Corrosion Resistance Properties of Plasma Nitrided Ti-6Al-4V Alloy in Nitric Acid Solutions

Corrosion Resistance Properties of Plasma Nitrided Ti-6Al-4V Alloy in Nitric Acid Solutions PDF Author: Alessio Fossati
Publisher:
ISBN:
Category :
Languages : en
Pages : 11

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Corrosion Resistance Properties of Plasma Nitrided Ti-6Al-4V Alloy in Nitric Acid Solutions

Corrosion Resistance Properties of Plasma Nitrided Ti-6Al-4V Alloy in Nitric Acid Solutions PDF Author: Alessio Fossati
Publisher:
ISBN:
Category :
Languages : en
Pages : 11

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Nanomaterials and Their Biomedical Applications

Nanomaterials and Their Biomedical Applications PDF Author: Tuhin Subhra Santra
Publisher: Springer Nature
ISBN: 9813362529
Category : Science
Languages : en
Pages : 552

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Book Description
This book highlights the evolution of, and novel challenges currently facing, nanomaterials science, nanoengineering, and nanotechnology, and their applications and development in the biological and biomedical fields. It details different nanoscale and nanostructured materials syntheses, processing, characterization, and applications, and considers improvements that can be made in nanostructured materials with their different biomedical applications. The book also briefly covers the state of the art of different nanomaterials design, synthesis, fabrication and their potential biomedical applications. It will be particularly useful for reading and research purposes, especially for science and engineering students, academics, and industrial researchers.

Environment Related Surface Phenomena and Their Influence on Properties of Ti-6Al-4V and Ti-6Al-2Sn-4Zr-2Mo : Oxidation at Elevated Temperature and Corrosion During Chemical Treatment

Environment Related Surface Phenomena and Their Influence on Properties of Ti-6Al-4V and Ti-6Al-2Sn-4Zr-2Mo : Oxidation at Elevated Temperature and Corrosion During Chemical Treatment PDF Author: Birhan Sefer
Publisher:
ISBN:
Category :
Languages : en
Pages : 183

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This thesis covers investigation of the surface phenomena of Ti-6Al-4V and Ti-6Al-2Sn-4Zr-2Mo alloys related with oxidation at elevated temperature and corrosion during chemical treatment in hydrofluoric-nitric acid (HF/HNO3) solutions. The explored phenomena are related to manufacturing and service conditions of aero-engine components. During manufacturing and operation, the alloys are sunjected to elevated temperatures in oxygen environment. In such conditions an oxide on the surface and an oxygen enriched layer below the oxide, commonly referred as alpha-case is formed. Alpha-case is a hard and brittle layer that is detrimental to the mechanical properties and must therefore be completely eliminated. A conventional method for elimination of alpha-case is chemical processing in HF/HNO3 solutions, i.e. chemical milling. Isothermal oxidation treatments in air at 500, 593 and 700 oC for up to 500 hours were carried out in this thesis. Both alloys developed rutile type of oxide structure and Ti-6Al-2Sn-4Zr-2Mo exhibited stronger oxidation resistance than Ti-6Al-4V. Transition from parabolic to linear oxidation rate was observed at 700 oC and = 200 hours for both alloys. The difference in the oxidation kinetics of the two alloys is suggested to be related with the chemical composition of the alloys. The oxygen enriched layer, i.e. alpha-case layer, was characterised and its thickness was measured using conventional metallographic and microscopic techniques. The parabolic rate constants, the oxygen diffusion parameters and activation energies were estimated in the temperature range of 500-700 oC for both alloys. Moreover, the oxidation for 500 hours at 700 oC resulted in microstructural changes and element re-distribution. The bulk and alpha-case layer hardness at micro- and nano-scale were measured using microhardness and nanoindentation techniques. The alpha-case layer had higher hardness due to the solid solution strengthening effect of the diffused oxygen. The effect of chemical milling in 1:11 HF/HNO3 solution on the surface integrity, and the influence on low cycle fatigue (LCF) strength of cast Ti-6Al-2Sn-4Zr-2Mo alloy was investigated. Five and sixty minutes chemical processing times and three imposed total strain ranges in fatigue tests were evaluated. Significant drop in fatigue life was observed for the samples etched before LCF testing, as compared to the non-etched samples. The influence from etching was found to be most detrimental for fatigue samples tested at the lowest strain ranges. The fatigue life reduction was correlated with the number of crack initiation sites. Multiple crack initiation sites were observed for the etched samples, whereas only one crack initiation site was discerned in the non-etched samples. Inspection of the surface of the etched samples revealed selective and severely etched prior ß grain boundaries and pit formation at the triple joints of the prior ß grain boundaries. These surface defects were considered as stress raisers promoting an earlier fatigue crack initiation. The influence of two molar concentration ratios of HF and HNO3 acids (1:3 and 1:11) on the corrosion behaviour of cast Ti-6Al-4V and Ti-6Al-2Sn-4Zr-2Mo were investigated by electrochemical and atomic force microscopy (AFM) techniques. The corrosion of the two alloys was a function of the concentration ratio of the acids and also of the alloys¿ chemical compositions. The AFM measurements showed faster dissolution rate of the a-phase than the ß-phase in the Widmanstätten microstructure. It was considered that the reason for this is formation of local micro-galvanic cells between the phases. Moreover, the Volta-potential was measured using scanning Kelvin probe force microscopy (SKPFM) and the obtained maps revealed difference in the Volta-potential between the a- and the ß-laths in both alloys. This observation strengthened the likelihood for formation and operation of micro-galvanic cells between the phases.

