A Computational Study of the Chemical Kinetics of Hydrogen Combustion PDF Download
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Author: T. L. Burks
Publisher:
ISBN:
Category : Chemical kinetics
Languages : en
Pages : 70
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Book Description
A set of elementary reactions and their corresponding rate coefficients has been assembled to describe the homogeneous H2-O2 reaction system over the temperature range 300-3000 K. The reaction mechanism was drawn together assuming that H2-O2 reactive mixtures could be adequately described in terms of self-consistent, thermal distributions of electronically neutral, ground-state reactants, intermediates and products. The resulting time-dependent ordinary differential equations describing the system were integrated assuming various initial pressures, temperatures and initial concentrations of reactants and diluents. The computed results have been compared with experimentally observed induction times, second explosion limits, the rate of reaction above the second explosion limit and the temporal behavior of reaction species. The good agreement between the computational and experimental results attests to the accuracy of the assembled mechanism in its description of the homogeneous reaction system and supports the validity of the set of associated rate coefficients for the elementary reactions of the mechanism over a broad range of reaction conditions. (Author).
Author: T. L. Burks
Publisher:
ISBN:
Category : Chemical kinetics
Languages : en
Pages : 70
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Book Description
A set of elementary reactions and their corresponding rate coefficients has been assembled to describe the homogeneous H2-O2 reaction system over the temperature range 300-3000 K. The reaction mechanism was drawn together assuming that H2-O2 reactive mixtures could be adequately described in terms of self-consistent, thermal distributions of electronically neutral, ground-state reactants, intermediates and products. The resulting time-dependent ordinary differential equations describing the system were integrated assuming various initial pressures, temperatures and initial concentrations of reactants and diluents. The computed results have been compared with experimentally observed induction times, second explosion limits, the rate of reaction above the second explosion limit and the temporal behavior of reaction species. The good agreement between the computational and experimental results attests to the accuracy of the assembled mechanism in its description of the homogeneous reaction system and supports the validity of the set of associated rate coefficients for the elementary reactions of the mechanism over a broad range of reaction conditions. (Author).
Author: Ellis Hyman
Publisher:
ISBN:
Category :
Languages : en
Pages : 85
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Book Description
Accomplishments in combustion hydrodynamics and chemistry studies consisted of a computational study of the chemical kinetics of hydrogen combustion along with some subsidiary studies and programming. Comparisons with experimental results have been generally good over a broad range of reaction conditions for induction times, seconds explosion limits, and other parameters. (Author).
Author: Frédérique Battin-Leclerc
Publisher: Springer Science & Business Media
ISBN: 1447153073
Category : Technology & Engineering
Languages : en
Pages : 657
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Book Description
This overview compiles the on-going research in Europe to enlarge and deepen the understanding of the reaction mechanisms and pathways associated with the combustion of an increased range of fuels. Focus is given to the formation of a large number of hazardous minor pollutants and the inability of current combustion models to predict the formation of minor products such as alkenes, dienes, aromatics, aldehydes and soot nano-particles which have a deleterious impact on both the environment and on human health. Cleaner Combustion describes, at a fundamental level, the reactive chemistry of minor pollutants within extensively validated detailed mechanisms for traditional fuels, but also innovative surrogates, describing the complex chemistry of new environmentally important bio-fuels. Divided into five sections, a broad yet detailed coverage of related research is provided. Beginning with the development of detailed kinetic mechanisms, chapters go on to explore techniques to obtain reliable experimental data, soot and polycyclic aromatic hydrocarbons, mechanism reduction and uncertainty analysis, and elementary reactions. This comprehensive coverage of current research provides a solid foundation for researchers, managers, policy makers and industry operators working in or developing this innovative and globally relevant field.
Author: John Buckmaster
Publisher: Springer Science & Business Media
ISBN: 9401110506
Category : Technology & Engineering
Languages : en
Pages : 639
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Book Description
This volume contains the proceedings of the Workshop on Com bustion, sponsored by the Institute for Computer Applications in Science and Engineering (ICASE) and the NASA Langley Research Center (LaRC). It was held on October 12-14, 1992, and was the sec ond workshop in the series on the subject. The first was held in 1989, and its proceedings were published by Springer-Verlag under the title "Major Research Topics in Combustion," edited by M. Y. Hussaini, A. Kumar, and R. G. Voigt. The focus of the second workshop was directed towards the development, analysis, and application of basic models in high speed propulsion of particular interest to NASA. The exploration of a dual approach combining asymptotic and numerical methods for the analysis of the models was particularly encouraged. The objectives of this workshop were i) the genesis of models that would capture or reflect the basic pllysical phenomena in SCRAMJETs and/or oblique detonation-wave engines (ODWE), and ii) the stimulation of a greater interaction between NASA exper imental research community and the academic community. The lead paper by D. Bushnell on the status and issues of high speed propulsion relevant to both the SCRAMJET and the ODWE parallels his keynote address which set the stage of the workshop. Following the lead paper were five technical sessions with titles and chairs: Experiments (C. Rogers), Reacting Free Shear Layers (C. E. Grosch), Detonations (A. K. Kapila), Ignition and Struc ture (J. Buckmaster), and Unsteady Behaviour ('1'. L. Jackson).
Author: E. P. Dougherty
Publisher:
ISBN:
Category :
Languages : en
Pages : 72
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Book Description
Kinetic modeling calculations on the H2-02 system have been carried out with an extensive reaction set to probe the vicinity of the three explosion limits. Sensitivity analysis is used throughout this investigation to study system behavior, in particular, to elucidate mechanistic details. The concentrations and sensitivity profiles are discussed in light of the appropriate experimental results and existing theories of hydrogen combustion. The results indicate the present model to be useful over a wide pressure-temperature range.
Author: National Measurement Laboratory (U.S.)
Publisher:
ISBN:
Category : Chemical kinetics
Languages : en
Pages : 100
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Book Description
Author: Francesco Creta
Publisher:
ISBN:
Category :
Languages : en
Pages : 179
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Book Description
Author: Prasad V. R. K. S. Pokkunuri
Publisher:
ISBN:
Category : Diesel motor
Languages : en
Pages : 356
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Book Description
Author: Anil Waman Date
Publisher: Springer Nature
ISBN: 981151853X
Category : Science
Languages : en
Pages : 413
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Book Description
This book is intended to serve as a textbook for advanced undergraduate and graduate students as well as professionals engaged in application of thermo-fluid science to the study of combustion. The relevant thermo-chemistry and thermo-physical data required for this study are provided in the 6 appendices along with appropriate curve-fit coefficients. To facilitate gradual learning, two chapters are devoted to thermodynamics of pure and gaseous mixture substances, followed by one chapter each on chemical equilibrium and chemical kinetics. This material when coupled with a dedicated chapter on understanding of equations governing transport of momentum, heat and mass in the presence of chemical reactions provides adequate grounding to undertake analysis of practical combustion equipment, of premixed and diffusion flames as well as of solid particle and liquid droplet combustion. The learnings from the aforementioned chapters are taken to a uniquely strong chapter on application case studies, some of which have special relevance for developing countries.
Author: Wayne Douglas Erickson
Publisher:
ISBN:
Category : Aerodynamics, Hypersonic
Languages : en
Pages : 52
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Book Description
