Author: Sarah A. Brockbank
Publisher:
ISBN:
Category : Electronic dissertations
Languages : en
Pages : 293
Book Description
Aqueous Henry's Law Constants, Infinite Dilution Activity Coefficients, and Water Solubility: Critically Evaluated Database, Experimental Analysis, and Prediction Methods
Author: Sarah A. Brockbank
Publisher:
ISBN:
Category : Electronic dissertations
Languages : en
Pages : 293
Book Description
Publisher:
ISBN:
Category : Electronic dissertations
Languages : en
Pages : 293
Book Description
The Experimental Determination of Solubilities
Author: G. T. Hefter
Publisher: John Wiley & Sons
ISBN: 0471497088
Category : Science
Languages : en
Pages : 657
Book Description
* Guidelines are provided on the reliability of various methods, as well as information for selecting the appropriate technique. * Unique coverage of the whole range of solubility measurements. * Very useful for investigators interested in embarking upon solubility measurements.
Publisher: John Wiley & Sons
ISBN: 0471497088
Category : Science
Languages : en
Pages : 657
Book Description
* Guidelines are provided on the reliability of various methods, as well as information for selecting the appropriate technique. * Unique coverage of the whole range of solubility measurements. * Very useful for investigators interested in embarking upon solubility measurements.
Evaluation and Prediction of Henry's Law Constants and Aqueous Solubilities for Solvents and Hydrocarbon Fuel Components. Volume 2. Experimental Henry's Law Data
Author: G. B. Howe
Publisher:
ISBN:
Category :
Languages : en
Pages : 372
Book Description
Laboratory measurements of Henry's law constants are reported for 51 chemicals spanning a wide range of chemical structures and volatilities. A static headspace method (Equilibrium Partitioning in Closed Systems, referred to as EPICS) was used to measure Henry's Law Constant, with the standard batch air-stripping method used as a check. An average precision of 5 percent was obtained for the EPICS runs, and the Henry's law constants agreed reasonably well (within 10 percent) with the batch air-stripping results and other reported experimental values. Measurements were conducted over a temperature range of 10-30 C, and the data were correlated with a temperature regression equation coupled with a temperature-dependent error term based on 95 percent confidence limits. The aqueous solubilities of the study compounds were also determined via the shake-flask method at temperatures of 10, 20, and 30 degrees Celsius. Finally, the results of this study were incorporated into a thermodynamic correlation (UNIFAC), based on chemical structure, which allows the prediction of Henry's law constants and aqueous solubilities for a wide variety of pure compounds and mixtures in dilute aqueous solutions. Volume II contains the experimental Henry's law data. Appendix A - Summary of Literature Search, and Appendix B Summary of EPICS Results are included in this volume. Keywords: Water pollution, Soil contamination. (aw).
Publisher:
ISBN:
Category :
Languages : en
Pages : 372
Book Description
Laboratory measurements of Henry's law constants are reported for 51 chemicals spanning a wide range of chemical structures and volatilities. A static headspace method (Equilibrium Partitioning in Closed Systems, referred to as EPICS) was used to measure Henry's Law Constant, with the standard batch air-stripping method used as a check. An average precision of 5 percent was obtained for the EPICS runs, and the Henry's law constants agreed reasonably well (within 10 percent) with the batch air-stripping results and other reported experimental values. Measurements were conducted over a temperature range of 10-30 C, and the data were correlated with a temperature regression equation coupled with a temperature-dependent error term based on 95 percent confidence limits. The aqueous solubilities of the study compounds were also determined via the shake-flask method at temperatures of 10, 20, and 30 degrees Celsius. Finally, the results of this study were incorporated into a thermodynamic correlation (UNIFAC), based on chemical structure, which allows the prediction of Henry's law constants and aqueous solubilities for a wide variety of pure compounds and mixtures in dilute aqueous solutions. Volume II contains the experimental Henry's law data. Appendix A - Summary of Literature Search, and Appendix B Summary of EPICS Results are included in this volume. Keywords: Water pollution, Soil contamination. (aw).
