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Author: A.K. Galwey
Publisher: Elsevier
ISBN: 0080542794
Category : Science
Languages : en
Pages : 626
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Book Description
The principal objective of this book is to stimulate interest in research that will extend available theory towards a greater understanding of the steps involved in solid-state decompositions and the properties of solids that control reactivities. Much of the activity in this field has been directed towards increasing the range of reactants for which decomposition kinetic data is available, rather than extending insights into the fundamental chemistry of the reactions being studied. The first part of the book (Chapters 1-6) is concerned with theoretical aspects of the subject. The second part (Chapters 7-17) surveys groups of reactions classified by similarities of chemical composition. The final Chapter (18) reviews the subject by unifying features identified as significant and proposes possible directions for future progress.Studies of thermal reactions of ionic compounds have contributed considerably to the theory of solid-state chemistry. Furthermore, many of these rate processes have substantial technological importance, for example, in the manufacture of cement, the exploitation of ores and in the stability testing of drugs, explosives and oxidizing agents. Despite the prolonged and continuing research effort concerned with these reactions, there is no recent overall review. This book is intended to contribute towards correcting this omission. The essential unity of the subject is recognized by the systematic treatment of reactions, carefully selected to be instructive and representative of the subject as a whole. The authors have contributed more than 200 original research articles to the literature, many during their 25 years of collaboration.Features of this book:• Gives a comprehensive in-depth survey of a rarely-reviewed subject.• Reviews methods used in studies of thermal decompositions of solids.• Discusses patterns of subject development perceived from an extensive literature survey.This book is expected to be of greatest value and interest to scientists concerned with the chemical properties and reactions of solids, including chemists, physicists, pharmacists, material scientists, crystallographers, metallurgists and others. This wide coverage of the literature dealing with thermal reactions of solids will be of value to both academic and industrial researchers by reviewing the current status of the theory of the subject. It could also provide a useful starting point for the exploitation of crystalline materials in practical and industrial applications. The contents will also be relevant to a wide variety of researchers, including, for example, those concerned with the stabilities of polymers and composite materials, the processing of minerals, the shelf-lives of pharmaceuticals, etc.
Author: A.K. Galwey
Publisher: Elsevier
ISBN: 0080542794
Category : Science
Languages : en
Pages : 626
Get Book Here
Book Description
The principal objective of this book is to stimulate interest in research that will extend available theory towards a greater understanding of the steps involved in solid-state decompositions and the properties of solids that control reactivities. Much of the activity in this field has been directed towards increasing the range of reactants for which decomposition kinetic data is available, rather than extending insights into the fundamental chemistry of the reactions being studied. The first part of the book (Chapters 1-6) is concerned with theoretical aspects of the subject. The second part (Chapters 7-17) surveys groups of reactions classified by similarities of chemical composition. The final Chapter (18) reviews the subject by unifying features identified as significant and proposes possible directions for future progress.Studies of thermal reactions of ionic compounds have contributed considerably to the theory of solid-state chemistry. Furthermore, many of these rate processes have substantial technological importance, for example, in the manufacture of cement, the exploitation of ores and in the stability testing of drugs, explosives and oxidizing agents. Despite the prolonged and continuing research effort concerned with these reactions, there is no recent overall review. This book is intended to contribute towards correcting this omission. The essential unity of the subject is recognized by the systematic treatment of reactions, carefully selected to be instructive and representative of the subject as a whole. The authors have contributed more than 200 original research articles to the literature, many during their 25 years of collaboration.Features of this book:• Gives a comprehensive in-depth survey of a rarely-reviewed subject.• Reviews methods used in studies of thermal decompositions of solids.• Discusses patterns of subject development perceived from an extensive literature survey.This book is expected to be of greatest value and interest to scientists concerned with the chemical properties and reactions of solids, including chemists, physicists, pharmacists, material scientists, crystallographers, metallurgists and others. This wide coverage of the literature dealing with thermal reactions of solids will be of value to both academic and industrial researchers by reviewing the current status of the theory of the subject. It could also provide a useful starting point for the exploitation of crystalline materials in practical and industrial applications. The contents will also be relevant to a wide variety of researchers, including, for example, those concerned with the stabilities of polymers and composite materials, the processing of minerals, the shelf-lives of pharmaceuticals, etc.
