The Effect of Transient Flow on Contaminant Dispersion in Porous Media

The Effect of Transient Flow on Contaminant Dispersion in Porous Media PDF Author: François A. Richard
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ISBN:
Category :
Languages : en
Pages : 0

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Book Description
Our ability to predict solute transport in groundwater is limited by our imperfect understanding of the physical processes governing the spreading of underground contaminant plumes beneath the surface. Inaccurate prediction of solute migration can in turn result in unreliable risk analyses, or higher costs for groundwater decontamination. It is generally accepted that spatial variations in the hydraulic conductivity of porous materials largely contributes to the spreading of solutes dissolved in groundwater. Unsteady hydraulic gradients can also enhance this dispersion by imposing an additional source of variability on the flow field. Most field and numerical studies assume steady state groundwater flow, despite compelling field evidence suggesting that flow transience may be ubiquitous. This study characterizes the effects of transient groundwater flow on contaminant migration in both homogeneous and heterogeneous porous media. The macroscopic dispersion of miscible solutes subjected to unsteady flow fields is assessed quantitatively through a series of laboratory experiments and numerical simulations. An innovative laboratory model is presented, which consists of a two-dimensional flow cell and coupled hydraulic control system that allow the construction of spatially homogeneous or heterogeneous porous media of prescribed statistical properties, and to impose deterministic flow transients on the system. A monitoring procedure combining image processing with spatial moment analysis is used to characterize with great spatial and temporal resolution the evolution of contaminant plumes, as measured from sequences of digital images acquired during the course of laboratory experiments. Results suggest that the influence of flow transience on solute dispersion compares well with results reported in the literature, based on theoretical or numerical investigations. Changes in the mean flow direction significantly increase transverse dispersion in proportion to the rotation angle; conversely, longitudinal dispersivity decreases in response to variations in the flow direction, but to a lesser extent. Reversing hydraulic gradients can cause a reduction in the plume extents, or plume "shrinking". Although both the spatial and temporal variability enhance solute spreading, heterogeneity of the porous medium can mask the temporal variations in the flow field. The increased complexity introduced by the spatial and temporal variability can lead to inconsistencies between experimental and numerical models.

The Effect of Transient Flow on Contaminant Dispersion in Porous Media

The Effect of Transient Flow on Contaminant Dispersion in Porous Media PDF Author: François A. Richard
Publisher:
ISBN:
Category :
Languages : en
Pages : 0

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Book Description
Our ability to predict solute transport in groundwater is limited by our imperfect understanding of the physical processes governing the spreading of underground contaminant plumes beneath the surface. Inaccurate prediction of solute migration can in turn result in unreliable risk analyses, or higher costs for groundwater decontamination. It is generally accepted that spatial variations in the hydraulic conductivity of porous materials largely contributes to the spreading of solutes dissolved in groundwater. Unsteady hydraulic gradients can also enhance this dispersion by imposing an additional source of variability on the flow field. Most field and numerical studies assume steady state groundwater flow, despite compelling field evidence suggesting that flow transience may be ubiquitous. This study characterizes the effects of transient groundwater flow on contaminant migration in both homogeneous and heterogeneous porous media. The macroscopic dispersion of miscible solutes subjected to unsteady flow fields is assessed quantitatively through a series of laboratory experiments and numerical simulations. An innovative laboratory model is presented, which consists of a two-dimensional flow cell and coupled hydraulic control system that allow the construction of spatially homogeneous or heterogeneous porous media of prescribed statistical properties, and to impose deterministic flow transients on the system. A monitoring procedure combining image processing with spatial moment analysis is used to characterize with great spatial and temporal resolution the evolution of contaminant plumes, as measured from sequences of digital images acquired during the course of laboratory experiments. Results suggest that the influence of flow transience on solute dispersion compares well with results reported in the literature, based on theoretical or numerical investigations. Changes in the mean flow direction significantly increase transverse dispersion in proportion to the rotation angle; conversely, longitudinal dispersivity decreases in response to variations in the flow direction, but to a lesser extent. Reversing hydraulic gradients can cause a reduction in the plume extents, or plume "shrinking". Although both the spatial and temporal variability enhance solute spreading, heterogeneity of the porous medium can mask the temporal variations in the flow field. The increased complexity introduced by the spatial and temporal variability can lead to inconsistencies between experimental and numerical models.

Influences of Flow Transients and Porous Medium Heterogeneity on Colloid-Associated Contaminant Transport in the Vadose Zone

Influences of Flow Transients and Porous Medium Heterogeneity on Colloid-Associated Contaminant Transport in the Vadose Zone PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Book Description
Our research is guided by an EMSP objective to improve conceptual and predictive models of contaminant movement in vadose-zone environments. As described in the report National Roadmap for Vadose-Zone Science and Technology [DOE, 2001], soil-water colloids are capable of adsorbing contaminants, such as radionuclides and metals, and facilitating their migration through the vadose zone and towards groundwater reservoirs. Our research centers on advancing understanding of this phenomenon. In particular, we are combining mathematical modeling with laboratory experimentation at pore and column scales to (1) elucidate the effects of porewater-flow transients on colloid mobilization in unsaturated porous media; (2) explore the sensitivity of colloid deposition rates to changes in porewater chemistry and colloid mineralogy; (3) develop mathematical models appropriate for simulating colloid mobilization, transport, and deposition under both steady-flow and transient-flow conditions; (4) identify mechanisms that govern mineral-colloid mobilization and deposition in unsaturated porous media; (5) quantify the effects of mineral-grain geometry and surface roughness on colloid-filtration rates; and (6) evaluate the influences of colloids on the transport of strontium and cesium (i.e., DOE-contaminants-of-concern) through soils and sediments.

