Author: Jean-Francis Marucco
Publisher: L'Editeur : EDP Sciences
ISBN: 9782868836731
Category :
Languages : fr
Pages : 565
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Book Description
Cet ouvrage a pour but de définir les bases de la chimie des solides. Il est destiné aux étudiants des licences et mastères de chimie, chimie physique, sciences physiques et sciences des matériaux, ainsi qu'aux élèves des écoles d'ingénieurs en chimie. Il traite en particulier : - les structures cristallines, l'énergie réticulaire et ses implications ; -la structure électronique des composés binaires ; -la thermodynamique des solides et les réactions solides-gaz ; - les défauts ponctuels et la non-staschiométrie ; -les substitutions cationiques et le dopage ; -des notions de thermodynamique des phénomènes irréversibles ; - le transport de matière et la diffusion ; - le transport de charges et la conductivité électronique ; - le transport de matière chargée et la conductivité ionique ; - les piles et la réactivité chimique ; -le pouvoir thermoélectrique, les applications théoriques et pratiques. De nombreux exemples, figures et exercices permettent d'illustrer ces différents domaines.
Author: P. Lacombe
Publisher:
ISBN: 9780444416995
Category :
Languages : en
Pages : 600
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Book Description
Author: N. Hannay
Publisher: Springer Science & Business Media
ISBN: 1468426648
Category : Science
Languages : en
Pages : 788
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Book Description
The last quarter-century has been marked by the extremely rapid growth of the solid-state sciences. They include what is now the largest subfield of physics, and the materials engineering sciences have likewise flourished. And, playing an active role throughout this vast area of science and engineer ing have been very large numbers of chemists. Yet, even though the role of chemistry in the solid-state sciences has been a vital one and the solid-state sciences have, in turn, made enormous contributions to chemical thought, solid-state chemistry has not been recognized by the general body of chemists as a major subfield of chemistry. Solid-state chemistry is not even well defined as to content. Some, for example, would have it include only the quantum chemistry of solids and would reject thermodynamics and phase equilibria; this is nonsense. Solid-state chemistry has many facets, and one of the purposes of this Treatise is to help define the field. Perhaps the most general characteristic of solid-state chemistry, and one which helps differentiate it from solid-state physics, is its focus on the chemical composition and atomic configuration of real solids and on the relationship of composition and structure to the chemical and physical properties of the solid. Real solids are usually extremely complex and exhibit almost infinite variety in their compositional and structural features.
Author: Paul Hagenmuller
Publisher: Elsevier
ISBN: 1483191656
Category : Science
Languages : en
Pages : 570
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Book Description
Solid Electrolytes: General Principles, Characterization, Materials, Applications presents specific theories and experimental methods in the field of superionic conductors. It discusses that high ionic conductivity in solids requires specific structural and energetic conditions. It addresses the problems involved in the study and use of solid electrolytes. Some of the topics covered in the book are the introduction to the theory of solid electrolytes; macroscopic evidence for liquid nature; structural models; kinetic models; crystal structures and fast ionic conduction; interstitial motion in body-centered cubic structures; and materials with the fluorite and antifluorite structures. The diffraction studies of superionic conductors are covered. The significance of defects and disorder to ionic conductivity are discussed. The text describes the transport mechanisms and lattice defects. A study of the diffusion and ionic conductivity equations is presented. A chapter is devoted to the quasi-elastic neutron scattering. Another section focuses on the complex conductivity in the microwave range. The book can provide useful information to scientists, physicists, students, and researchers.
Author: Aaron Wold
Publisher: Springer Science & Business Media
ISBN: 9780412036217
Category : Science
Languages : en
Pages : 270
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Book Description
The subject matterofsolid state chemistry lies within the spheres ofboth physical and inorganic chemistry. In addition, there is a large overlap with solid state physics and materials engineering. However, solid state chemistry has still to be recognized by the general body ofchemists as a legitimate subfield ofchemistry. The discipline is not even well defined as to content and has many facets that make writing a textbook a formidable task. The early studies carried out in the United States by Roland Ward and his co workers emphasized the synthesisofnew materials and the determination oftheir structure. His work on doped alkaline earth sulfides formed the basis for the development of infrared phosphors and his pioneering studies on oxides were important in understanding the structural features of both the perovskite oxides as well as the magnetoplumbites. In 1945, A. F. Wells published the first edition of Structural Inorganic Chemistry. This work attempts to demonstrate that the synthesis, structure, and properties of solids form an important part of inorganic chemistry. Now, after almost 50 years during which many notable advances have been made in solid state chemistry, it is still evident that the synthesis, structure determination, and properties of solids receive little attention in most treatments of inorganic chemistry. The development of the field since the early studies of Roland Ward (early 1940s) has been rapid.
