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Author: Johannes Kästner
Publisher: Royal Society of Chemistry
ISBN: 1839160381
Category : Science
Languages : en
Pages : 398
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Book Description
Quantum tunnelling is one of the strangest phenomena in chemistry, where we see the wave nature of atoms acting in “impossible” ways. By letting molecules pass through the kinetic barrier instead of over it, this effect can lead to chemical reactions even close to the absolute zero, to atypical spectroscopic observations, to bizarre selectivity, or to colossal isotopic effects. Quantum mechanical tunnelling observations might be infrequent in chemistry, but it permeates through all its disciplines producing remarkable chemical outcomes. For that reason, the 21st century has seen a great increase in theoretical and experimental findings involving molecular tunnelling effects, as well as in novel techniques that permit their accurate predictions and analysis. Including experimental, computational and theoretical chapters, from the physical and organic to the biochemistry fields, from the applied to the academic arenas, this new book provides a broad and conceptual perspective on tunnelling reactions and how to study them. Quantum Tunnelling in Molecules is the obligatory stop for both the specialist and those new to this world.
Author: Johannes Kästner
Publisher: Royal Society of Chemistry
ISBN: 1839160381
Category : Science
Languages : en
Pages : 398
Get Book Here
Book Description
Quantum tunnelling is one of the strangest phenomena in chemistry, where we see the wave nature of atoms acting in “impossible” ways. By letting molecules pass through the kinetic barrier instead of over it, this effect can lead to chemical reactions even close to the absolute zero, to atypical spectroscopic observations, to bizarre selectivity, or to colossal isotopic effects. Quantum mechanical tunnelling observations might be infrequent in chemistry, but it permeates through all its disciplines producing remarkable chemical outcomes. For that reason, the 21st century has seen a great increase in theoretical and experimental findings involving molecular tunnelling effects, as well as in novel techniques that permit their accurate predictions and analysis. Including experimental, computational and theoretical chapters, from the physical and organic to the biochemistry fields, from the applied to the academic arenas, this new book provides a broad and conceptual perspective on tunnelling reactions and how to study them. Quantum Tunnelling in Molecules is the obligatory stop for both the specialist and those new to this world.
Author: Hiroki Nakamura
Publisher: CRC Press
ISBN: 1466507322
Category : Science
Languages : en
Pages : 225
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Book Description
Quantum mechanical tunneling plays important roles in a wide range of natural sciences, from nuclear and solid-state physics to proton transfer and chemical reactions in chemistry and biology. Responding to the need for further understanding of multidimensional tunneling, the authors have recently developed practical methods that can be applied to
Author: Tetsuo Miyazaki
Publisher: Springer Science & Business Media
ISBN: 9783540015260
Category : Science
Languages : en
Pages : 332
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Book Description
Atom tunneling phenomena are a new paradigm in the science of materials. This book provides a wealth of interesting information about atom tunneling phenomena in physics, chemistry and biology. Topics include the theory of atom tunneling reactions, conclusive evidence and controlling factors for such reactions in solid hydrogen, tunneling dislocation motion, coherent tunneling diffusion, the production of interstellar molecules and semiconductors using tunneling reactions, the effect of atom tunneling on molecular structure and crystalline structure, the suppression of mutation and cancer by an atom tunneling reaction of vitamin C, and atom tunneling reactions of vitamin E and of enzymes. This book provides graduate students and nonspecialist readers with fascinating insights into the world of atom tunneling phenomena.
Author: E. L. Wolf
Publisher: Oxford University Press
ISBN: 0199589496
Category : Literary Collections
Languages : en
Pages : 617
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Book Description
Electron tunnelling spectroscopy as a research tool has strongly advanced understanding of superconductivity. This book explains the physics and instrumentation behind the advances illustrated in beautiful images of atoms, rings of atoms and exotic states in high temperature superconductors, and summarizes the state of knowledge that has resulted.
