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Author: Gerhard Fritz
Publisher: Springer Science & Business Media
ISBN: 3642708005
Category : Science
Languages : en
Pages : 269
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Book Description
Carbosilanes are compounds in which the elements silicon and carbon alternate in the molecular skeleton [1]. Just as the alkanes are formally derived from the diamond lattice and the aromatics from the graphite lattice, the carbosilanes are structurally derived from silicon carbide. Because of the tetravalent nature of silicon and carbon we can expect stable linear, cyclic and polycyclic compounds to occur. However, carbosilanes do not exist in nature. This book is an attempt to give a summarized presentation. Carbosilanes are, of course, part" of organosilicon chemistry, but their behavior differentiates them distinctly from other organosilicon compounds. The differences result primarily from the alternating Si-C-Si arrangements in the molecular skeleton, and especially the various methylene bridges (CH , CHX, CX ; X = halogen) cause changes in z z Si-C bond polarization and hence influence the reaction possibilities. It is convenient to regard carbosilanes as similar to silicones except that the oxygen bridges of silicones are replaced by methylene units. However, this does not accurately account for all the chemical properties of these compounds. Carbosilanes are related more directly to silicon carbide, as shown occasionally by the reactive behavior of polycyclic car bosilanes. Therefore, in view of the present interest shown for thermally stable cera mics of unusual character, interesting possibilities arise for further development. Most cyclic carbosilanes can be classified in two groups: the carborundanes and the Si-scaphanes. Compounds belonging to the carborundane class maintain Si-C six-membered rings in the boat conformation.
Author: Gerhard Fritz
Publisher: Springer Science & Business Media
ISBN: 3642708005
Category : Science
Languages : en
Pages : 269
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Book Description
Carbosilanes are compounds in which the elements silicon and carbon alternate in the molecular skeleton [1]. Just as the alkanes are formally derived from the diamond lattice and the aromatics from the graphite lattice, the carbosilanes are structurally derived from silicon carbide. Because of the tetravalent nature of silicon and carbon we can expect stable linear, cyclic and polycyclic compounds to occur. However, carbosilanes do not exist in nature. This book is an attempt to give a summarized presentation. Carbosilanes are, of course, part" of organosilicon chemistry, but their behavior differentiates them distinctly from other organosilicon compounds. The differences result primarily from the alternating Si-C-Si arrangements in the molecular skeleton, and especially the various methylene bridges (CH , CHX, CX ; X = halogen) cause changes in z z Si-C bond polarization and hence influence the reaction possibilities. It is convenient to regard carbosilanes as similar to silicones except that the oxygen bridges of silicones are replaced by methylene units. However, this does not accurately account for all the chemical properties of these compounds. Carbosilanes are related more directly to silicon carbide, as shown occasionally by the reactive behavior of polycyclic car bosilanes. Therefore, in view of the present interest shown for thermally stable cera mics of unusual character, interesting possibilities arise for further development. Most cyclic carbosilanes can be classified in two groups: the carborundanes and the Si-scaphanes. Compounds belonging to the carborundane class maintain Si-C six-membered rings in the boat conformation.
Author:
Publisher: Academic Press
ISBN: 008057856X
Category : Science
Languages : en
Pages : 459
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Book Description
Advances in Inorganic Chemistry and Radiochemistry
Author: H.R. Kricheldorf
Publisher: Springer Science & Business Media
ISBN: 3642791751
Category : Technology & Engineering
Languages : en
Pages : 507
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Book Description
Silicon in Polymer Synthesis gives the first concise overview of silicon used for the synthesis and modification of polymers. The first section gives an introduction to the topic. The subsequent chapters detail the current status both from the basic research as well as from the industrial application points of view.
Author: R.G. Jones
Publisher: Springer Science & Business Media
ISBN: 9781402003486
Category : Science
Languages : en
Pages : 796
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Book Description
Within this text, for the first time the synthesis, structural characteristics, physical properties, applications and potential applications of polysiloxanes, polycarbosilanes, polysilazanes, polysilanes, and other silicon-containing polymers are detailed. For years to come this book will be the first point of entry for those seeking to learn about the very significant differences that exist between carbon-based polymers and those with silicon in their backbone.