Author: BRACCINI Muriel
Publisher: Lavoisier
ISBN: 2746275511
Category :
Languages : en
Pages : 274
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Book Description
Cet ouvrage rassemble différentes contributions autour des problèmes de mécanique posés par les interfaces solide/solide. Que ce soit dans les matériaux traditionnels (alliages polyphasés, composites) ou dans les nouvelles technologies (couches minces, nano- et micro-dispositifs) les interfaces sont omniprésentes et conditionnent souvent le fonctionnement optimal de ces structures multi-constituées. Les différents aspects abordés ont pour objectif d'apporter les notions de base nécessaires à l'étude et à la compréhension des états de déformation et de contrainte au voisinage des interfaces dans les matériaux hétérogènes et leurs conséquences pratiques. Cet ouvrage s'adresse aux ingénieurs confrontés à des problèmes spécifiques dus aux effets d'hétérogénéités ainsi qu'aux chercheurs scientifiques abordant les problèmes fondamentaux liés à l'influence d'une interface sur le comportement mécanique d'un élément de matière hétérogène. Il pourra également être utile aux étudiants d'école d'ingénieur, de master et de doctorat en physique de la matière condensée ou en science et génie des matériaux.
Author: Lesley E. Smart
Publisher: CRC Press
ISBN: 9780748740680
Category : Science
Languages : en
Pages : 412
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Book Description
Intended for first- and second-year undergraduates, this introduction to solid-state chemistry includes practical examples of applications and modern developments to offer students the opportunity to apply their knowledge in real-life situations. It aims to provide students with a thorough understanding of the traditional knowledge of crystal structures: lattices, unit cells, close packing, and octahedral and tetrahedral holes and their occupation by various ions in the well-known crystal structures. This descriptive work is augmented by free-electron and band theory. Links to other branches of chemistry and practical examples are emphasized, as are the links back to band theory and crystal structures. For this second edition, the book has been updated throughout and has two new chapters, one on X-ray diffraction techniques and another on solid-state preparative methods, as well as new sections on symmetry and ferroelectrics.
Author: Poul Hagenmuller
Publisher: Elsevier
ISBN: 0323144055
Category : Science
Languages : en
Pages : 646
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Book Description
Inorganic Solid Fluorides: Chemistry and Physics deals with the chemical and physical properties of inorganic solid fluorides and covers topics ranging from methods used in the preparation of fluorides to the crystal chemistry of fluorides and transition metal oxyfluorides. Defects in solid fluorides are also discussed, along with fluorine intercalation compounds of graphite and high oxidation states in fluorine chemistry. This book is comprised of 21 chapters and begins with an overview of general trends related to fluorides, including bonding problems and economic implications of fluorides. Some of the methods for the synthesis of inorganic solid fluorides are then described, including gas-phase reactions, reactions in solution, gas-solid reactions, and partial or all solid-state reactions. Subsequent chapters explore the properties of fluoride glasses; ferromagnetism and ferrimagnetism in fluorides; competing spin interactions and frustration effects in fluorides; and electronic conduction in fluorides. Fast fluorine ion conductors and nonlinear properties of fluorides are also considered. The final chapter is devoted to industrial uses of inorganic fluorides. This monograph should be of interest to physicists and inorganic chemists as well as students of physics and inorganic chemistry.
Author: N. Hannay
Publisher: Springer Science & Business Media
ISBN: 1468480820
Category : Science
Languages : en
Pages : 731
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Book Description
The last quarter-century has been marked by the extremely rapid growth of the solid-state sciences. They include what is now the largest subfield of physics, and the materials engineering sciences have likewise flourished. And, playing an active role throughout this vast area of science and engineer ing have been very large numbers of chemists. Yet, even though the role of chemistry in the solid-state sciences has been a vital one and the solid-state sciences have, in turn, made enormous contributions to chemical thought, solid-state chemistry has not been recognized by the general body of chemists as a major subfield of chemistry. Solid-state chemistry is not even well defined as to content. Some, for example, would have it include only the quantum chemistry of solids and would reject thermodynamics and phase equilibria; this is nonsense. Solid-state chemistry has many facets, and one of the purposes of this Treatise is to help define the field. Perhaps the most general characteristic of solid-state chemistry, and one which helps differentiate it from solid-state physics, is its focus on the chemical composition and atomic configuration of real solids and on the relationship of composition and structure to the chemical and physical properties of the solid. Real solids are usually extremely complex and exhibit almost infinite variety in their compositional and structural features.
Author:
Publisher:
ISBN:
Category : Chemistry
Languages : en
Pages : 1028
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Book Description
