Author: Ju-Hee So
Publisher:
ISBN:
Category :
Languages : en
Pages : 148

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Author: Logan Ali Stewart
Publisher:
ISBN:
Category :
Languages : en
Pages : 113

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Gallium-based liquid metal alloys have garnered attention for their use in self-healing and flexible electronics, soft robotics, catalysis, and biomedicine. Advances in these next-generation materials have only been made possible through understanding the liquid-metal interfaces and the interactions of matter with these liquids. We propose that liquid metal chemistry of gallium and gallium-based alloys can be subdivided into a series of interfacial phenomenon. To study the interfacial properties of liquid metal, eutectic gallium indium (E-GaIn), a non-toxic liquid metal alloy comprised of ~75% gallium and ~25% indium, and has a melting temperature of 15.5 C, was employed for its liquid state at room temperature. With an overview of the breadth of chemistry involved within liquid metal systems, we first consider the oxidation of liquid metals in air. Room-temperature liquid metals, their interactions in air, and the kinetics of oxidation are critical first steps towards understanding the materials properties of liquid metals, such as surface-energy/surface-tension that originate at the metal-oxide interface. Once understood, this oxidation can be prevented via surface-bound ligands. We employed gallium-thiol chemistry and bi-functional thiol molecules as capping ligands for the surface stabilization of gallium-based liquid-metal nanostructures. These surface stabilization effects, within mixtures of liquid metal and polar solution, such as water and ethanol, are examined as a new type of emulsified system. These emulsified systems, with the help of surface-active molecules, can exist in both their singly and doubly emulsified forms. Like mercury and other liquid metals, E-GaIn has a high surface tension, which when broken can form ultra-small droplets, ~4 nm. These ultra-small liquid metal droplets were found to undergo higher order assemblies in the form of fractal aggregates under evaporation of the surrounding solvent. When examining the doubly emulsified form, these liquid metal droplets present a novel approach for the encapsulation of cargo. The material properties of E-GaIn present an interesting avenue for the study of nanocarriers. Eutectic gallium indium, which has low toxicity, enable considering this liquid metal for drug-delivery applications. Furthermore, where traditional nanoparticle carriers typically have cargo decorated on the surface, or within pores and imperfections; liquid-metal double emulsions, which have a non-metallic phase embedded within the core of the liquid metal droplets, allow for cargo loading much larger than the surface of the nanostructure. Lastly, competition for interfaces and the role of self-assembly at metallic interfaces presents a scaffold for the post-encapsulation functionalization of liquid metal carriers. The 'skin' of liquid E-GaIn, whether comprised of metal oxide, metal thiolate, or pristine surface can act as a barrier for reaction kinetics, such as in the case of surface oxidation and the prevention of it with thiol/thiolate assemblies at the liquid metal interface, or a regenerative reactive interface, as in the case of surface-initiated galvanic reduction. Galvanic reduction with gallium, as the name implies, can act as a free-electron surface for the reduction of simple metal salts. Similar to hanging mercury drop experiments, liquid metals provide a pristine, self-regenerating, liquid metal surface. We explore the galvanic reduction of silver salts on nanoscopic liquid metal seeds via solution-liquid-solid-growth of silver nanovines. We found these arboriform liquid metal structures were grown as diffusion-limited aggregates and we were able to impart control on both the growth front thickness and aspect ratio. The manipulation of liquid metals with surface-active molecules will have applications in next-generation devices and soft robotics. By incorporating liquid metal as the conductive contacts, we enable malleable devices. Liquid metals enable new applications of traditional conductive materials with certain advantages. We envision robots, sensors, and a variety of future prospects where liquid metal can open new doors to a variety of applications. In an effort to explore these devices, we have shown that E GaIn is an ideal contact material for an ultra-thin indium oxide based field-effect transistor (FET). These liquid-metal-enabled devices provide lower barriers to charge transfer, yielding lower power devices as compared to gold. Liquid-metal-enabled emulsions, materials, and devices present new chapters in inorganic chemistry, materials chemistry, engineering, nanoscience, and medicine. By looking at the interfacial phenomenon that dictates the interactions of liquid metal with the environment, we explore these avenues of control and application. With the rise in availability for three-dimensional (3-D) printers, liquid metal and hybrid materials comprised of liquid-metal-based emulsions are a new frontier. The field of liquid-metal-enabled materials remains relatively unexplored.

Author: Praneshnandan Nithyanandam
Publisher:
ISBN:
Category :
Languages : en
Pages : 100

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Author: Lei Fu
Publisher: John Wiley & Sons
ISBN: 3527828184
Category : Technology & Engineering
Languages : en
Pages : 436

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An up-to-date exploration of the properties and most recent applications of liquid metals In Liquid Metal: Properties, Mechanisms, and Applications, a pair of distinguished researchers delivers a comprehensive exploration of liquid metals with a strong focus on their structure and physicochemical properties, preparation methods, and tuning strategies. The book also illustrates the applications of liquid metals in fields as varied as mediated synthesis, 3D printing, flexible electronics, biomedicine, energy storage, and energy conversion. The authors include coverage of reactive mediums for synthesizing and assembling nanomaterials and direct-writing electronics, and the book offers access to supplementary video materials to highlight the concepts discussed within. Recent advancements in the field of liquid metals are also discussed, as are new opportunities for research and development in this rapidly developing area. The book also includes: A thorough introduction to the fundamentals of liquid metal, including a history of its discovery, its structure and physical properties, and its preparation Comprehensive explorations of the external field tuning of liquid metal, including electrical, magnetic, and chemical tuning Practical discussions of liquid metal as a new reaction medium, including nanomaterial synthesis and alloy preparation In-depth examinations of constructing techniques of liquid metal-based architectures, including injection, imprinting, and mask-assisted depositing Perfect for materials scientists, electrochemists, and catalytic chemists, Liquid Metal: Properties, Mechanisms, and Applications also belongs in the libraries of inorganic chemists, electronics engineers, and biochemists.

