Chemical Physics of Liquids PDF Download
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Author: Norman Henry March
Publisher: CRC Press
ISBN: 9782881247224
Category : Science
Languages : en
Pages : 344
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Book Description
A full discussion of liquid structure theories for simple monoatomic liquids such as liquid argon or liquid lead is followed by discussion of both the structure of diatomic fluids such as liquid nitrogen and of molten salts. There are chapters on the thermodynamics and structure of electrolytes, on atomic transport, neutron scattering and time-dependent correlation functions, as well as treatment of chemical reactions in solution, beginning with a discussion of stochastic equations. Book club price, $85. Annotation copyrighted by Book News, Inc., Portland, OR
Author: Norman Henry March
Publisher: CRC Press
ISBN: 9782881247224
Category : Science
Languages : en
Pages : 344
Get Book Here
Book Description
A full discussion of liquid structure theories for simple monoatomic liquids such as liquid argon or liquid lead is followed by discussion of both the structure of diatomic fluids such as liquid nitrogen and of molten salts. There are chapters on the thermodynamics and structure of electrolytes, on atomic transport, neutron scattering and time-dependent correlation functions, as well as treatment of chemical reactions in solution, beginning with a discussion of stochastic equations. Book club price, $85. Annotation copyrighted by Book News, Inc., Portland, OR
Author: Makoto Yasutomi
Publisher: CRC Press
ISBN: 1000091627
Category : Science
Languages : en
Pages : 187
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Book Description
Unraveling the mystery of the negative thermal expansion of liquid water has been a challenge for scientists for centuries. Various theories have been proposed so far, but none has been able to solve this mystery. Since the thermodynamic properties of matter are determined by the interaction between particles, the mystery can be solved fundamentally if the thermodynamic physical quantities using the laws of thermodynamics and statistical mechanics are determined, the experimental results are reproduced, and the phenomena in relation to the shape of the interaction between particles are elucidated. In this sense, this book has fundamentally unraveled this mystery. In addition, it discusses the mysteries of isothermal compressibility, structural diversity, as well as liquefaction and boiling points of water in relation to the shape of the interaction between particles. It carefully explains the analysis and calculation methods so that they can be easily understood by the readers.
Author: Kazuya Saito
Publisher: Springer Nature
ISBN: 9811590230
Category : Science
Languages : en
Pages : 228
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Book Description
This book fills a gap in knowledge between chemistry- and physics-trained researchers about the properties of macroscopic (bulk) material. Although many good textbooks are available on solid-state (or condensed matter) physics, they generally treat simple systems such as simple metals and crystals consisting of atoms. On the other hand, textbooks on solid-state chemistry often avoid descriptions of theoretical background even at the simplest level. This book gives coherent descriptions from intermolecular interaction up to properties of condensed matter ranging from isotropic liquids to molecular crystals. By omitting details of specific systems for which comprehensive monographs are available—on liquid crystals and molecular conductors, for instance—this book highlights the effects of molecular properties, i.e., the presence of the shape and its deformation on the structure and properties of molecular systems.
Author: Shankar Prasad Das
Publisher: Cambridge University Press
ISBN: 1139500678
Category : Science
Languages : en
Pages : 585
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Book Description
Exploring important theories for understanding freezing and the liquid-glass transition, this book is useful for graduate students and researchers in soft-condensed matter physics, chemical physics and materials science. It details recent ideas and key developments, providing an up-to-date view of current understanding. The standard tools of statistical physics for the dense liquid state are covered. The freezing transition is described from the classical density functional approach. Classical nucleation theory as well as applications of density functional methods for nucleation of crystals from the melt are discussed, and compared to results from computer simulation of simple systems. Discussions of supercooled liquids form a major part of the book. Theories of slow dynamics and the dynamical heterogeneities of the glassy state are presented, as well as nonequilibrium dynamics and thermodynamic phase transitions at deep supercooling. Mathematical treatments are given in full detail so readers can learn the basic techniques.
Author: Biman Bagchi
Publisher: Oxford University Press
ISBN: 0199863334
Category : Science
Languages : en
Pages : 331
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Book Description
This book brings together many different relaxation phenomena in liquids under a common umbrella and provides a unified view of apparently diverse phenomena. It aligns recent experimental results obtained with modern techniques with recent theoretical developments. Such close interaction between experiment and theory in this area goes back to the works of Einstein, Smoluchowski, Kramers' and de Gennes. Development of ultrafast laser spectroscopy recently allowed study of various relaxation processes directly in the time domain, with time scales going down to picosecond (ps) and femtosecond (fs) time scales. This was a remarkable advance because many of the fundamental chemical processes occur precisely in this range and was inaccessible before the 1980s. Since then, an enormous wealth of information has been generated by many groups around the world, who have discovered many interesting phenomena that has fueled further growth in this field. As emphasized throughout the book, the seemingly different phenomena studied in this area are often closely related at a fundamental level. Biman Bagchi explains why relatively small although fairly sophisticated theoretical tools have been successful in explaining a wealth of experimental data at a semi-phenomenological level.
