecular Coordination Complexes

Supramolecular Coordination Complexes PDF Author: Sankarasekaran Shanmugaraju
Publisher: Elsevier
ISBN: 0323907059
Category : Science
Languages : en
Pages : 498

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Book Description
Supramolecular Coordination Complexes: Design, Synthesis, and Applications discusses the growth of the field and explores the advantages, opportunities and latest applications of supramolecular complexes. Beginning with an introduction to design principles, synthetic methods, and post-synthetic functionalization of supramolecular complexes, the book goes on to compile the different analytical and computational modeling methods used to understand the structure and functional properties of supramolecular structures. Applications of supramolecular complexes in biomedicine, sensing, catalysis and materials are then explored in detail. Drawing on the knowledge of a global team of experts, this book provides a wealth of interesting information for students and researchers working in the design, synthesis or application of such complexes. Discusses cutting-edge approaches for the investigation of supramolecular coordination chemistry Summarizes a varied range of supramolecular coordination, complex designs and applications Highlights the interdisciplinary connections between supramolecular chemistry and the fields of biology and materials science

Miktoarm Star Polymers

Miktoarm Star Polymers PDF Author: Ashok Kakkar
Publisher: Royal Society of Chemistry
ISBN: 1788010426
Category : Technology & Engineering
Languages : en
Pages : 241

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Book Description
The term ‘miktoarm polymers’ refers to asymmetric branched macromolecules, a relatively new entry to the macromolecular field. Recent advances in their synthesis and intriguing supramolecular chemistry in a desired medium has seen a fast expansion of their applications. The composition of miktoarm polymers can be tailored and even pre-defined to allow a desired combination of functions, meaning polymer chemists can have complete control of the overall architecture of these macromolecules. By carefully selecting the composition, they can create supramolecular structures with intriguing properties, particularly for applications in biology. Miktoarm Star Polymers features chapters from experts actively working in this field, and provides the reader with a unique introduction to the fundamental principles of this exciting macromolecular system. Topics covered include the design, synthesis, characterization, self-assembly and applications of miktoarm polymers. The book is an excellent overview and up to date guide to those working in research in polymer chemistry, materials science, and polymers for medical applications.

Complex Macromolecular Architectures

Complex Macromolecular Architectures PDF Author: Nikos Hadjichristidis
Publisher: Wiley
ISBN: 9780470825136
Category : Science
Languages : en
Pages : 0

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Book Description
The field of CMA (complex macromolecular architecture) stands at the cutting edge of materials science, and has been a locus of intense research activity in recent years. This book gives an extensive description of the synthesis, characterization, and self-assembly of recently-developed advanced architectural materials with a number of potential applications. The architectural polymers, including bio-conjugated hybrid polymers with poly(amino acid)s and gluco-polymers, star-branched and dendrimer-like hyperbranched polymers, cyclic polymers, dendrigraft polymers, rod-coil and helix-coil block copolymers, are introduced chapter by chapter in the book. In particular, the book also emphasizes the topic of synthetic breakthroughs by living/controlled polymerization since 2000. Furthermore, renowned authors contribute on special topics such as helical polyisocyanates, metallopolymers, stereospecific polymers, hydrogen-bonded supramolecular polymers, conjugated polymers, and polyrotaxanes, which have attracted considerable interest as novel polymer materials with potential future applications. In addition, recent advances in reactive blending achieved with well-defined end-functionalized polymers are discussed from an industrial point of view. Topics on polymer-based nanotechnologies, including self-assembled architectures and suprastructures, nano-structured materials and devices, nanofabrication, surface nanostructures, and their AFM imaging analysis of hetero-phased polymers are also included. Provides comprehensive coverage of recently developed advanced architectural materials Covers hot new areas such as: click chemistry; chain walking; polyhomologation; ADMET Edited by highly regarded scientists in the field Contains contributions from 26 leading experts from Europe, North America, and Asia Researchers in academia and industry specializing in polymer chemistry will find this book to be an ideal survey of the most recent advances in the area. The book is also suitable as supplementary reading for students enrolled in Polymer Synthetic Chemistry, Polymer Synthesis, Polymer Design, Advanced Polymer Chemistry, Soft Matter Science, and Materials Science courses. Color versions of selected figures can be found at www.wiley.com/go/hadjichristidis