Author: Boris V. L'vov
Publisher: Springer Science & Business Media
ISBN: 1402056729
Category : Science
Languages : en
Pages : 254
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Book Description
This book covers the results of investigations into the mechanisms and kinetics of thermal decompositions of solid and liquid substances on the basis of thermochemical analyses. The main features of these reactions are explained and many problems and unusual phenomena, which have accumulated in this field are interpreted. New methods of TA measurement and calculation have been developed, which permit the precision and accuracy of determination of kinetic parameters to be increased substantially.
Author: Sergey Vyazovkin
Publisher: Springer
ISBN: 3319141759
Category : Science
Languages : en
Pages : 247
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Book Description
The use of isoconversional kinetic methods for analysis of thermogravimetric and calorimetric data on thermally stimulated processes is quickly growing in popularity. The purpose of this book is to create the first comprehensive resource on the theory and applications of isoconversional methodology. The book introduces the reader to the kinetics of physical and chemical condensed phase processes that occur as a result of changing temperature and discusses how isoconversional analysis can provide important kinetic insights into them. The book will help the readers to develop a better understanding of the methodology, and promote its efficient usage and successful development.
Author: Sergey Vyazovkin
Publisher: MDPI
ISBN: 3039365592
Category : Science
Languages : en
Pages : 230
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Book Description
Changing the temperature of a substance can stimulate dramatic changes of its state. These changes can be intermolecular (physical) and intramolecular (chemical) in nature. Physical changes occur without breaking intramolecular bonds, and lead to transitions between the four major phases: gas, liquid, crystal, and glass. Chemical changes are associated with chemical reactions that originate from breaking intramolecular bonds. Phase transitions as well as chemical reactions occur at finite rates. Measuring the rates of processes is the realm of kinetics. The kinetics of thermally stimulated processes is routinely measured using thermal analysis techniques such as differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Knowing the process rates and their dependence on temperature is of vital importance for understanding the behavior of materials exposed to variations in temperature. In recent years, thermal analysis kinetics has made significant progress by developing computational tools for reliable kinetic analysis. It has also expanded its traditional application area to newly developed nano- and biomaterials. This Special Issue is a series of papers that reflect recent developments in the field and highlight the essential role of thermal analysis kinetics in understanding the processes responsible for the thermal behavior of various materials.
Author: Jaroslav Sestak
Publisher: Elsevier
ISBN: 0323858112
Category : Science
Languages : en
Pages : 646
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Book Description
Thermal Analysis and Thermodynamic Properties of Solids, Second Edition covers foundational principles and recent updates in the field, presenting an authoritative overview of theoretical knowledge and practical applications across several fields. Since the first edition of this book was published, large developments have occurred in the theoretical understanding of—and subsequent ability to assess and apply—principles of thermal analysis. Drawing on the knowledge of its expert author, this second edition provides fascinating insight for both new and experienced students, researchers, and industry professionals whose work is influenced or impacted by thermo analysis principles and tools. Part 1 provides a detailed introduction and guide to theoretical aspects of thermal analysis and the related impact of thermodynamics. Key terminology and concepts, the fundamentals of thermophysical examinations, thermostatics, equilibrium background, thermotics, reaction kinetics and models, thermokinetics and the exploitation of fractals are all discussed. Part 2 then goes on to discuss practical applications of this theoretical information to topics such as crystallization kinetics and glass states, thermodynamics in superconductor models, and climate change. - Includes fully updated as well as new chapters on kinetic phase diagrams, thermokinetics in DTA experiments, and crystallization kinetics - Discusses the influence of key derivatives such as thermostatics, thermodynamics, thermotics, and thermokinetics - Helps readers understand and describe reaction kinetics in solids, both in terms of simplified descriptions of the reaction mechanism models and averaged descriptions using fractals
Author: Tina Overton
Publisher: Oxford University Press
ISBN: 0198768125
Category : Science
Languages : en
Pages : 967
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Book Description
Leading the reader from the fundamental principles of inorganic chemistry, right through to cutting-edge research at the forefront of the subject, Inorganic Chemistry, Seventh Edition is the ideal course companion for the duration of a student's degree. The authors have drawn upon their extensive teaching and research experience to update this text; the seventh edition retains the much-praised clarity of style and layout from previous editions, while offering an enhanced section on 'expanding our horizons'. The latest innovative applications of green chemistry have been added, to clearly illustrate the real-world significance of the subject. This edition also sees a greater used of learning features, including substantial updates to the problem solving questions, additional self-tests and walk through explanations which enable students to check their understanding of key concepts and develop problem-solving skills. Providing comprehensive coverage of inorganic chemistry, while placing it in context, this text will enable the reader to fully master this important subject. Online Resources: Inorganic Chemistry, Seventh Edition is accompanied by a range of online resources: For registered adopters of the text: DT Figures, marginal structures, and tables of data ready to download DT Test bank For students: DT Answers to self-tests and exercises from the book DT Tables for group theory DT Web links DT Links to interactive structures and other resources on www.chemtube3D.com
