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Author: K. Lindenberg
Publisher: Wiley-VCH
ISBN: 9780471186830
Category : Science
Languages : en
Pages : 0
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Book Description
This is the first unified treatment of the properties of thermodynamically open and closed systems. It provides the theory and methodology that are necessary to understand nonlinear processes. The section on Classical Systems covers topics ranging from the evolution of probability to open and closed systems and non-Hamiltonian systems. The concluding section on Quantum Systems is equally detailed, treating the evolution of quantum systems, c-number fluctuations and operator fluctuations. The material covered is applicable to weather systems, ocean currents, dye lasers and many other nonequilibrium systems. The text is also suitable for students in graduate course. Numerous physical chemical examples facilitate self-study.
Author: K. Lindenberg
Publisher: Wiley-VCH
ISBN: 9780471186830
Category : Science
Languages : en
Pages : 0
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Book Description
This is the first unified treatment of the properties of thermodynamically open and closed systems. It provides the theory and methodology that are necessary to understand nonlinear processes. The section on Classical Systems covers topics ranging from the evolution of probability to open and closed systems and non-Hamiltonian systems. The concluding section on Quantum Systems is equally detailed, treating the evolution of quantum systems, c-number fluctuations and operator fluctuations. The material covered is applicable to weather systems, ocean currents, dye lasers and many other nonequilibrium systems. The text is also suitable for students in graduate course. Numerous physical chemical examples facilitate self-study.
Author: Robert Zwanzig
Publisher: Oxford University Press, USA
ISBN: 0195140184
Category : Science
Languages : en
Pages : 233
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Book Description
This is a presentation of the main ideas and methods of modern nonequilibrium statistical mechanics. It is the perfect introduction for anyone in chemistry or physics who needs an update or background in this time-dependent field. Topics covered include fluctuation-dissipation theorem; linear response theory; time correlation functions, and projection operators. Theoretical models are illustrated by real-world examples and numerous applications such as chemical reaction rates and spectral line shapes are covered. The mathematical treatments are detailed and easily understandable and the appendices include useful mathematical methods like the Laplace transforms, Gaussian random variables and phenomenological transport equations.
Author: Denis J. Evans
Publisher: ANU E Press
ISBN: 1921313234
Category : Science
Languages : en
Pages : 318
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Book Description
"There is a symbiotic relationship between theoretical nonequilibrium statistical mechanics on the one hand and the theory and practice of computer simulation on the other. Sometimes, the initiative for progress has been with the pragmatic requirements of computer simulation and at other times, the initiative has been with the fundamental theory of nonequilibrium processes. This book summarises progress in this field up to 1990"--Publisher's description.
Author: J. R. Dorfman
Publisher: Cambridge University Press
ISBN: 0521655897
Category : Science
Languages : en
Pages : 303
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Book Description
Introduction to applications and techniques in non-equilibrium statistical mechanics of chaotic dynamics.
Author: Vladimir Privman
Publisher: Cambridge University Press
ISBN: 052155974X
Category : Science
Languages : en
Pages : 490
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Book Description
Self-contained and up-to-date guide to one-dimensional reactions, dynamics, diffusion and adsorption.
Author: Joel Keizer
Publisher: Springer Science & Business Media
ISBN: 1461210542
Category : Science
Languages : en
Pages : 517
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Book Description
The structure of the theory ofthermodynamics has changed enormously since its inception in the middle of the nineteenth century. Shortly after Thomson and Clausius enunciated their versions of the Second Law, Clausius, Maxwell, and Boltzmann began actively pursuing the molecular basis of thermo dynamics, work that culminated in the Boltzmann equation and the theory of transport processes in dilute gases. Much later, Onsager undertook the elucidation of the symmetry oftransport coefficients and, thereby, established himself as the father of the theory of nonequilibrium thermodynamics. Com bining the statistical ideas of Gibbs and Langevin with the phenomenological transport equations, Onsager and others went on to develop a consistent statistical theory of irreversible processes. The power of that theory is in its ability to relate measurable quantities, such as transport coefficients and thermodynamic derivatives, to the results of experimental measurements. As powerful as that theory is, it is linear and limited in validity to a neighborhood of equilibrium. In recent years it has been possible to extend the statistical theory of nonequilibrium processes to include nonlinear effects. The modern theory, as expounded in this book, is applicable to a wide variety of systems both close to and far from equilibrium. The theory is based on the notion of elementary molecular processes, which manifest themselves as random changes in the extensive variables characterizing a system. The theory has a hierarchical character and, thus, can be applied at various levels of molecular detail.
