Author: Kōsuke Izutsu
Publisher: Blackwell Science Incorporated
ISBN: 9780632028757
Category : Science
Languages : en
Pages : 166

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Author: Marion Maclean Davis
Publisher:
ISBN:
Category : Acids
Languages : en
Pages : 170

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Book Description
A unified picture of acid-base behavior in aprotic organic solvents is presented, based on an extensive survey of the literature and experimental results of the author and associates. Evidence given to support this picture includes data pertaining to colligative properties of acids, bases, and salts and also conductance, dielectric constants, distribution between immiscible solvents, and spectral absorption in the infrared, visible, and ultraviolet. The acids upon which attention is centered are proton-donor compounds that are measurably ionized in water, such as aliphatic and aromatic carboxylic acids, substituted phenols and mineral acids. The bases of principal interest are likewise compounds capable of forming ions in water, for example, aliphatic and aromatic amines and derivatives of guanidine or pyridine. The solvents emphasized are hydrocarbons and halohydrocarbons, but data for dipolar aprotic solvents (for example, acetone, acetonitrile, and nitrobenzene) are included. Contrasts in acid-base behavior and in acidity and basicity scales in aprotic and water-like solvents are discussed. The role of hydrogen bonding in aprotic solvents is discussed at length. Important types of hydrogen-bonded structures include chelate rings; self-associated acids, bases, and salts; hydrogen-bonded ion pairs; and homo- and heteroconjugate cations and anions. Examples are given in which hydrogen bonding of these types affects such properties as the absorption spectrum of a salt, the catalytic effect of an acid, and the accurate location of a titration endpoint. (Author).

Author: J.J. Lagowski
Publisher: Elsevier
ISBN: 0323151035
Category : Technology & Engineering
Languages : en
Pages : 423

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Book Description
The Chemistry of Nonaqueous Solvents, Volume III: Inert, Aprotic, and Acidic Solvents is a compilation of critical surveys of specific solvent systems. The compendium contains discussions on the solution chemistry of sulfur dioxide and acyl halides; the solvent properties of hydrogen sulfide and carboxylic acids; and the Bronsted acid-base behavior in inert organic solvents. Chemists, researchers, and students of chemistry and chemical engineering will find the book a good reference material.

Author: Kosuke Izutsu
Publisher: John Wiley & Sons
ISBN: 9783527629169
Category : Science
Languages : en
Pages : 432

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Book Description
An excellent resource for all graduate students and researchers using electrochemical techniques. After introducing the reader to the fundamentals, the book focuses on the latest developments in the techniques and applications in this field. This second edition contains new material on environmentally-friendly solvents, such as room-temperature ionic liquids.

Author: Brian G. Cox
Publisher: Oxford University Press
ISBN: 019967051X
Category : Science
Languages : en
Pages : 156

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Book Description
This book seeks to enhance our understanding of acids and bases by reviewing and analysing their behaviour in non-aqueous solvents. The behaviour is related where possible to that in water, but correlations and contrasts between solvents are also presented.

Author: United States. National Bureau of Standards
Publisher:
ISBN:
Category : Physics
Languages : en
Pages : 160

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Author: Christian Reichardt
Publisher: John Wiley & Sons
ISBN: 3527605673
Category : Science
Languages : en
Pages : 653

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Book Description
In most cases, every chemist must deal with solvent effects, whether voluntarily or otherwise. Since its publication, this has been the standard reference on all topics related to solvents and solvent effects in organic chemistry. Christian Reichardt provides reliable information on the subject, allowing chemists to understand and effectively use these phenomena. 3rd updated and enlarged edition of a classic 35% more contents excellent, proven concept includes current developments, such as ionic liquids indispensable in research and industry From the reviews of the second edition: "...This is an immensely useful book, and the source that I would turn to first when seeking virtually any information about solvent effects." —Organometallics

Author: J. J. Lagowski
Publisher:
ISBN:
Category : Nonaqueous solvents
Languages : en
Pages : 430

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Author: W.L.F. Armarego
Publisher: Butterworth-Heinemann
ISBN: 0128054565
Category : Science
Languages : en
Pages : 1200

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Book Description
Purification of Laboratory Chemicals, Eighth Edition, tabulates methods taken from literature for purifying thousands of individual commercially available chemicals. To help in applying this information, the more common processes currently used for purification in chemical laboratories and new methods are discussed. For dealing with substances not separately listed, a chapter is included setting out the usual methods for purifying specific classes of compounds. - Features empirical formulae inserted for every entry - References all important applications of each substance - Updates and confirms the accuracy of all CAS registry numbers, molecular weights, original reference, and physical data - Provides increased coverage of the latest commercial chemical products, including pharmaceutical chemicals, updated safety and hazard material, and expanded coverage of laboratory and work practices and purification methods

Author: Dennis G. Peters
Publisher: The Electrochemical Society
ISBN: 9781566773928
Category : Science
Languages : en
Pages : 230

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Book Description