Chemical Looping Combustion in Interconnected Fluidized Bed Reactors - Simulation and Experimental Validation

Chemical Looping Combustion in Interconnected Fluidized Bed Reactors - Simulation and Experimental Validation PDF Author: Marvin Kramp
Publisher:
ISBN: 9783843918039
Category :
Languages : de
Pages : 181

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Chemical Looping Combustion in Interconnected Fluidized Bed Reactors - Simulation and Experimental Validation

Chemical Looping Combustion in Interconnected Fluidized Bed Reactors - Simulation and Experimental Validation PDF Author: Marvin Kramp
Publisher:
ISBN: 9783843918039
Category :
Languages : de
Pages : 181

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Dynamic Simulation of the Chemical Looping Combustion Process

Dynamic Simulation of the Chemical Looping Combustion Process PDF Author: Johannes Haus
Publisher: Cuvillier Verlag
ISBN: 3736963351
Category : Technology & Engineering
Languages : en
Pages : 140

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Book Description
In this Ph.D. thesis a system of coupled fluidized bed reactors is modelled and simulated dynamically. Chemical Looping Combustion was used as an exemplary process in both the numerical and the experimental part of this work. For the simulation purpose a novel flowsheeting software was used and models for the needed process units developed and integrated into this software. The needed unit models were three interconnected fluidized bed reactors in circulating and bubbling operation conditions, a cyclone for gas-solid separation and loop seals, which ensured solids transport and gas separation between the reactors. Additionally, lab scale experiments on the reactivity of the used solids, oxygen carrier and solid fuels, were conducted and kinetic parameters extracted. All unit models were connected to a process flowsheet and simulated dynamically. The simulation results were compared to experimental data from a 25 kWth pilot plant operated at the university by the author. It could be shown that a detailed and dynamic simulation of the whole process can be carried out over a time period of more than 45 minutes and the experimental results from start-up, steady state operation and shutdown of the plant were predicted accurately.

Computational Fluid Dynamics Modeling and Simulations of Fluidized Bed Reactors for Chemical Looping Combustion

Computational Fluid Dynamics Modeling and Simulations of Fluidized Bed Reactors for Chemical Looping Combustion PDF Author: Subhodeep Banerjee
Publisher:
ISBN:
Category : Electronic dissertations
Languages : en
Pages : 102

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Book Description
Chemical looping combustion (CLC) is a next generation combustion technology that shows great promise as a solution for the need of high-efficiency low-cost carbon capture from fossil fueled power plants. To realize this technology on an industrial scale, the development of high-fidelity simulations is a necessary step to develop a thorough understanding of the CLC process. Although there have been a number of experimental studies on CLC in recent years, CFD simulations have been limited in the literature.In this dissertation, reacting flow simulations of a CLC reactor are developed using the Eulerian approach based on a laboratory-scale experiment of a dual fluidized bed CLC system. The salient features of the fluidization behavior in the air reactor and fuel reactor beds representing a riser and a bubbling bed respectively are accurately captured in the simulation. This work is one of the first 3-D simulations of a complete circulating dual fluidized bed system; it highlights the importance of conducting 3-D simulations of CLC systems and the need for more accurate empirical reaction rate data for future CLC simulations.Simulations of the multiphase flow with chemical reactions in a spouted bed fuel reactor for coal-direct CLC are performed based on the Lagrangian particle tracking approach. The Discrete Element Method (DEM) provides the means for tracking the motion of individual metal oxide particles in the CLC system as they react with the fuel and is coupled with CFD for capturing the solid-gas multiphase hydrodynamics. The overall results of the coupled CFD-DEM simulations using Fe-based oxygen carriers reacting with gaseous CH4 demonstrate that chemical reactions have been successfully incorporated into the CFD-DEM approach. The simulations show a strong dependence of the fluidization performance of the fuel reactor on the density of bed material and provide important insight into selecting the right oxygen carrier for the enhanced performance.Given the high computing cost of CFD-DEM, it is necessary to develop a scaling methodology based on the principles of dynamic similarity that can be applied to expand the scope of this approach to larger CLC systems up to the industrial scale. A new scaling methodology based on the terminal velocity is proposed for spouted fluidized beds. Simulations of a laboratory-scale spouted fluidized bed are used to characterize the performance of the new scaling law in comparison with existing scaling laws in the literature. It is shown that the new model improves the accuracy of the simulation results compared to the other scaling methodologies while also providing the largest reduction in the number of particles and in turn in the computing cost.CFD-DEM simulations are conducted of the binary particle bed associated with a coal-direct CLC system consisting of coal (represented by plastic beads) and oxygen carrier particles and validated against an experimental riser-based carbon stripper. The simulation results of the particle behavior and the separation ratio of the particles are in excellent agreement with the experiment. A credible simulation of a binary particle bed is of particular importance for understanding the details of the fluidization behavior; the baseline simulation established in this work can be used as a tool for designing and optimizing the performance of such systems.The simulations conducted in this dissertation provide a strong foundation for future simulations of CD-CLC systems using solid coal as fuel, considering the additional complexities associated with the changing density and diameter of the coal particles as devolatilization and gasification process occur. A complete reacting flow simulation in the CFD-DEM framework will be crucial for the successful deployment of CD-CLC technology from the laboratory scale to pilot and industrial scale projects.

Handbook of Chemical Looping Technology

Handbook of Chemical Looping Technology PDF Author: Ronald W. Breault
Publisher: John Wiley & Sons
ISBN: 3527342028
Category : Business & Economics
Languages : en
Pages : 488

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Book Description
This comprehensive and up-to-date handbook on this highly topical field, covering everything from new process concepts to commercial applications. Describing novel developments as well as established methods, the authors start with the evaluation of different oxygen carriers and subsequently illuminate various technological concepts for the energy conversion process. They then go on to discuss the potential for commercial applications in gaseous, coal, and fuel combustion processes in industry. The result is an invaluable source for every scientist in the field, from inorganic chemists in academia to chemical engineers in industry.

