Anomalous Rare Earths and Actinides

Anomalous Rare Earths and Actinides PDF Author: J.X. Boucherle
Publisher: Elsevier
ISBN: 1483257231
Category : Science
Languages : en
Pages : 733

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Book Description
Anomalous Rare Earths and Actinides: Valence Fluctuation and Heavy Fermions focuses on the characteristics, reactions, transformations, technologies, and processes involved in the study of anomalous rare earths and actinides. The selection first offers information on lanthanides and actinides and electronic structures in cerium monopnictides. Topics include rare earth metals with fluctuating valencies, 'normal' rare earth metals, and band calculation and Fermi surface. The text then elaborates on neutron scattering studies of anomalous rare earth compounds, including magnetic neutron scattering measurements, stability and localization of magnetic moments, and condensed state. The manuscript examines the transport properties of cerium monochalcogenides and pressure-volume relationships of cerium monochalcogenides and monopnictides. The text also ponders on the theory of anisotropic magnetic behavior in hybridizing actinide systems; band hybridization effects on indirect magnetic coupling of localized moments; and neutron scattering from transuranium materials. The selection is a dependable reference for readers interested in the research on anomalous rare earths and actinides.

Anomalous Rare Earths and Actinides

Anomalous Rare Earths and Actinides PDF Author: J.X. Boucherle
Publisher: Elsevier
ISBN: 1483257231
Category : Science
Languages : en
Pages : 733

Get Book Here

Book Description
Anomalous Rare Earths and Actinides: Valence Fluctuation and Heavy Fermions focuses on the characteristics, reactions, transformations, technologies, and processes involved in the study of anomalous rare earths and actinides. The selection first offers information on lanthanides and actinides and electronic structures in cerium monopnictides. Topics include rare earth metals with fluctuating valencies, 'normal' rare earth metals, and band calculation and Fermi surface. The text then elaborates on neutron scattering studies of anomalous rare earth compounds, including magnetic neutron scattering measurements, stability and localization of magnetic moments, and condensed state. The manuscript examines the transport properties of cerium monochalcogenides and pressure-volume relationships of cerium monochalcogenides and monopnictides. The text also ponders on the theory of anisotropic magnetic behavior in hybridizing actinide systems; band hybridization effects on indirect magnetic coupling of localized moments; and neutron scattering from transuranium materials. The selection is a dependable reference for readers interested in the research on anomalous rare earths and actinides.

Handbook on the Physics and Chemistry of Rare Earths

Handbook on the Physics and Chemistry of Rare Earths PDF Author:
Publisher: North Holland
ISBN: 9780444634832
Category : Science
Languages : en
Pages : 0

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Book Description
Handbook on the Physics and Chemistry of Rare Earths is a continuous series of books covering all aspects of rare earth science, including chemistry, life sciences, materials science, and physics. The main emphasis of the handbook is on rare earth elements [Sc, Y and the lanthanides (La through Lu)], but whenever relevant, information is also included on the closely related actinide elements. The individual chapters are comprehensive, broad, up-to-date, critical reviews written by highly experienced invited experts. The series, which was started in 1978 by Professor Karl A. Gschneidner Jr., combines and integrates both the fundamentals and applications of these elements, now publishing two volumes a year.

Handbook on the Physics and Chemistry of Rare Earths

Handbook on the Physics and Chemistry of Rare Earths PDF Author: J.-C. G. Bünzli
Publisher: Newnes
ISBN: 0444595341
Category : Science
Languages : en
Pages : 639

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Book Description
The rare earths represent a group of chemical elements, the lanthanides, together with scandium and yttrium, which exhibit similar chemical properties. They are strategically important to developed and developing nations as they have a wide variety of applications in catalysis, the defense industry, aerospace, the materials and life sciences and in sustainable energy technologies. The Handbook on the Physics and Chemistry of the Rare Earths is a continuing authoritative series that deals with the science and technology of the rare earth elements in an integrated manner. Each chapter is a comprehensive, up-to-date, critical review of a particular segment of the field. The work offers the researcher and graduate student a complete and thorough coverage of this fascinating field. - Individual chapters are comprehensive, broad, critical reviews - Contributions are written by highly experienced, invited experts - Gives an up-to-date overview of developments in the field