Author: Jean-Louis Barrat
Publisher: Cambridge University Press
ISBN: 9780521789530
Category : Science
Languages : en
Pages : 410
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Book Description
Presenting a unified approach, this book focusses on the concepts and theoretical methods that are necessary for an understanding of the physics and chemistry of the fluid state. The authors do not attempt to cover the whole field in an encyclopedic manner. Instead, important ideas are presented in a concise and rigorous style, and illustrated with examples from both simple molecular liquids and more complex soft condensed matter systems such as polymers, colloids, and liquid crystals.
Author: H. Eugene Stanley
Publisher: Wiley
ISBN: 9781118453445
Category : Science
Languages : en
Pages : 652
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Book Description
The Advances in Chemical Physics series—thecutting edge of research in chemical physics The Advances in Chemical Physics series provides the chemicalphysics and physical chemistry fields with a forum for critical,authoritative evaluations of advances in every area of thediscipline. Filled with cutting-edge research reported in acohesive manner not found elsewhere in the literature, each volumeof the Advances in Chemical Physics series presents contributionsfrom internationally renowned chemists and serves as the perfectsupplement to any advanced graduate class devoted to the study ofchemical physics. This volume explores: Electron Spin Resonance Studies of Supercooled Water Water-like Anomalies of Core-Softened Fluids: Dependence on theTrajectories in (P, ϱ, T) Space Water Proton Environment: A New Water Anomaly at AtomicScale? Polymorphism and Anomalous Melting in Isotropic Fluids Computer Simulations of Liquid Silica: Water-Like Thermodynamicand Dynamic Anomalies, and the Evidence for Polyamorphism
Author: Felix Franks
Publisher: Springer Science & Business Media
ISBN: 146848334X
Category : Science
Languages : en
Pages : 610
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Book Description
to arrive at some temporary consensus model or models; and to present reliable physical data pertaining to water under a range of conditions, i.e., "Dorsey revisited," albeit on a less ambitious scale. I should like to acknowledge a debt of gratitude to several of my col leagues, to Prof. D. J. G. Ives and Prof. Robert L. Kay for valuable guidance and active encouragement, to the contributors to this volume for their willing cooperation, and to my wife and daughters for the understanding shown to a husband and father who hid in his study for many an evening. My very special thanks go to Mrs. Joyce Johnson, who did all the cor respondence and much of the arduous editorial work with her usual cheerful efficiency. F. FRANKS Biophysics Division Unilever Research Laboratory ColworthjWelwyn Colworth House, Sharnbrook, Bedford March 1972 Contents Chapter 1 Introduction-Water, the Unique Chemical F. Franks I. lntroduction ........................................ . 2. The Occurrence and Distribution of Water on the Earth 2 3. Water and Life ...................................... 4 4. The Scientific Study of Water-A Short History ........ 8 5. The Place of Water among Liquids . . . . . . . . . . . . . . . 13 . . . . . Chapter 2 The Water Moleeule C. W. Kern and M. Karplus 1. Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21 . . . . . . . . . . 2. Principles of Structure and Spectra: The Born-Oppenheimer Separation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22 . . . . . . . . . . . . 3. The Electronic Motion ............................... 26 3.1. The Ground Electronic State of Water ............ 31 3.2. The Excited Electronic States of Water ........... 50 4. The Nuclear Motion ................................. 52 5. External-Field Effects ................................. 70 5.1. Perturbed Hartree-Fock Method . . . . . . . . . . . . . . . 74 . . .
Author: W. Ronald Fawcett
Publisher: Oxford University Press
ISBN: 0195094328
Category : Language Arts & Disciplines
Languages : en
Pages : 638
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Book Description
Fawcett (chemistry, University of California-Davis) introduces modern topics in solution chemistry to senior undergraduates and graduate students who have completed two semesters or three quarters of chemical thermodynamics and statistical mechanics.
Author: Jean-Pierre Hansen
Publisher: Elsevier
ISBN: 0080571018
Category : Science
Languages : en
Pages : 569
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Book Description
This book gives a comprehensive and up-to-date treatment of the theory of "simple" liquids. The new second edition has been rearranged and considerably expanded to give a balanced account both of basic theory and of the advances of the past decade. It presents the main ideas of modern liquid state theory in a way that is both pedagogical and self-contained. The book should be accessible to graduate students and research workers, both experimentalists and theorists, who have a good background in elementary mechanics. - Compares theoretical deductions with experimental results - Molecular dynamics - Monte Carlo computations - Covers ionic, metallic, and molecular liquids