Author: Jing Liu
Publisher: Springer
ISBN: 9811327092
Category : Technology & Engineering
Languages : en
Pages : 379

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This book discusses the core principles and practical applications of a brand new machine category: liquid-metal soft machines and motors. After a brief introduction on the conventional soft robot and its allied materials, it presents the new conceptual liquid-metal machine, which revolutionizes existing rigid robots, both large and small. It outlines the typical features of the soft liquid-metal materials and describes the various transformation capabilities, mergence of separate metal droplets, self-rotation and planar locomotion of liquid-metal objects under external or internal mechanism. Further, it introduces a series of unusual phenomena discovered while developing the shape changeable smart soft machine and interprets the related mechanisms regarding the effects of the shape, size, voltage, orientation and geometries of the external fields to control the liquid-metal transformers. Moreover, the book illustrates typical strategies to construct a group of different advanced functional liquid-metal soft machines, since such machines or robots are hard to fabricate using rigid-metal or conventional materials. With highly significant fundamental and practical findings, this book is intended for researchers interested in establishing a general method for making future smart soft machine and accompanying robots.

Author:
Publisher:
ISBN:
Category : Chemistry
Languages : en
Pages : 2540

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Author: Takashi Nakanishi
Publisher: John Wiley & Sons
ISBN: 3527804951
Category : Technology & Engineering
Languages : en
Pages : 323

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The first book to comprehensively cover the burgeoning new class of soft materials known as functional organic liquids Functional organic liquids, a new concept in soft matter materials science, exhibit favorable properties compared to amorphous polymers and ionic liquids. They are composed of a functional core unit and a side chain, which induces fluidity even at room temperature. Due to their fluidity, functional organic liquids can adopt any shape and geometry and fulfill their function in stretchable and bendable devices for applications in photovoltaics, organic electronics, biomedicine, and biochemistry. Presented in five parts, this book starts with an overview of the design methods and properties of functional organic liquids. The next three parts focus on the applications of this exciting new class of soft materials in the fields of energy conversion, nanotechnology, and biomaterials. They study the liquids for energy conversion, those containing inorganic nanoclusters, and solvent-free soft biomaterials. Functional Organic Liquids concludes with a comparison in terms of properties and application potential between functional organic liquids and more conventional soft matter such as ionic liquids and liquid metals. -Examines the current state of science and technology for functional organic liquids -Focuses on potential and already realized applications such as functional organic liquids for energy conversion -Stimulates researchers to move forward on future development and applications Functional Organic Liquids is an excellent book for materials scientists, polymer chemists, organic chemists, physical chemists, surface chemists, and surface physicists.

Author:
Publisher:
ISBN:
Category : Dissertation abstracts
Languages : en
Pages : 806

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Author: David J. Fisher
Publisher: Materials Research Forum LLC
ISBN: 1644900696
Category : Technology & Engineering
Languages : en
Pages : 138

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Liquid metal alloys are of rapidly increasing interest in electronics because they combine the high electrical conductivity of metals with the ease of manipulation and reconfiguration of liquids. The book focuses on such issues as self-assembled monolayers, energy-harvesting, reconfigurable and flexible antennae, sensors, conformable electronics, the creation of non-wetting super-hydrophobic or super-lyophobic surfaces, vacuum-assisted infiltration techniques, development of microfluidics, deformable electrodes and wearable electronics. The book references 270 original resources and includes their direct web link for in-depth reading. Keywords: Liquid Metals, Gallium-Indium Alloys, Galinstan, EGaIn, Self-Assembled Monolayers, Energy-Harvesting, Reconfigurable Antennae, Sensors, Conformable Electrodes, Stretchable Wires and Interconnects, Self-Healing Circuits, Gallium-Lyophilic Surfaces, Wettability of Liquid Metal, Substrate Topology, Selective Wetting Deposition Technique, Gallium-Indium Droplets on Thin Metal Films, Substrate Texture upon Wetting, Dielectrophoresis, Microfluidics, Deformable Electrodes, Wearable Electronics, Flexible Antennae, Surface Oxidation of Alloys.

Author: John B. Wachtman
Publisher: John Wiley & Sons
ISBN: 9780470451502
Category : Technology & Engineering
Languages : en
Pages : 496

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A Comprehensive and Self-Contained Treatment of the Theory and Practical Applications of Ceramic Materials When failure occurs in ceramic materials, it is often catastrophic, instantaneous, and total. Now in its Second Edition, this important book arms readers with a thorough and accurate understanding of the causes of these failures and how to design ceramics for failure avoidance. It systematically covers: Stress and strain Types of mechanical behavior Strength of defect-free solids Linear elastic fracture mechanics Measurements of elasticity, strength, and fracture toughness Subcritical crack propagation Toughening mechanisms in ceramics Effects of microstructure on toughness and strength Cyclic fatigue of ceramics Thermal stress and thermal shock in ceramics Fractography Dislocation and plastic deformation in ceramics Creep and superplasticity of ceramics Creep rupture at high temperatures and safe life design Hardness and wear And more While maintaining the first edition's reputation for being an indispensable professional resource, this new edition has been updated with sketches, explanations, figures, tables, summaries, and problem sets to make it more student-friendly as a textbook in undergraduate and graduate courses on the mechanical properties of ceramics.