Author: Carolyn M. Van Vliet
Publisher: World Scientific
ISBN: 9812704779
Category : Science
Languages : en
Pages : 987
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Book Description
This book encompasses our current understanding of the ensemble approach to many-body physics, phase transitions and other thermal phenomena, as well as the quantum foundations of linear response theory, kinetic equations and stochastic processes. It is destined to be a standard text for graduate students, but it will also serve the specialist-researcher in this fascinating field; some more elementary topics have been included in order to make the book self-contained.The historical methods of J Willard Gibbs and Ludwig Boltzmann, applied to the quantum description rather than phase space, are featured. The tools for computations in the microcanonical, canonical and grand-canonical ensembles are carefully developed and then applied to a variety of classical and standard quantum situations. After the language of second quantization has been introduced, strongly interacting systems, such as quantum liquids, superfluids and superconductivity, are treated in detail. For the connoisseur, there is a section on diagrammatic methods and applications.In the second part dealing with non-equilibrium processes, the emphasis is on the quantum foundations of Markovian behaviour and irreversibility via the Pauli-Van Hove master equation. Justifiable linear response expressions and the quantum-Boltzmann approach are discussed and applied to various condensed matter problems. From this basis the Onsager-Casimir relations are derived, together with the mesoscopic master equation, the Langevin equation and the Fokker-Planck truncation procedure. Brownian motion and modern stochastic problems such as fluctuations in optical signals and radiation fields briefly make the round.
Author: Katja Lindenberg
Publisher: Wiley-VCH
ISBN:
Category : Science
Languages : en
Pages : 472
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Book Description
This is the first unified treatment of the properties of thermodynamically open and closed systems. It provides the theory and methodology that are necessary to understand nonlinear processes. The section on Classical Systems covers topics ranging from the evolution of probability to open and closed systems and non-Hamiltonian systems. The concluding section on Quantum Systems is equally detailed, treating the evolution of quantum systems, c-number fluctuations and operator fluctuations. The material covered is applicable to weather systems, ocean currents, dye lasers and many other nonequilibrium systems. The text is also suitable for students in graduate course. Numerous physical chemical examples facilitate self-study.
Author: Andrea Puglisi
Publisher: MDPI
ISBN: 3038970573
Category : Mathematics
Languages : en
Pages : 335
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Book Description
This book is a printed edition of the Special Issue "Thermodynamics and Statistical Mechanics of Small Systems" that was published in Entropy
Author: Signe Kjelstrup
Publisher: World Scientific
ISBN: 9812779132
Category : Technology & Engineering
Languages : en
Pages : 451
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Book Description
The purpose of this book is to encourage the use of non-equilibrium thermodynamics to describe transport in complex, heterogeneous media. With large coupling effects between the transport of heat, mass, charge and chemical reactions at surfaces, it is important to know how one should properly integrate across systems where different phases are in contact. No other book gives a prescription of how to set up flux equations for transports across heterogeneous systems.The authors apply the thermodynamic description in terms of excess densities, developed by Gibbs for equilibrium, to non-equilibrium systems. The treatment is restricted to transport into and through the surface. Using local equilibrium together with the balance equations for the surface, expressions for the excess entropy production of the surface and of the contact line are derived. Many examples are given to illustrate how the theory can be applied to coupled transport of mass, heat, charge and chemical reactions; in phase transitions, at electrode surfaces and in fuel cells. Molecular simulations and analytical studies are used to add insight.