Developments and Applications in Solubility
Author: Trevor M Letcher
Publisher: Royal Society of Chemistry
ISBN: 1847557686
Category : Science
Languages : en
Pages : 433
Book Description
Solubility is fundamental to most areas of chemistry and is one of the most basic of thermodynamic properties. It underlies most industrial processes. Bringing together the latest developments and ideas, Developments and Applications in Solubility covers many varied and disparate topics. The book is a collection of work from leading experts in their fields and covers the theory of solubility, modelling and simulation, industrial applications and new data and recent developments relating to solubility. Of particular interest are sections on: experimental, calculated and predicted solubilities; solubility phenomena in 'green' quaternary mixtures involving ionic liquids; molecular simulation approaches to solubility; solubility impurities in cryogenic liquids and carbon dioxide in chemical processes. The book is a definitive and comprehensive reference to what is new in solubility and is ideal for researcher scientists, industrialists and academics
Publisher: Royal Society of Chemistry
ISBN: 1847557686
Category : Science
Languages : en
Pages : 433
Book Description
Solubility is fundamental to most areas of chemistry and is one of the most basic of thermodynamic properties. It underlies most industrial processes. Bringing together the latest developments and ideas, Developments and Applications in Solubility covers many varied and disparate topics. The book is a collection of work from leading experts in their fields and covers the theory of solubility, modelling and simulation, industrial applications and new data and recent developments relating to solubility. Of particular interest are sections on: experimental, calculated and predicted solubilities; solubility phenomena in 'green' quaternary mixtures involving ionic liquids; molecular simulation approaches to solubility; solubility impurities in cryogenic liquids and carbon dioxide in chemical processes. The book is a definitive and comprehensive reference to what is new in solubility and is ideal for researcher scientists, industrialists and academics
Evaluation and Prediction of Henry's Law Constants and Aqueous Solubilities for Solvents and Hydrocarbon Fuel Components. Volume 1. Technical Discussion
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 96
Book Description
Laboratory measurements of Henry's law constants are reported for 51 chemicals, spanning a wide range of chemical structures and volatilities. A static headspace method (Equilibrium Partitioning in Closed Systems, referred to as EPICS) was used to measure Henry's Law Constant, with the standard batch air- stripping method used as a check. An average precision of 5 percent was obtained for the EPICS runs, and the Henry's law constants agreed reasonably well(within 10 percent) with the batch air-stripping results and other reported experimental values. Measurements were conducted over a temperature range of 10-30 C, and the data were correlated with a temperature regression equation coupled with a temperature-dependent error term based on 95 percent confidence limits. The aqueous solubilities of the study compounds were also determined via the shake- flask method at temperatures of 10,20, and 30 degrees Celsius. Keywords: Volatile organics, Solvents, Fuels, Henry's law constants, Aqueous solubilities, Air water distribution.
Publisher:
ISBN:
Category :
Languages : en
Pages : 96
Book Description
Laboratory measurements of Henry's law constants are reported for 51 chemicals, spanning a wide range of chemical structures and volatilities. A static headspace method (Equilibrium Partitioning in Closed Systems, referred to as EPICS) was used to measure Henry's Law Constant, with the standard batch air- stripping method used as a check. An average precision of 5 percent was obtained for the EPICS runs, and the Henry's law constants agreed reasonably well(within 10 percent) with the batch air-stripping results and other reported experimental values. Measurements were conducted over a temperature range of 10-30 C, and the data were correlated with a temperature regression equation coupled with a temperature-dependent error term based on 95 percent confidence limits. The aqueous solubilities of the study compounds were also determined via the shake- flask method at temperatures of 10,20, and 30 degrees Celsius. Keywords: Volatile organics, Solvents, Fuels, Henry's law constants, Aqueous solubilities, Air water distribution.
Evaluation and Prediction of Henry's Law Constants and Aqueous Solubilities for Solvents and Hydrocarbon Fuel Components
Author: G. B. Howe
Publisher:
ISBN:
Category : Henry's law
Languages : en
Pages : 99
Book Description
Publisher:
ISBN:
Category : Henry's law
Languages : en
Pages : 99
Book Description
Applicability of Theoretical and Semi-empirical Models for Predicting Infinite Dilution Activity Coefficients
Author: David Irvin Eikens
Publisher:
ISBN:
Category :
Languages : en
Pages : 448
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 448
Book Description
Determination of Henry's Law Constant and Activity Coefficient at Infinite Dilution
Author: Dinesh M. Shah
Publisher:
ISBN:
Category :
Languages : en
Pages : 236
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 236
Book Description
Activity Coefficients at Infinite Dilution for Partially Miscible Liquid Systems
Author: Georgieanna Lobien
Publisher:
ISBN:
Category :
Languages : en
Pages : 484
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 484
Book Description
Activity Coefficients at Infinite Dilution
Author: Jürgen Gmehling
Publisher:
ISBN: 9783897461079
Category :
Languages : en
Pages : 2
Book Description
Publisher:
ISBN: 9783897461079
Category :
Languages : en
Pages : 2
Book Description