Modeling and Simulation of Fluidized Bed Reactors for Chemical Looping Combustion

Modeling and Simulation of Fluidized Bed Reactors for Chemical Looping Combustion PDF Author: Ramesh K. Agarwal
Publisher: Springer
ISBN: 9783031113345
Category : Technology & Engineering
Languages : en
Pages : 0

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Book Description
The book describes the clean coal technology of chemical looping combustion (CLC) for power generation with pure CO2 capture. The focus of the book is on the modeling and simulation of CLC. It includes fundamental concepts behind CLC and considers all categories of fluidized beds and reactors, including a variety of oxygen carriers. The book includes process simulations with Aspen PlusĀ® software using coal, natural gas, and biomass and computational fluid dynamics (CFD) simulations using both the Eulerian and Lagrangian methods. It describes various drag models, turbulence models, and kinetics models required for CFD simulations of CLC and covers single reactor, partial, and full-simulations, single/multi-stage as well as single-particle simulations, and CLC with reverse flow. A large number of examples for both process simulations using Aspen Plus and CFD simulations using a variety of fluidized beds/reactors employing both the two-fluid and Computational Fluid Dynamics / Discrete Element Method (CFD-DEM) model are provided. Modeling and Simulation of Fluidized Bed Reactors for Chemical Looping Combustion will be an invaluable reference for industry practitioners and researchers in academic and industrial R&D currently working on clean energy technologies and power generation with carbon capture.

Operation of a System of Interconnected Fluidized Bed Reactors in the Chemical Looping Combustion Process

Operation of a System of Interconnected Fluidized Bed Reactors in the Chemical Looping Combustion Process PDF Author:
Publisher:
ISBN: 9783736946880
Category :
Languages : en
Pages : 0

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Operation of a System of Interconnected Fluidized Bed Reactors in the Chemical Looping Combustion Process

Operation of a System of Interconnected Fluidized Bed Reactors in the Chemical Looping Combustion Process PDF Author: Andreas Thon
Publisher:
ISBN: 9783954046881
Category :
Languages : en
Pages : 196

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Coal and Biomass Gasification

Coal and Biomass Gasification PDF Author: Santanu De
Publisher: Springer
ISBN: 981107335X
Category : Technology & Engineering
Languages : en
Pages : 524

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Book Description
This book addresses the science and technology of the gasification process and the production of electricity, synthetic fuels and other useful chemicals. Pursuing a holistic approach, it covers the fundamentals of gasification and its various applications. In addition to discussing recent advances and outlining future directions, it covers advanced topics such as underground coal gasification and chemical looping combustion, and describes the state-of-the-art experimental techniques, modeling and numerical simulations, environmentally friendly approaches, and technological challenges involved. Written in an easy-to-understand format with a comprehensive glossary and bibliography, the book offers an ideal reference guide to coal and biomass gasification for beginners, engineers and researchers involved in designing or operating gasification plants.

Dynamic Flowsheet Simulation of Solids Processes

Dynamic Flowsheet Simulation of Solids Processes PDF Author: Stefan Heinrich
Publisher: Springer Nature
ISBN: 3030451682
Category : Science
Languages : en
Pages : 626

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Book Description
This book presents the latest advances in flowsheet simulation of solids processes, focusing on the dynamic behaviour of systems with interconnected solids processing units, but also covering stationary simulation. The book includes the modelling of solids processing units, for example for comminution, sifting and particle formulation and also for reaction systems. Furthermore, it examines new approaches for the description of solids and their property distributions and for the mathematical treatment of flowsheets with multivariate population balances.

Fluidized Bed Technologies for Near-Zero Emission Combustion and Gasification

Fluidized Bed Technologies for Near-Zero Emission Combustion and Gasification PDF Author: Fabrizio Scala
Publisher: Elsevier
ISBN: 0857098802
Category : Technology & Engineering
Languages : en
Pages : 1091

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Book Description
Fluidized bed (FB) combustion and gasification are advanced techniques for fuel flexible, high efficiency and low emission conversion. Fuels are combusted or gasified as a fluidized bed suspended by jets with sorbents that remove harmful emissions such as SOx. CO2 capture can also be incorporated. Fluidized bed technologies for near-zero emission combustion and gasification provides an overview of established FB technologies while also detailing recent developments in the field. Part one, an introductory section, reviews fluidization science and FB technologies and includes chapters on particle characterization and behaviour, properties of stationary and circulating fluidized beds, heat and mass transfer and attrition in FB combustion and gasification systems. Part two expands on this introduction to explore the fundamentals of FB combustion and gasification including the conversion of solid, liquid and gaseous fuels, pollutant emission and reactor design and scale up. Part three highlights recent advances in a variety of FB combustion and gasification technologies before part four moves on to focus on emerging CO2 capture technologies. Finally, part five explores other applications of FB technology including (FB) petroleum refining and chemical production. Fluidized bed technologies for near-zero emission combustion and gasification is a technical resource for power plant operators, industrial engineers working with fluidized bed combustion and gasification systems and researchers, scientists and academics in the field. Examines the fundamentals of fluidized bed (FB) technologies, including the conversion of solid, liquid and gaseous fuels Explores recent advances in a variety of technologies such as pressurized FB combustion, and the measurement, monitoring and control of FB combustion and gasification Discusses emerging technologies and examines applications of FB in other processes