The Thermodynamics of Intermediate Uranium Fluorides from Measurements of the Disproportionation Pressures PDF Download
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Author: Paul A. Agron
Publisher:
ISBN:
Category : Uranium fluorides
Languages : en
Pages : 18
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Author: Paul A. Agron
Publisher:
ISBN:
Category : Uranium fluorides
Languages : en
Pages : 18
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Book Description
Author: Donald T. Hawkins
Publisher: Springer Science & Business Media
ISBN: 1468461478
Category : Science
Languages : en
Pages : 250
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Book Description
Coverage For some time, we have contemplated a comprehensive review of the structures and force fields of the binary fluorides. This bibliography of 1498 references marks the first step of that effort. We are pub lishing this material now rather than waiting until the review is complete some two years hence because we believe that the information already accumulated will be of immediate use to a broad spectrum of researchers. Anyone ambitious enough to read through all the articles on binary fluorides will find that the struc tures and force fields of many of these molecules are at present unknown. For example, it has not been clearly established to which point group(s) the lanthanide trifluorides should be assigned. There remain interesting problems relating to the role of Jahn-Teller and pseudo-Jahn-Teller distortions in some of the transition metal fluorides such as VF , MoF , ReF , and ReF , to name only a few. One s s 6 7 also finds fascinating examples of large-amplitude motions, or pseudorotations, as they are often called, in such molecules as XeF 6, I F 7, and PF 5' For those binary fluorides whose equilibrium geometries are precisely known, there still exists the problem of accurately determining the harmonic force field. In a few cases, most notably the Group VA trifluorides, there has been some attempt made at extracting the cubic and quartic contributions to the force field.
Author:
Publisher:
ISBN:
Category : Thermochemistry
Languages : en
Pages : 274
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Author: United States. National Bureau of Standards
Publisher:
ISBN:
Category : Chemistry, Physical and theoretical
Languages : en
Pages : 288
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"Abstract" signed: Thomas B. Douglas, project leader.
Author: Joseph Jacob Katz
Publisher:
ISBN:
Category : Uranium
Languages : en
Pages : 348
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Author: Ingmar Grenthe
Publisher: Elsevier Science & Technology
ISBN:
Category : Science
Languages : en
Pages : 744
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Book Description
This volume provides a comprehensive overview on the chemical thermodynamics of those elements that are of particular importance in the safety assessment of radioactive waste disposal systems. This is the first volume in a series of critical reviews to be published on this subject. The book provides an extensive compilation of chemical thermodynamic data for uranium. A description of procedures for activity corrections and uncertainty estimates is given. A critical discussion of data needed for nuclear waste management assessments, including areas where significant gaps of knowledge exist is presented. A detailed inventory of chemical thermodynamic data for inorganic compounds and complexes of uranium is listed. Data and their uncertainty limits are recommended for 74 aqueous complexes and 199 solid and 31 gaseous compounds containing uranium, and on 52 aqueous and 17 solid auxiliary species containing no uranium. The data are internally consistent and compatible with the CODATA Key Values. The book contains a detailed discussion of procedures used for activity factor corrections in aqueous solution, as well as including methods for making uncertainty estimates.
Author:
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ISBN:
Category : Nuclear energy
Languages : en
Pages : 382
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Consists of AECD 1-2023 (no. 1-1779 called MDDC).
Author: United States. National Bureau of Standards
Publisher:
ISBN:
Category : Weights and measures
Languages : en
Pages : 910
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Author:
Publisher:
ISBN:
Category : Energy development
Languages : en
Pages : 448
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Author: United States Dept. of Commerce. Office of Technical Services
Publisher:
ISBN:
Category : Uranium
Languages : en
Pages : 16
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