Surface Modification of Ti-6Al-4V Alloy by Plasma Source Ion Implantation

Surface Modification of Ti-6Al-4V Alloy by Plasma Source Ion Implantation PDF Author: Xiaohong Qiu
Publisher:
ISBN:
Category :
Languages : en
Pages : 300

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Metals Abstracts

Metals Abstracts PDF Author:
Publisher:
ISBN:
Category : Metallurgy
Languages : en
Pages : 972

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Corrosion of Titanium

Corrosion of Titanium PDF Author: J. D. Jackson
Publisher:
ISBN:
Category : Titanium
Languages : en
Pages : 54

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Titanium Alloys

Titanium Alloys PDF Author: W Sha
Publisher: Elsevier
ISBN: 1845695860
Category : Technology & Engineering
Languages : en
Pages : 588

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Book Description
Given their growing importance in the aerospace, automotive, sports and medical sectors, modelling the microstructure and properties of titanium and its alloys is a vital part of research into the development of new applications. This is the first time a book has been dedicated to modelling techniques for titanium.Part one discusses experimental techniques such as microscopy, synchrotron radiation X-ray diffraction and differential scanning calorimetry. Part two reviews physical modelling methods including thermodynamic modelling, the Johnson-Mehl-Avrami method, finite element modelling, the phase-field method, the cellular automata method, crystallographic and fracture behaviour of titanium aluminide and atomistic simulations of interfaces and dislocations relevant to TiAl. Part three covers neural network models and Part four examines surface engineering products. These include surface nitriding: phase composition, microstructure, mechanical properties, morphology and corrosion; nitriding: modelling of hardness profiles and kinetics; and aluminising: fabrication of Ti coatings by mechanical alloying.With its distinguished authors, Titanium alloys: Modelling of microstructure, properties and applications is a standard reference for industry and researchers concerned with titanium modelling, as well as users of titanium, titanium alloys and titanium aluminide in the aerospace, automotive, sports and medical implant sectors. - Comprehensively assesses modelling techniques for titanium, including experimental techniques such as microscopy and differential scanning calorimetry - Reviews physical modelling methods including thermodynamic modelling and finite element modelling - Examines surface engineering products with specific chapters focused on surface nitriding and aluminising

Advanced Coatings for Corrosion Protection

Advanced Coatings for Corrosion Protection PDF Author: Wolfram Fürbeth
Publisher: MDPI
ISBN: 3039439219
Category : Technology & Engineering
Languages : en
Pages : 222

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Book Description
Corrosion is a significant issue in many industrial fields. Among other strategies, coatings are by far the most important technology for corrosion protection of metallic surfaces. The Special Issue “Advanced Coatings for Corrosion Protection” has been launched as a means to present recent developments in any type of advanced coating for corrosion protection. This book compiles 15 contributions on metallic, inorganic, polymeric and nanoparticle enhanced coatings that provide corrosion protection as well as other functionalities.

Manufacturing and Application of Stainless Steels

Manufacturing and Application of Stainless Steels PDF Author: Andrea Di Schino
Publisher: MDPI
ISBN: 3039286501
Category : Technology & Engineering
Languages : en
Pages : 260

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Book Description
Stainless steels represent a quite interesting material family, both from a scientific and commercial point of view, following to their excellent combination in terms of strength and ductility together with corrosion resistance. Thanks to such properties, stainless steels have been indispensable for the technological progress during the last century and their annual consumption increased faster than other materials. They find application in all these fields requiring good corrosion resistance together with ability to be worked into complex geometries. Despite to their diffusion as a consolidated materials, many research fields are active regarding the possibility to increase stainless steels mechanical properties and corrosion resistance by grain refinement or by alloying by interstitial elements. At the same time innovations are coming from the manufacturing process of such a family of materials, also including the possibility to manufacture them starting from metals powder for 3D printing. The Special Issue scope embraces interdisciplinary work covering physical metallurgy and processes, reporting about experimental and theoretical progress concerning microstructural evolution during processing, microstructure-properties relations, applications including automotive, energy and structural.

Plasma Nitriding of Steels

Plasma Nitriding of Steels PDF Author: Hossein Aghajani
Publisher: Springer
ISBN: 3319430688
Category : Technology & Engineering
Languages : en
Pages : 192

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Book Description
This book focuses on the effect of plasma nitriding on the properties of steels. Parameters of different grades of steels are considered, such as structural and constructional steels, stainless steels and tools steels. The reader will find within the text an introduction to nitriding treatment, the basis of plasma and its roll in nitriding. The authors also address the advantages and disadvantages of plasma nitriding in comparison with other nitriding methods.