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Author: Byung Chan Eu
Publisher:
ISBN: 9789813226067
Category :
Languages : en
Pages : 653
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Book Description
Author: Byung Chan Eu
Publisher:
ISBN: 9789813226067
Category :
Languages : en
Pages : 653
Get Book Here
Book Description
Author: Byung Chan Eu
Publisher: World Scientific Publishing Company
ISBN: 9813226072
Category : Technology & Engineering
Languages : en
Pages : 630
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Book Description
This book enables the reader to learn, in a single volume, equilibrium and nonequilibrium thermodynamics as well as generalized forms of hydrodynamics for linear and nonlinear processes applied to various hydrodynamic flow processes — including chemical oscillation phenomena and pattern formations, shock wave phenomena, sound wave propagations, and Liesegang pattern formation, amongst others.Chemical Thermodynamics introduces advanced undergraduate students and graduate students to the fundamental ideas and notions of the first and second laws of thermodynamics by seamlessly combining equilibrium and nonequilibrium thermodynamics in a unicameral viewpoint based on the first and second law of thermodynamics. Part I of the book discusses equilibrium thermodynamics in historical deference, covering topics generally dealt with in traditional equilibrium thermodynamics. In Part II, the concept of entropy for reversible processes is extended and developed for thermodynamics of irreversible processes by using the concept of calortropy (heat evolution), so that the mathematical theory of macroscopic processes in matter, including a generalized form of hydrodynamics, is ensured to remain consistent with the thermodynamic laws.
Author: Leonard K. Nash
Publisher: Courier Corporation
ISBN: 0486151840
Category : Science
Languages : en
Pages : 271
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Book Description
This text addresses the use of purely thermal data in calculating the position of equilibrium in a chemical reaction. Its argument highlights the physical content of thermodynamics, as distinct from purely mathematical aspects. Methods are limited to a very few of the most elementary operations of the calculus, all of which are explained in an appendix. Readers need no more than a sound background in high school mathematics and physics, as well as some familiarity with the leading quantitative concepts of an introductory college chemistry course. An introduction establishes the fundamentals of temperature, heat and work, reversibility, and pressure-volume work. The first principle of thermodynamics is explored in terms of energy, enthalpy, thermochemistry and Hess's Law, heat capacity, Kirchhoff's equations, and adiabatic processes. Considerations of the second principle of thermodynamics encompass the Carnot cycle, the concept of entropy, and evaluation of entropy changes. The consequences of thermodynamic principles are examined in chapters on the free energies, the Clapeyron equation, ideal solutions and colligative properties, and the equilibrium state and equilibrium constant. Numerous problems appear throughout the text, in addition to 30 fully worked illustrative examples.
Author: Byung Chan Eu
Publisher: World Scientific
ISBN: 9814295116
Category : Science
Languages : en
Pages : 467
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Book Description
Thermodynamics is an ever evolving subject. This book aims to introduce to advanced undergraduate students and graduate students the fundamental ideas and notions of the first and second laws of thermodynamics in a manner unavailable in the usual textbooks on the subject of thermodynamics. For example, it treats the notions of unavailable work, compensated and uncompensated heats, and dissipation, which make it possible to formulate the thermodynamic laws in more broadened forms than those in the conventional treatment of equilibrium thermodynamics. It thus strives to prepare students for more advanced subjects of irreversible processes, which are encountered in our everyday scientific activities. In addition, it also aims to provide them with functional and practical knowledge of equilibrium chemical thermodynamics of reversible processes in real fluids. It discusses temperature, work and heat, thermodynamic laws, equilibrium conditions and thermodynamic stability, thermodynamics of reversible processes in gases and liquids, in surfaces, chemical equilibria, reversible processes in electrolyte solutions and dielectrics in static electric and magnetic fields. A couple of examples for irreversible processes associated with fluid flows and chemical pattern formation and wave propagations are discussed as examples for applications of broader treatments of the thermodynamic laws in the realm of irreversible phenomena.
Author: J. Rajaram
Publisher: Pearson Education India
ISBN: 933252016X
Category :
Languages : en
Pages : 697
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Book Description
Aimed at providing undergraduate and postgraduate students with an understanding of this subject, the book brings out the thermodynamic interrelationships by explaining its essential elements. It begins with the fundamentals and progresses to advanced concepts to enable students to appreciate the application of thermodynamics in different areas of chemistry. Chemical Thermodynamics is written in a simple and lucid language, the discussion and explanations being interspersed with appropriate worked-out examples. Every chapter is accompanied by adequate end-of-chapter exercises.