Handbook on the Physics and Chemistry of Rare Earths

Handbook on the Physics and Chemistry of Rare Earths PDF Author:
Publisher: Elsevier
ISBN: 044463875X
Category : Science
Languages : en
Pages : 350

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Book Description
Handbook on the Physics and Chemistry of Rare Earths: Including Actinides, Volume 51, is a continuous series of books covering all aspects of rare earth science, including chemistry, life sciences, materials science and physics. This latest release includes chapters on the Effect of Pressure on the Interplay Between Orbital and Magnetic Ordering, Kondo Effect, Valence Fluctuation, and Superconductivity in Rare-Earth Compounds and a section on Rare-Earth: Doped Waveguide Amplifiers and Lasers. The book's main emphasis is on rare earth elements [Sc, Y, and the lanthanides (La through Lu], but whenever relevant, information is also included on the closely related actinide elements. Individual chapters in the ongoing series consist of comprehensive, broad, up-to-date, critical reviews written by highly experienced, invited experts. The series, which was started in 1978 by Professor Karl A. Gschneidner Jr., combines, and integrates, both the fundamentals and applications of these elements with two published volumes each year. - Presents up-to-date overviews and new developments in the field of rare earths, covering both their physics and chemistry - Contains Individual chapters that are comprehensive and broad, with critical reviews - Provides contributions from highly experienced, invited experts

Lanthanides And Actinides, The: Synthesis, Reactivity, Properties And Applications

Lanthanides And Actinides, The: Synthesis, Reactivity, Properties And Applications PDF Author: Stephen T Liddle
Publisher: World Scientific
ISBN: 1800610173
Category : Science
Languages : en
Pages : 727

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Book Description
The Lanthanides and Actinides: Synthesis, Reactivity, Properties and Applications constitutes an introduction to and comprehensive coverage of f-block chemistry encompassing the following areas: periodicity, natural occurrence and extraction, separations, electronic structure, coordination chemistry, organometallic chemistry, small molecule activation, catalysis, organic synthesis applications, magnetism, spectroscopy, computation, materials, photonics, solar cell technology, biological imaging, and technological applications. Under these subject areas the book provides a broad but deep coverage, providing basic overviews as well as detailed chapters on specific areas.This book, targeted at academics, postgraduates and advanced undergraduates, will serve as an ideal introductory text and key reference work to the Lanthanides and Actinides.

Energy Research Abstracts

Energy Research Abstracts PDF Author:
Publisher:
ISBN:
Category : Power resources
Languages : en
Pages : 868

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Book Description


Handbook on the Physics and Chemistry of Rare Earths

Handbook on the Physics and Chemistry of Rare Earths PDF Author: L. Eyring
Publisher: Elsevier
ISBN: 9780444507624
Category : Science
Languages : en
Pages : 780

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Book Description
This volume of the handbook covers a variety of topics with three chapters dealing with a range of lanthanide magnetic materials, and three individual chapters concerning equiatomic ternary ytterbium intermetallic compounds, rare-earth polysulfides, and lanthanide organic complexes. Two the chapters also include information of the actinides and the comparative lanthanide/actinide behaviors.

Handbook on the Physics and Chemistry of Rare Earths

Handbook on the Physics and Chemistry of Rare Earths PDF Author: K.A. Gschneidner
Publisher: Elsevier
ISBN: 0080544371
Category : Science
Languages : en
Pages : 656

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Book Description
This volume of the Handbook is the first of a two-volume set of reviews devoted to the rare-earth-based high-temperature oxide superconductors (commonly known as hiTC superconductors). The history of hiTC superconductors is a few months short of being 14 years old when Bednorz and Müller published their results which showed that (La,BA)2CuO4 had a superconducting transition of ~30 K, which was about 7K higher than any other known superconducting material. Within a year the upper temperature limit was raised to nearly 100K with the discovery of an ~90K superconducting transition in YBa2Cu3O7-&dgr;. The announcement of a superconductor with a transition temperature higher than the boiling point of liquid nitrogen set-off a frenzy of research on trying to find other oxide hiTC superconductors. Within a few months the maximum superconducting transition reached 110 K (Bi2Sr2Ca2Cu3010, and then 122K (TlBa2Ca3Cu4O11. It took several years to push TC up another 11 K to 133 K with the discovery of superconductivity in HgBa2Ca2Cu3O8, which is still the record holder today.