Author: Roberto Marquardt
Publisher: Elsevier
ISBN: 0128172355
Category : Science
Languages : en
Pages : 376
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Book Description
Molecular Spectroscopy and Quantum Dynamics, an exciting new work edited by Professors Martin Quack and Roberto Marquardt, contains comprehensive information on the current state-of-the-art experimental and theoretical methods and techniques used to unravel ultra-fast phenomena in atoms, molecules and condensed matter, along with future perspectives on the field. - Contains new insights into the quantum dynamics and spectroscopy of electronic and nuclear motion - Presents the most recent developments in the detection and interpretation of ultra-fast phenomena - Includes a discussion of the importance of these phenomena for the understanding of chemical reaction dynamics and kinetics in relation to molecular spectra and structure
Author: Ronald Percy Bell
Publisher:
ISBN: 9781489928924
Category :
Languages : en
Pages : 236
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Book Description
Author: V.I. Gol'danskii
Publisher: Routledge
ISBN: 1351406701
Category : Science
Languages : en
Pages : 345
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Book Description
Surveys the contemporary concepts and theoretical and experimental results of tunneling processes. Examines from a unified viewpoint not only chemical reactions but also other physical physicochemical and biological phenomena in which the tunneling effect is of great importance. Covers the general ideas of tunneling, the low temperature chemical reactions that manifest tunneling mechanisms, tunneling effects in amorphous materials, quantum diffusion and surface phenomena in quantum crystals, hopping diffusion and tunneling scavenging of electrons, and tunneling effects in biological systems.
Author: Leon Gunther
Publisher: Springer Science & Business Media
ISBN: 9401104034
Category : Science
Languages : en
Pages : 503
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Book Description
The first NATO Advanced Workshop on Quantum Tunneling of Magnetization (QTM) was organized and co-directed by Bernard Barbara, Leon Gunther, Nicolas Garcia, and Anthony Leggett and was held from June, 27 through July 1, 1994 in Grenoble and Chichilianne, France. These Proceedings include twenty-nine articles that represent the contributions of the participants in the Workshop. Quantum Tunneling of Magnetization is not only interesting for purely academic reasons. It was pointed out in the review article by L. Gunther in the December, 1990 issue of Physics World, that QTM may be destined to play a significant role within the next two decades in limiting the density of information storage in magnetic systems. Recent advances have indicated that this limitation may well be reached even earlier than first predicted. Furthermore, the number of people who have entered the field of study of QTM during these past few years has increased many fi)ld. The time was therefore opportune to hold a Workshop to bring together for the first time the leading researchers of QTM, both theoretical and experimental, so as to discuss the current status of the field. The most controversial issue at the time of the Workshop was how to establish r.eliable criteria for determining whether experimental results do indeed reveal manifestations of QTM. We believe that much progress was made at the Workshop on this issue.
Author: Rai, Vibhuti Narayan
Publisher: KIT Scientific Publishing
ISBN: 3731512017
Category : Science
Languages : en
Pages : 150
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Book Description
In this work, a clear pathway is presented to achieve well-defined electronically decoupled chromophores from metallic leads without requiring additional insulating layers. To study such self-decoupled molecules, STM equipped with an efficient light detection setup has been used. Results show that the chromophores mounted on tripodal molecular platforms adsorbed on a gold surface present well-defined and efficient electroluminescence down to the single-molecule level.
Author: Joel M Bowman
Publisher: World Scientific
ISBN: 9811237921
Category : Science
Languages : en
Pages : 603
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Book Description
Vibrational Dynamics of Molecules represents the definitive concise text on the cutting-edge field of vibrational molecular chemistry. The chapter contributors are a Who's Who of world leaders in the field. The editor, Joel Bowman, is widely considered as one of the founding fathers of theoretical reaction dynamics. The included topics span the field, from fundamental theory such as collocation methods and vibrational CI methods, to interesting applications such as astrochemistry, supramolecular systems and virtual computational spectroscopy. This is a useful reference for theoretical chemists, spectroscopists, physicists, undergraduate and graduate students, lecturers and software developers.