Author: H. Y. Sohn
Publisher: Elsevier
ISBN: 0128164662
Category : Science
Languages : en
Pages : 536
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Book Description
Fluid-Solid Reactions, Second Edition takes a detailed and thorough look at the scope of fluid-solid reaction systems, focusing on the four phenomena: external mass transfer, pore diffusion, chemical reaction, and adsorption/desorption. This completely revised new edition builds on the classic original edition through the introduction of cutting-edge new theories and applications, including the formulation and application of a new and convenient law that governs fluid-solid reaction kinetics. This book will be of primary interest to practicing engineers engaged in process research, development, and design in the many fields where fluid-solid reactions are critical to workflow and research. Fluid-solid reactions play a major role in the technology of most industrialized nations. These reactions encompass a very broad field, including the extraction of metals from their ores, the combustion of solid fuels, coal gasification, and the incineration of solid refuse. Features 50% new and revised content, arming researchers with the latest developments in the field Details a new unified approach to modeling the rates of fluid-solid reaction systems Authored by one of the world’s foremost experts on fluid-solid reactions and their applications in the field
Author: James E. House
Publisher: Elsevier
ISBN: 0443134294
Category : Technology & Engineering
Languages : en
Pages : 350
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Book Description
Introduction to Solid State Chemistry provides a strong background to the structures of solids and factors that determine this structure. The content presented will also stress transformations of solids both in physical forms and chemical composition. In so doing, topics such as phase transitions, sintering, reactions of coordination compounds, photovoltaic compounds are described, whilst kinetics and mechanisms of solid state reactions are covered in depth. There are currently few books that deal with solid state chemistry, where a considerable number instead deal with solid state physics and materials science/engineering. This book provides someone needing or wishing to learn about the chemistry of solids a comprehensive resource that describes structures of solids, the behaviour of solids under applied stresses, the types of reactions that solids undergo, and the phenomenological aspects of reactions in solids. Kinetics of reactions in solids is very seldom covered in current literature and an understanding of the mechanisms of reactions in solids is necessary for many applications. James E. House provides a balanced treatment of structure, dynamics, and behaviour of solids at a level commensurate with upper-level undergraduates or beginning graduate students who wish to obtain an introduction and overview to solid state chemistry. - Provides a?fundamental introduction and entry point to solid state chemistry, acting as a useful prerequisite for further learning in the area - Presents a balanced approach that not only emphasizes structures of solids but also provides information on reactions of solids and how they occur - Gives much-needed focus to the kinetics of reactions of solids and their mechanisms where existing literature covers little of this - Explores crucial solid state chemistry topics such as solar energy conversion, reactions of solid coordination compounds, diffusion, sintering, and other transformations of solids - Features accessible and well-written examples and case studies featuring many new and bespoke supporting illustrations, offering an excellent framework that will help students to understand reaction mechanisms
Author: Marzena Rams-Baron
Publisher: Springer
ISBN: 3319720023
Category : Science
Languages : en
Pages : 234
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Book Description
This book explains theoretical and technological aspects of amorphous drug formulations. It is intended for all those wishing to increase their knowledge in the field of amorphous pharmaceuticals. Conversion of crystalline material into the amorphous state, as described in this book, is a way to overcome limited water solubility of drug formulations, in this way enhancing the chemical activity and bioavailability inside the body. Written by experts from various fields and backgrounds, the book introduces to fundamental physical aspects (explaining differences between the ordered and the disordered solid states, the enhancement of solubility resulting from drugs amorphization, physical instability and how it can be overcome) as well as preparation and formulation procedures to produce and stabilize amorphous pharmaceuticals. Readers will thus gain a well-funded understanding and find a multi-faceted discussion of the properties and advantages of amorphous drugs and of the challenges in producing and stabilizing them. The book is an ideal source of information for researchers and students as well as professionals engaged in research and development of amorphous pharmaceutical products.
Author: United States. Air Force. Directorate of Chemical and Atmospheric Sciences
Publisher:
ISBN:
Category : Atmospheric chemistry
Languages : en
Pages : 248
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Book Description