Handbook on the Physics and Chemistry of Rare Earths

Handbook on the Physics and Chemistry of Rare Earths PDF Author: Karl A. Gschneidner
Publisher: Elsevier
ISBN: 9780444515872
Category : Juvenile Nonfiction
Languages : en
Pages : 548

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Book Description
This volume of the Handbook adds five new chapters to the science of rare earths. Two of the chapters deal with intermetallic compounds. An overview of ternary systems containing rare earths, transition metals and indium - Chapter 218 - opens the volume. It is followed by Chapter 219 sorting out relationships between superconductivity and magnetism. The next two chapters are dedicated to complex compounds of rare earths: Chapter 220 describes structural studies using circularly polarized luminescence spectroscopy of lanthanide systems, while Chapter 221 examines rare-earth metal-organic frameworks, also known as coordination polymers. The final Chapter 222 deals with the catalytic activity of rare earths in site-selective hydrolysis of DNA and RNA. Ya. Kalychak, V. Zaremba, R. Pöttgen, M. Lukachuk, and R.-D. Hoffmann review the synthesis conditions, isothermal sections of phase diagrams, crystallography and basic physical properties of ternary intermetallic compounds consisting of the rare-earth metals, transition metals and indium. P. Thalmeier and G. Zwicknagl revisit the last decade of research uncovering some of the mysteries of the superconducting state, especially those related to heavy fermion superconductivity and the co-existence of the superconducting and exotic magnetically ordered states. J. P. Riehl and G. Muller review how the molecular stereochemistry of lanthanide complexes both in pure forms and in mixtures can be probed using circularly polarized luminescence. O. Guillou and C. Daiguebonne assess rare earth-containing metal-organic frameworks, also known as coordination polymers, which hold a potential as working bodies for opto-electronic and magnetic devices, microporous materials for a variety of uses, such as size- and shape-selective separations, catalyst support and hydrogen storage materials. Concluding the volume, M. Komiyama argues that future biotechnology may well rely on the use of rare-earth ions as unique catalysts that can slice DNA and RNA in order to allow their reprogramming, and thus lead to more effective bioengineered processes.

Rare-Earths and Actinides in High Energy Spectroscopy

Rare-Earths and Actinides in High Energy Spectroscopy PDF Author: Christiane Bonnelle
Publisher: Springer
ISBN: 904812879X
Category : Science
Languages : en
Pages : 393

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Book Description
This unique monograph covers recent theoretical and experimental results on the complex character of f electrons in materials containing lanthanides (rare earths) or actinides, such as alpha-cerium and delta-plutonium. It answers the urgent need for a general presentation of the body of experimental and theoretical results presently available in this challenging domain. Some of the fast developing applications of lanthanide and actinide materials are mentioned. Materials containing atoms with an open f shell have electronic and crystalline properties that are controlled by the localized or delocalized character of the f electrons. This book gives a theoretical discussion of the various spectroscopic methods that shed light on the character of the f electrons and on the connection between their localization and the properties of these materials. Part 1 covers the characteristics of the f electrons in atoms and solids and includes a discussion of the properties of lanthanides and actinides in connection with the f electrons. Part 2 describes the various spectroscopic methods that are used to establish the electronic distributions and energies of the states. Examples involve the determination of f electron distributions by high energy spectroscopy methods with separate treatment of the valence and core electrons. Part 3 concentrates on the theoretical treatment of electronic transitions involving f electrons and simulations of the lanthanide spectra, including comparison with the available experimental data. Part 4 discusses the localized or delocalized character of the f electrons in actinides and their compounds, including comparison (analogies & differences) between the 4f and 5f electron materials. This monograph should be of great value for researchers, academics and engineers working in the fields of high energy spectroscopy, electronic and nuclear science and technology, as well as materials involving rare earths and radio-elements.