Transient Flow and Dispersion Analysis in Porous Media Using Boundary Element Method

Transient Flow and Dispersion Analysis in Porous Media Using Boundary Element Method PDF Author: T. I. Eldho
Publisher:
ISBN:
Category :
Languages : en
Pages : 0

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An Assessment of the Role of Transient Flow on the Dispersion of Non-reactive Solutes in Porous Media, a Numerical Study

An Assessment of the Role of Transient Flow on the Dispersion of Non-reactive Solutes in Porous Media, a Numerical Study PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Chemical Transport Through Fractured Porous Media in a Transient Radial Flow System

Chemical Transport Through Fractured Porous Media in a Transient Radial Flow System PDF Author: Chao Shan
Publisher:
ISBN:
Category :
Languages : en
Pages : 210

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Diffusion in Natural Porous Media

Diffusion in Natural Porous Media PDF Author: Peter Grathwohl
Publisher: Springer Science & Business Media
ISBN: 146155683X
Category : Science
Languages : en
Pages : 198

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Book Description
Diffusion in Natural Porous Media: Contaminant Transport, Sorption/Desorption and Dissolution Kinetics introduces the general principles of diffusion in the subsurface environment and discusses the implications for the fate and transport of contaminants in soils and groundwater. Emphasis is placed on sorption/desorption and the dissolution kinetics of organic contaminants, both of which are limited by the slow speed of molecular diffusion. Diffusion in Natural Porous Media: Contaminant Transport, Sorption/Desorption and Dissolution Kinetics compiles methods for calculating the diffusion coefficients of organic compounds (in aqueous solution or vapor phase) in natural porous media. The author uses analytical solutions of Fick's 2nd law and some simple numerical models to model diffusive transport under various initial and boundary conditions. A number of these models may be solved using spreadsheets. The book examines sorption/desorption rates of organic compounds in various soils and aquifer materials, and also examines the dissolution kinetics of nonaqueous phase liquids in aquifers, in both the trapped residual phase and in pools. Diffusion in Natural Porous Media: Contaminant Transport, Sorption/Desorption and Dissolution Kinetics concludes with a discussion of the impact of slow diffusion processes on soil and groundwater decontamination and the implications of these processes for groundwater risk assessment.

Transverse Dispersion in Liquid Flow Through Porous Media

Transverse Dispersion in Liquid Flow Through Porous Media PDF Author: Eugene Sidney Simpson
Publisher:
ISBN:
Category : Diffusion in hydrology
Languages : en
Pages : 40

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Transient Compressible Flows in Porous Media

Transient Compressible Flows in Porous Media PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Book Description
Transient compressible flow in porous media was investigated analytically. The major portion of the investigation was directed toward improving and understanding of dispersion in these flows and developing rapid accurate numerical techniques for predicting the extent of dispersion. The results are of interest in the containment of underground nuclear experiments. The transient one-dimensional transport of a trace component in a gas flow is analyzed. A conservation equation accounting for the effects of convective transport, dispersive transport, and decay, is developed. This relation, as well as a relation governing the fluid flow, is used to predict trace component concentration as a function of position and time. A detailed analysis of transport associated with the isothermal flow of an ideal gas is done. Because the governing equations are nonlinear, numerical calculations are performed. The ideal gas flow is calculated using a highly stable implicit iterative procedure with an Eulerian mesh. In order to avoid problems of anomolous dispersion associated with finite difference calculation, trace component convection and dispersion are calculated using a Lagrangian mesh. Details of the Eulerian- Lagrangian numerical technique are presented. Computer codes have been developed and implemented on the Lawrence Livermore Laboratory computer system. (TFD).

Seminar on Transport and Fate of Contaminants in the Subsurface

Seminar on Transport and Fate of Contaminants in the Subsurface PDF Author:
Publisher:
ISBN:
Category : Groundwater
Languages : en
Pages : 348

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Transient Compressible Flows in Porous Media

Transient Compressible Flows in Porous Media PDF Author: Frank A. Morrison
Publisher:
ISBN:
Category : Fluid dynamics
Languages : en
Pages : 160

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Book Description
Transient compressible flow in porous media was investigated analytically. The major portion of the investigation was directed toward improving and understanding of dispersion in these flows and developing rapid accurate numerical techniques for predicting the extent of dispersion. The results are of interest in the containment of underground nuclear experiments. The transient one-dimensional transport of a trace component in a gas flow is analyzed. A conservation equation accounting for the effects of convective transport, dispersive transport, and decay, is developed. This relation, as well as a relation governing the fluid flow, is used to predict trace component concentration as a function of position and time. A detailed analysis of transport associated with the isothermal flow of an ideal gas is done. Because the governing equations are nonlinear, numerical calculations are performed. The ideal gas flow is calculated using a highly stable implicit iterative procedure with an Eulerian mesh. In order to avoid problems of anomolous dispersion associated with finite difference calculation, trace component convection and dispersion are calculated using a Lagrangian mesh. Details of the Eulerian-Lagrangian numerical technique are presented. Computer codes have been developed and implemented on the Lawrence Livermore Laboratory computer system.(TFD).