Author: Katrine Seip Førland
Publisher: John Wiley & Sons
ISBN:
Category : Science
Languages : en
Pages : 304
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Book Description
Irreversible thermodynamics is an extension of classical thermodynamics to give a unified method of treating transport processes. This book develops the theoretical basis and relates it to reality by examples. These theories are then applied to solve some important problems within varied fields of science and technology. To facilitate understanding, the basic equations are derived in a simple manner, using a minimum of mathematics.
Author: David Jou
Publisher: Springer Science & Business Media
ISBN: 3642974309
Category : Science
Languages : en
Pages : 320
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Book Description
Classical irreversible thermodynamics, as developed by Onsager, Prigogine and many other authors, is based on the local-equilibrium hypothesis. Out of equilibrium, any system is assumed to depend locally on the same set of variables as when it is in eqUilibrium. This leads to a formal thermody namic structure identical to that of eqUilibrium: intensive parameters such as temperature, pressure and chemical potentials are well-defined quantities keeping their usual meaning, thermodynamic potentials are derived as Leg endre transformations and all equilibrium thermodynamic relations retain their validity. The theory based on this hypothesis has turned out to be very useful and has achieved a number of successes in many practical situations. of interest in going However, the recent decade has witnessed a surge beyond the classical formulation. There are several reasons for this. One of them is the development of experimental methods able to deal with the response of systems to high-frequency and short-wavelength perturbations, such as ultrasound propagation and light and neutron scattering. The ob served results have led to generalizations of the classical hydrodynamical theories, by including memory functions or generalized transport coefficients depending on the frequency and the wavevector. This field has generated impressive progress in non-equilibrium statistical mechanics, but for the moment it has not brought about a parallel development in non-equilibrium thermodynamics. An extension of thermodynamics compatible with gener alized hydrodynamics therefore appears to be a natural subject of research.
Author: D. Winterbone
Publisher: Butterworth-Heinemann
ISBN: 0080523366
Category : Science
Languages : en
Pages : 399
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Book Description
Although the basic theories of thermodynamics are adequately covered by a number of existing texts, there is little literature that addresses more advanced topics. In this comprehensive work the author redresses this balance, drawing on his twenty-five years of experience of teaching thermodynamics at undergraduate and postgraduate level, to produce a definitive text to cover thoroughly, advanced syllabuses. The book introduces the basic concepts which apply over the whole range of new technologies, considering: a new approach to cycles, enabling their irreversibility to be taken into account; a detailed study of combustion to show how the chemical energy in a fuel is converted into thermal energy and emissions; an analysis of fuel cells to give an understanding of the direct conversion of chemical energy to electrical power; a detailed study of property relationships to enable more sophisticated analyses to be made of both high and low temperature plant and irreversible thermodynamics, whose principles might hold a key to new ways of efficiently covering energy to power (e.g. solar energy, fuel cells). Worked examples are included in most of the chapters, followed by exercises with solutions. By developing thermodynamics from an explicitly equilibrium perspective, showing how all systems attempt to reach a state of equilibrium, and the effects of these systems when they cannot, the result is an unparalleled insight into the more advanced considerations when converting any form of energy into power, that will prove invaluable to students and professional engineers of all disciplines.
Author: Milo D. Koretsky
Publisher: John Wiley & Sons
ISBN: 0470259612
Category : Technology & Engineering
Languages : en
Pages : 724
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Book Description
Chemical engineers face the challenge of learning the difficult concept and application of entropy and the 2nd Law of Thermodynamics. By following a visual approach and offering qualitative discussions of the role of molecular interactions, Koretsky helps them understand and visualize thermodynamics. Highlighted examples show how the material is applied in the real world. Expanded coverage includes biological content and examples, the Equation of State approach for both liquid and vapor phases in VLE, and the practical side of the 2nd Law. Engineers will then be able to use this resource as the basis for more advanced concepts.
Author: A.P.H. Peters
Publisher: CRC Press
ISBN: 020349427X
Category : Science
Languages : en
Pages : 216
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Book Description
The first edition of Concise Chemical Thermodynamics proved to be a very popular introduction to a subject many undergraduate students perceive as a difficult topic, because it presented thermodynamics with practical chemical examples in a way that used little mathematics. In this second edition the text has been carefully revised to ensure the same approach is maintained. Students are led to an understanding of Gibbs free energy early on, and the concept is demonstrated in several different fields. The book includes discussions of experimental equilibrium data, an introduction to electrochemistry, a brief survey of Ellingham diagrams, and a treatment of entropy without reference to the Carnot cycle. A new chapter on computer-based methods in thermodynamics has been added to reflect current technological trends and practices. Thermodynamic data has been revised in light of information provided by the work of the Scientific Group Thermodata Europe, to ensure that the symbols and units reflect the latest IUPAC rules. In addition, the problems and examples have been updated, replaced, and amplified to reflect current understanding and concerns. Undergraduate students of chemistry will find this an ideal introduction to chemical thermodynamics.
