Author: Robert Edward Blake
Publisher:
ISBN:
Category :
Languages : en
Pages : 304
Book Description
The Synthesis, Characterization and Study of Transition Metal Complexes for the Oxidation and Activation of Hydrocarbons
Author: Robert Edward Blake
Publisher:
ISBN:
Category :
Languages : en
Pages : 304
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 304
Book Description
Activation of Saturated Hydrocarbons by Transition Metal Complexes
Author: A.E. Shilov
Publisher: Springer Science & Business Media
ISBN: 9789027716286
Category : Science
Languages : en
Pages : 226
Book Description
Publisher: Springer Science & Business Media
ISBN: 9789027716286
Category : Science
Languages : en
Pages : 226
Book Description
Synthesis, Characterization, and Computational Studies of Unsaturated Transition Metal Complexes
Author: Lori Anne Watson
Publisher:
ISBN:
Category :
Languages : en
Pages : 504
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 504
Book Description
Synthesis and Characterization of Transition Metal Complexes
Author: Milan M. Milutinović
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
Book Description
Transition metals and their complexes have an important impact on chemistry and are found in many application in life in general. Ruthenium and rhodium are two members of noble metals and proved to be suitable for anticancer activity. With the aim of changing the coordination environment in ruthenium and rhodium complexes, this thesis presents a series of Ru(II) polypyridyl and Rh(III) pincer-type complexes. All new Ru(II) and Rh(III) complexes were characterized by NMR spectroscopy, ESI-MS spectrometry and UV-Vis spectrophotometry . For some of the complexes a single crystal X-ray crystallography was performed. The substitution reactions of Ru(II) and Rh(III) complexes with mononucleotides, oligonucleotides and amino acids were studied quantitatively by UV-Vis spectroscopy. Measurements of the activation enthalpies and entropies for all synthesized complexes are supporting an associative mechanism for the substitution process. NMR spectroscopy studies were performed on some Ru(II) complexes where after the hydrolyses of the metal-Cl bond the complexes are capable to interact with guanine derivatives forming monofunctional adducts via N7 atom. The interactions of Ru(II) and Rh(III) complexes with fully complementary 15-mer and 22-mer duplexes of DNA and fully complementary 13-mer duplexes of RNA were studied by UV-Vis spectroscopy. The interactions of ruthenium(II) and rhodium(III) complexes with calf thymus and herring testes DNA were examined by absorption using UV-Vis spectroscopy, fluorescence emission spectral studies by ethidium bromide displacement studies and viscosity measurements. ; eng
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
Book Description
Transition metals and their complexes have an important impact on chemistry and are found in many application in life in general. Ruthenium and rhodium are two members of noble metals and proved to be suitable for anticancer activity. With the aim of changing the coordination environment in ruthenium and rhodium complexes, this thesis presents a series of Ru(II) polypyridyl and Rh(III) pincer-type complexes. All new Ru(II) and Rh(III) complexes were characterized by NMR spectroscopy, ESI-MS spectrometry and UV-Vis spectrophotometry . For some of the complexes a single crystal X-ray crystallography was performed. The substitution reactions of Ru(II) and Rh(III) complexes with mononucleotides, oligonucleotides and amino acids were studied quantitatively by UV-Vis spectroscopy. Measurements of the activation enthalpies and entropies for all synthesized complexes are supporting an associative mechanism for the substitution process. NMR spectroscopy studies were performed on some Ru(II) complexes where after the hydrolyses of the metal-Cl bond the complexes are capable to interact with guanine derivatives forming monofunctional adducts via N7 atom. The interactions of Ru(II) and Rh(III) complexes with fully complementary 15-mer and 22-mer duplexes of DNA and fully complementary 13-mer duplexes of RNA were studied by UV-Vis spectroscopy. The interactions of ruthenium(II) and rhodium(III) complexes with calf thymus and herring testes DNA were examined by absorption using UV-Vis spectroscopy, fluorescence emission spectral studies by ethidium bromide displacement studies and viscosity measurements. ; eng
Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes
Author: A.E. Shilov
Publisher: Springer Science & Business Media
ISBN: 9781402004209
Category : Science
Languages : en
Pages : 556
Book Description
hemistry is the science about breaking and forming of bonds between atoms. One of the most important processes for organic chemistry is breaking bonds C–H, as well as C–C in various compounds, and primarily, in hydrocarbons. Among hydrocarbons, saturated hydrocarbons, alkanes (methane, ethane, propane, hexane etc. ), are especially attractive as substrates for chemical transformations. This is because, on the one hand, alkanes are the main constituents of oil and natural gas, and consequently are the principal feedstocks for chemical industry. On the other hand, these substances are known to be the less reactive organic compounds. Saturated hydrocarbons may be called the “noble gases of organic chemistry” and, if so, the first representative of their family – methane – may be compared with extremely inert helium. As in all comparisons, this parallel between noble gases and alkanes is not fully accurate. Indeed the transformations of alkanes, including methane, have been known for a long time. These reactions involve the interaction with molecular oxygen from air (burning – the main source of energy!), as well as some mutual interconversions of saturated and unsaturated hydrocarbons. However, all these transformations occur at elevated temperatures (higher than 300–500 °C) and are usually characterized by a lack of selectivity. The conversion of alkanes into carbon dioxide and water during burning is an extremely valuable process – but not from a chemist viewpoint.