Author: Deborah Chung
Publisher: Elsevier
ISBN: 0080500730
Category : Technology & Engineering
Languages : en
Pages : 229
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Book Description
In Carbon Fiber Composites, the reader is introduced to a wide range of carbon fiber composites, including polymer-matrix, metal matrix, carbon-matrix, ceramic-matrix and hybrid composites. The subject is examined in a tutorial fashion, so that no prior knowledge of the field is required. In contrast to other books on composites, this book emphasizes materials rather than mechanics, as the prominence of composite materials has resulted from their increased presence in applications other than structure. Provides up-to-date information on the entire spectrum of carbon fiber composites Emphasizes processing as the foundation of composite materials development Addresses the processing, properties and applications of each type of material systematically
Author: Gary Savage
Publisher: Springer Science & Business Media
ISBN: 9780412361500
Category : Computers
Languages : en
Pages : 404
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Book Description
Carbon is a material around which a whole branch of science has developed. This book introduces carbon-carbon materials with respect to their relationship to other carbon materials. Each of the major production methods is covered and a chapter is devoted to the susceptibility to oxidation.
Author: J. Tharini
Publisher: Springer Nature
ISBN: 3031487192
Category :
Languages : en
Pages : 300
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Book Description
Author: E. Savage
Publisher: Springer Science & Business Media
ISBN: 9401115869
Category : Technology & Engineering
Languages : en
Pages : 393
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Book Description
Carbon fibre reinforced carbon composites form a very specialized group of materials. They may be considered as a development of the family of carbon fibre reinforced polymer composites which are becoming ever more prevalent in modern engineering. Since the early 1960s a large number of so-called 'advanced materials' have appeared on the scene. Carbon~arbon is arguably the most successful of all these products finding many and varied applications. In the field of Formula 1 motor racing for example, the present levels of performance simply could not be achieved without the use of carbon-carbon brakes and clutches. Despite the materials' obvious assets, they have not, and will not, reach their full potential until their inherent problems of excessive production costs and oxidation resistance have been addressed properly. In this respect the 'carbon-carbon story', of much potential but only limited success, serves as a lesson to all those involved in materials research, development and application. In writing this book I have tried to set up a logical progression of what the materials are, how they are made, what their assets and deficiencies are, what they are used for and to what extent they are commercially exploited. Each specialized chapter may be considered in isolation or as part of a sequence, whereas the final chapter provides a summary of the principal concepts as well as a basic review of the economic situation past, present and, hopefully, future.
Author: Xin Jiang
Publisher: John Wiley & Sons
ISBN: 1119313600
Category : Technology & Engineering
Languages : en
Pages : 304
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Book Description
Connects knowledge about synthesis, properties, and applications of novel carbon materials and carbon-based composites This book provides readers with new knowledge on the synthesis, properties, and applications of novel carbon materials and carbon-based composites, including thin films of silicon carbide, carbon nitrite, and their related composites. It examines the direct bottom-up synthesis of the carbon-based composite systems and their potential applications, and discusses the growth mechanism of the composite structures. It features applications that range from mechanical, electronic, chemical, biochemical, medical, and environmental to functional devices. Novel Carbon Materials and Composites: Synthesis, Properties and Applications covers an overview of the synthesis, properties, and applications of novel carbon materials and composites. Especially, it covers everything from chemical vapor deposition of silicon carbide films and their electrochemical applications to applications of various novel carbon materials for the construction of supercapacitors to chemical vapor deposition of diamond/silicon carbide composite films to the covering and fabrication processes of nanodot composites. Looks at the recent progress and achievements in the fields of novel carbon materials and composites, including thin films of silicon carbide, carbon nitrite, and their related composites Discusses the many applications of carbon materials and composites Focuses on the hot topic of the fabrication of carbon-based composite materials and their abilities to extend the potential applications of carbon materials Published as a title in the new Wiley book series Nanocarbon Chemistry and Interfaces. Novel Carbon Materials and Composites: Synthesis, Properties and Applications is an important book for academic researchers and industrial scientists working in the fabrication and application of carbon materials and carbon-based composite materials and related fields.
Author: Nazario Martin
Publisher: John Wiley & Sons
ISBN: 3527650148
Category : Technology & Engineering
Languages : en
Pages : 421
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Book Description
Collating our current knowledge and the latest developments for enabling breakthrough discoveries, this book focuses on the synthesis and applications of materials that are based on supramolecular assemblies of carbon nanostructures, with an emphasis on fullerenes and nanotubes. In so doing, it provides readers with an overview of the different types of supramolecular architectures, accentuating the outstanding geometrical, electronic and photophysical properties of the building blocks and the resulting structures. It makes use of basic concepts and real-life applications -- from simple syntheses to complex architectures, from instructive examples to working experimental procedures, and from photophysics to solar cells. A large part of each chapter is devoted to the methods and possibilities of controlling and tuning these molecular assemblies in order to obtain working devices. Fascinating reading for materials scientists, organic chemists, molecular physicists, and those in the semiconductor industry.
