Deactivation And Regeneration Of Zeolite Catalysts PDF Download
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Author: Michel Guisnet
Publisher: World Scientific Publishing Company
ISBN: 1911299530
Category : Science
Languages : en
Pages : 359
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Book Description
In chemical processes, the progressive deactivation of solid catalysts is a major economic concern and mastering their stability has become as essential as controlling their activity and selectivity. For these reasons, there is a strong motivation to understand the mechanisms leading to any loss in activity and/or selectivity and to find out the efficient preventive measures and regenerative solutions that open the way towards cheaper and cleaner processes. This book covers the fundamental and applied aspects of solid catalyst deactivation in a comprehensive way and encompasses the state of the art in the field of reactions catalyzed by zeolites. This particular choice is justified by the widespread use of molecular sieves in refining, petrochemicals and organic chemicals synthesis processes, by the large variety in the nature of their active sites (acid, base, acid-base, redox, bifunctional) and especially by their peculiar features, in terms of crystallinity, structural order and textural properties, which make them ideal models for heterogeneous catalysis. The aim of this book is to be a critical review in the field of zeolite deactivation and regeneration by collecting contributions from experts in the field which describe the factors, explain the techniques to study the causes and suggest methods to prevent (or limit) catalyst deactivation. At the same time, a selection of commercial processes and exemplar cases provides the reader with theoretical insights and practical hints on the deactivation mechanisms and draws attention to the key role played by the loss of activity on process design and industrial practice./a
Author: Michel Guisnet
Publisher: World Scientific Publishing Company
ISBN: 1911299530
Category : Science
Languages : en
Pages : 359
Get Book Here
Book Description
In chemical processes, the progressive deactivation of solid catalysts is a major economic concern and mastering their stability has become as essential as controlling their activity and selectivity. For these reasons, there is a strong motivation to understand the mechanisms leading to any loss in activity and/or selectivity and to find out the efficient preventive measures and regenerative solutions that open the way towards cheaper and cleaner processes. This book covers the fundamental and applied aspects of solid catalyst deactivation in a comprehensive way and encompasses the state of the art in the field of reactions catalyzed by zeolites. This particular choice is justified by the widespread use of molecular sieves in refining, petrochemicals and organic chemicals synthesis processes, by the large variety in the nature of their active sites (acid, base, acid-base, redox, bifunctional) and especially by their peculiar features, in terms of crystallinity, structural order and textural properties, which make them ideal models for heterogeneous catalysis. The aim of this book is to be a critical review in the field of zeolite deactivation and regeneration by collecting contributions from experts in the field which describe the factors, explain the techniques to study the causes and suggest methods to prevent (or limit) catalyst deactivation. At the same time, a selection of commercial processes and exemplar cases provides the reader with theoretical insights and practical hints on the deactivation mechanisms and draws attention to the key role played by the loss of activity on process design and industrial practice./a
Author: J.L. Figueiredo
Publisher: Springer Science & Business Media
ISBN: 940097597X
Category : Science
Languages : en
Pages : 398
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Book Description
Most catalysts used in the chemical and petrochemical indus tries are strongly affected by one or another form of deactivation, leading to poor performances and reduced life. The increasing num ber of scientific communications devoted to the subject in recent years, and culminating with an International Symposium held in Antwerp in October 1980, is a measure of the interest it arouses in both the industrial and academic communities. A stage has been reached whereby it was thought that a NATO Advanced Study Institute on "Catalyst Deactivation" might be fruit ful in establishing the state of the art and in stimulating a more systematic research on the phenomenon. Such a meeting was held ~n Lagos, Portugal, from 18 to 29 May 1981. The purpose of the Institute was to present and discuss in a didatic and systematic way the various processes that lead to cata lyst deactivation, namely coking, poisoning and solid state trans formations, and at the same time to promote the exchange of ideas and experiences among the participants, drawn from industry and uni versity. The lectures presented at the Institute are collected in this volume with the exception of Dr. L.L.Hegedus "Catalyst Poisoning", which has been previously published (Catalysis Reviews, Science md Engineering, 23, 377-476, 1981).