Publisher: Springer Science & Business Media
ISBN: 9781402004209
Category : Science
Languages : en
Pages : 556
Book Description
hemistry is the science about breaking and forming of bonds between atoms. One of the most important processes for organic chemistry is breaking bonds C–H, as well as C–C in various compounds, and primarily, in hydrocarbons. Among hydrocarbons, saturated hydrocarbons, alkanes (methane, ethane, propane, hexane etc. ), are especially attractive as substrates for chemical transformations. This is because, on the one hand, alkanes are the main constituents of oil and natural gas, and consequently are the principal feedstocks for chemical industry. On the other hand, these substances are known to be the less reactive organic compounds. Saturated hydrocarbons may be called the “noble gases of organic chemistry” and, if so, the first representative of their family – methane – may be compared with extremely inert helium. As in all comparisons, this parallel between noble gases and alkanes is not fully accurate. Indeed the transformations of alkanes, including methane, have been known for a long time. These reactions involve the interaction with molecular oxygen from air (burning – the main source of energy!), as well as some mutual interconversions of saturated and unsaturated hydrocarbons. However, all these transformations occur at elevated temperatures (higher than 300–500 °C) and are usually characterized by a lack of selectivity. The conversion of alkanes into carbon dioxide and water during burning is an extremely valuable process – but not from a chemist viewpoint.
Preparation, Characterisation and Reactivity of Low Oxidation State d-Block Metal Complexes Stabilised by Extremely Bulky Amide Ligands
Author: Jamie Hicks
Publisher: Springer
ISBN: 9811029059
Category : Science
Languages : en
Pages : 214
Book Description
This thesis describes the synthesis and characterization of numerous metal-metal bonded complexes that are stabilized by extremely bulky amide ligands. It provides a comprehensive overview of the field, including discussions on groundbreaking complexes and reactions, before presenting in detail, exciting new findings from the PhD studies. The thesis appeals to researchers, professors and chemistry undergraduates with an interest in inorganic and/or organometallic chemistry.
Publisher: Springer
ISBN: 9811029059
Category : Science
Languages : en
Pages : 214
Book Description
This thesis describes the synthesis and characterization of numerous metal-metal bonded complexes that are stabilized by extremely bulky amide ligands. It provides a comprehensive overview of the field, including discussions on groundbreaking complexes and reactions, before presenting in detail, exciting new findings from the PhD studies. The thesis appeals to researchers, professors and chemistry undergraduates with an interest in inorganic and/or organometallic chemistry.
Transition metal Organometallics In Organic Synthesis
Author: Howard Alper
Publisher: Elsevier
ISBN: 0323161936
Category : Science
Languages : en
Pages : 271
Book Description
Transition Metal Organometallics in Organic Synthesis: Volume I reviews the literature in the field of organic synthesis with a focus on the most effective synthetic transformations. The text covers topics such as the general considerations in organic synthesis, C-C and C-X bond formations, and the isomerization and reorganization reactions of olefins. Also covered are topics such as displacement reactions with transition metal complexes, electrophilic reactions of organopalladium complexes, carbonylation reactions, and metal-carbene complexes — its structure, spectra, bonding, and direct synthesis. The book is recommended as a reference for chemists and inorganic chemists who would like to learn the applications of organometallic complexes as reagents and catalysts.
Publisher: Elsevier
ISBN: 0323161936
Category : Science
Languages : en
Pages : 271
Book Description
Transition Metal Organometallics in Organic Synthesis: Volume I reviews the literature in the field of organic synthesis with a focus on the most effective synthetic transformations. The text covers topics such as the general considerations in organic synthesis, C-C and C-X bond formations, and the isomerization and reorganization reactions of olefins. Also covered are topics such as displacement reactions with transition metal complexes, electrophilic reactions of organopalladium complexes, carbonylation reactions, and metal-carbene complexes — its structure, spectra, bonding, and direct synthesis. The book is recommended as a reference for chemists and inorganic chemists who would like to learn the applications of organometallic complexes as reagents and catalysts.
Synthesis, Characterization, and Reactivity of Transition Metal Complexes Containing Multi-donor Ligands
Author: John C. Linehan
Publisher:
ISBN:
Category :
Languages : en
Pages : 514
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 514
Book Description
Synthesis, Characterization and Reactivity of Late Transition Metal Boryl Complexes
Author: Carl N. Iverson
Publisher:
ISBN:
Category : Alkenes
Languages : en
Pages : 320
Book Description
Publisher:
ISBN:
Category : Alkenes
Languages : en
Pages : 320
Book Description
Synthesis and Characterization of Transition Metal Complexes for Oxidation, Reduction, and Carbonylation Reactions
Author: Cassandra P. Lilly
Publisher:
ISBN:
Category :
Languages : en
Pages : 241
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 241
Book Description