New Trends in Nonionic (co)polymers and Hybrids

New Trends in Nonionic (co)polymers and Hybrids PDF Author: Ecaterina Stela Dragan
Publisher: Nova Publishers
ISBN: 9781600210518
Category : Science
Languages : en
Pages : 304

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Book Description
This book tries to disseminate recent research results, and to stimulate new and extended activities in the field of polymer science and hybrid materials. Spectacular advances in polymer synthesis have led to a high level of control over molecular and supramolecular architectures. The book tries to get attention of the reader on some representative topics of polymer science and hybrid materials by seven contributions from prominent authors who are involved either in the synthesis and characterisation of linear and non-linear nonionic polymers, or in the design and characterisation of new hybrid materials.

Photophysics of Supramolecular Architectures

Photophysics of Supramolecular Architectures PDF Author: Paulpandian Muthu Mareeswaran
Publisher: Bentham Science Publishers
ISBN: 9815049208
Category : Science
Languages : en
Pages : 237

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Book Description
This reference provides collective information about the physical andphotophysical changes of supramolecules after encapsulation. It coversluminescent systems involving a range of host molecules such as calixarenes, cyclodextrin, resorcinanene-crowns, pillararenes, cucurbituril, andmetallacycles. Chapters also discuss the effect of the macrocyclic environment onthe properties of functionalized molecules, including the variations in foldingand unfolding patterns. Each chapter is supplemented with detailed references,making this an ideal resource for scholars interested in supramolecularphotophysics.

Co-crystals

Co-crystals PDF Author: Christer B Aakeröy
Publisher: Royal Society of Chemistry
ISBN: 1788011155
Category : Science
Languages : en
Pages : 354

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Book Description
This book combines co-crystal applications of commercial and practical interest from diverse fields into a single volume. It also examines effective structural design of co-crystals, and provides insights into practical synthesis and characterization techniques.

Handbook of Condensation Thermoplastic Elastomers

Handbook of Condensation Thermoplastic Elastomers PDF Author: Stoyko Fakirov
Publisher: John Wiley & Sons
ISBN: 3527606890
Category : Technology & Engineering
Languages : en
Pages : 643

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Book Description
Reporting on the work of an international team of scientists actively involved in the study of thermoplastic elastomers (TPE) based on polyesters, polyamides, and polyurethanes, this book is the first to provide a detailed description of condensation TPE with close attention paid to polyamide-based systems. Reflecting the increasing importance of TPE as engineering plastics, the authors discuss the widened application opportunities by preparing systems with various chemical compositions and molecular structures as (semi-) interpenetrating networks. The contents also cover the chemical aspects, physical structure and properties, life cycle assessment, and recycling possibilities as well as such unique "smart" properties like the shape memory effect of the three classes of thermoplastic elastomers.

Scientific and Technical Aerospace Reports

Scientific and Technical Aerospace Reports PDF Author:
Publisher:
ISBN:
Category : Aeronautics
Languages : en
Pages : 982

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Book Description


Core Concepts in Supramolecular Chemistry and Nanochemistry

Core Concepts in Supramolecular Chemistry and Nanochemistry PDF Author: Jonathan W. Steed
Publisher: John Wiley & Sons
ISBN: 9780470858707
Category : Science
Languages : en
Pages : 320

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Book Description
Supramolecular chemistry and nanochemistry are two strongly interrelated cutting edge frontiers in research in the chemical sciences. The results of recent work in the area are now an increasing part of modern degree courses and hugely important to researchers. Core Concepts in Supramolecular Chemistry and Nanochemistry clearly outlines the fundamentals that underlie supramolecular chemistry and nanochemistry and takes an umbrella view of the whole area. This concise textbook traces the fascinating modern practice of the chemistry of the non-covalent bond from its fundamental origins through to it expression in the emergence of nanochemistry. Fusing synthetic materials and supramolecular chemistry with crystal engineering and the emerging principles of nanotechnology, the book is an ideal introduction to current chemical thought for researchers and a superb resource for students entering these exciting areas for the first time. The book builds from first principles rather than adopting a review style and includes key references to guide the reader through influential work. supplementary website featuring powerpoint slides of the figures in the book further references in each chapter builds from first principles rather than adopting a review style includes chapter on nanochemistry clear diagrams to highlight basic principles