Author: John B. Butt
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 520
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Book Description
Author: Manfred Baerns
Publisher: Springer Science & Business Media
ISBN: 3662059819
Category : Science
Languages : en
Pages : 540
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Book Description
Written by a team of internationally recognized experts, this book addresses the most important types of catalytic reactions and catalysts as used in industrial practice. Both applied aspects and the essential scientific principles are described. The main topics can be summarized as follows: heterogeneous, homogeneous and biocatalysis, catalyst preparation and characterization, catalytic reaction engineering and kinetics, catalyst deactivation and industrial perspective.
Author: J. Oudar
Publisher: CRC Press
ISBN: 9780824773380
Category : Science
Languages : en
Pages : 356
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Book Description
Deactivation and Poisoning of Catalysts presents the most current research in the area of heterogeneous catalysis. It focuses on the chemically induced effects associated with bonded surface species that cause catalyst activity decline -- and in some cases a change in catalyst specificity. In addition, this volume examines poisoning of dispersed metal catalysts ... the thermodynamics of sulfur-metal and carbon-metal interactions ... model poisoning reactions on single crystals ... deactivation in petroleum refining and petrochemical processes ... coking of metal catalysts ... and more. The new approaches and solutions to catalyst deactivation and poisoning presented in this guide are invaluable to all heterogeneous catalysis specialists, including chemical and petroleum engineers, and surface, synthetic, physical, and industrial chemists. Book jacket.
Author: Jerzy Skrzypek
Publisher:
ISBN:
Category : Catalysis
Languages : en
Pages : 174
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Book Description
Author: Ronald Hughes
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 294
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Book Description
Author: Dushyant Shekhawat
Publisher: Elsevier
ISBN: 0444535640
Category : Technology & Engineering
Languages : en
Pages : 569
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Book Description
Fuel Cells: Technologies for Fuel Processing provides an overview of the most important aspects of fuel reforming to the generally interested reader, researcher, technologist, teacher, student, or engineer. The topics covered include all aspects of fuel reforming: fundamental chemistry, different modes of reforming, catalysts, catalyst deactivation, fuel desulfurization, reaction engineering, novel reforming concepts, thermodynamics, heat and mass transfer issues, system design, and recent research and development. While no attempt is made to describe the fuel cell itself, there is sufficient description of the fuel cell to show how it affects the fuel reformer. By focusing on the fundamentals, this book aims to be a source of information now and in the future. By avoiding time-sensitive information/analysis (e.g., economics) it serves as a single source of information for scientists and engineers in fuel processing technology. The material is presented in such a way that this book will serve as a reference for graduate level courses, fuel cell developers, and fuel cell researchers. - Chapters written by experts in each area - Extensive bibliography supporting each chapter - Detailed index - Up-to-date diagrams and full colour illustrations
Author: L. Melo
Publisher: Springer Science & Business Media
ISBN: 9400928130
Category : Science
Languages : en
Pages : 720
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Book Description
The fouling of heat exchangers, reactors and catalysts remains one of the most urgent problems facing the process industries. Over the past ten years there has been limited research and investigation into the underlying mechanisms which give rise to this problem. For convenience, particularly in heat exchanger technology, the mechanisms involved have been subdivided into different subject areas. It is often the situation that individuals or groups of workers have concentra ted efforts in one or two of these specialist areas and there is a need to integrate the ideas across the whole spectrum of the subject. In addition, topics such as adhesion and surface phenomena have not been properly taken into account up till now in the assessment of the fouling processes. For this reason it was considered essential that the recognised experts from around the world, who are actively concerned with research, development and design in the fieId, should meet and exchange ideas and experience. Such a meeting was held at Alvor, Portugal, in May 1987, sponsored by the NATO Advanced St~dy Institutes Programme. In order to obtain a common basis for the work of the Advanced Study Institute, the whole technological field was reviewed right from the basic concepts to the frontiers of present knowledge. Each invited contributor was asked to make an overall presentation covering his or her area of expertise.
Author: Zhongyi Liu
Publisher: Springer Nature
ISBN: 9811564116
Category : Science
Languages : en
Pages : 355
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Book Description
This book provides a comprehensive description of the catalytic technologies for selective hydrogenation of benzene to cyclohexene. Focusing on selective hydrogenation of benzene to prepare cyclohexene and its downstream products, such as cyclohexanone, bulk chemicals and high-value fine chemicals, it also discusses the objective laws, reaction mechanisms and scientific significance based on experimental data, analysis and characterization results. Given its scope, the book will appeal to a broad readership, particularly professionals at universities and scientific research institutes, senior undergraduates, master's and doctoral graduate students as well as practitioners in industry.
