Techniques for the Study of Ion-Molecule Reactions

Techniques for the Study of Ion-Molecule Reactions PDF Author: James M. Farrar
Publisher: Wiley-Interscience
ISBN:
Category : Science
Languages : en
Pages : 680

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Book Description
The first comprehensive collection of all the major techniques used to study gas phase interactions is presented in this volume. With complete coverage of what a given technique can accomplish, its advantages and disadvantages, the book is designed to teach advanced students and researchers entering the field how to investigate a broad range of topics. Included is coverage of traditional topics such as ion cyclotron resonance, as well as more recent innovations, including Fourier transform mass spectrometry and ionic cluster studies. Several diagrams of instrumentation and examples of experimental data are also provided.

Techniques for the Study of Ion-Molecule Reactions

Techniques for the Study of Ion-Molecule Reactions PDF Author: James M. Farrar
Publisher: Wiley-Interscience
ISBN:
Category : Science
Languages : en
Pages : 680

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Book Description
The first comprehensive collection of all the major techniques used to study gas phase interactions is presented in this volume. With complete coverage of what a given technique can accomplish, its advantages and disadvantages, the book is designed to teach advanced students and researchers entering the field how to investigate a broad range of topics. Included is coverage of traditional topics such as ion cyclotron resonance, as well as more recent innovations, including Fourier transform mass spectrometry and ionic cluster studies. Several diagrams of instrumentation and examples of experimental data are also provided.

Kinetics of Ion-Molecule Reactions

Kinetics of Ion-Molecule Reactions PDF Author: Pierre J. Ausloos
Publisher: Springer Science & Business Media
ISBN: 1461329310
Category : Science
Languages : en
Pages : 507

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Book Description
The investigation of the elementary reactions of reactive intermediate species began about half a centruy ago with the advent of free radical kinetics as an active area of chemical research. In spite of the relatively greater ease of detection of a species carrying an electrical charge, and the fact that organic chemists had for decades postulated mechanisms involving ionic intermediates, the systematic study of the elementary reactions of ions was delayed for more than twenty years after the first beginnings of free radical kinetics. Even at this writing, in 1978, the word "kinetics" is considered by many chemists to be synomomous with "kinetics of neutral species". Yet in spite of the relatively late start and separation from the mainstream of kinetics, the field of ion physics and chemistry is fluorishing, and growing at an ever faster pace. Instrumentalists devise ever more sophisticated apparatuses with capabilities of delving into nearly every aspect of the interactions between ions and molecules. Even satellites orbiting the earth are now being used effectively to determine rate coefficients of ionospheric ion-neutral reactions, some of which can not as yet be measured in the laboratory.

Gas Phase Ion Chemistry

Gas Phase Ion Chemistry PDF Author: Michael T. Bowers
Publisher: Academic Press
ISBN: 1483216497
Category : Science
Languages : en
Pages : 363

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Book Description
Gas Phase Ion Chemistry, Volume 2 covers the advances in gas phase ion chemistry. The book discusses the stabilities of positive ions from equilibrium gas-phase basicity measurements; the experimental methods used to determine molecular electron affinities, specifically photoelectron spectroscopy, photodetachment spectroscopy, charge transfer, and collisional ionization; and the gas-phase acidity scale. The text also describes the basis of the technique of chemical ionization mass spectrometry; the energetics and mechanisms of unimolecular reactions of positive ions; and the photodissociation of gas-phase ions. The applications of molecular beam techniques to the study of ion-molecule collisions; as well as the variational treatment of charge transfer reactions are also encompassed. Chemists and biochemists will find the book invaluable.

A Study of Ion-molecule Reactions Using the Flowing Afterglow Technique

A Study of Ion-molecule Reactions Using the Flowing Afterglow Technique PDF Author: Linda Margaret Parker
Publisher:
ISBN:
Category : Afterglow (Physics)
Languages : en
Pages : 270

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Book Description


Ion-Molecule Reactions

Ion-Molecule Reactions PDF Author: J. Franklin
Publisher: Springer Science & Business Media
ISBN: 1475700881
Category : Science
Languages : en
Pages : 394

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Book Description
After a few faint stirrings of interest in ion-molecule reactions during the early days of mass spectrometry, the subject was almost completely neglected for many years. There was a renascence of interest in the subject following pioneering experiments by Tal'roze in Russia and independently by Steven son and Schissler and Field, Franklin, and Lampe in this country. Since that time, interest in the subject has continued to grow and the number of papers published to expand almost exponentially during the past 15 years. The result is a body of literature that is now almost beyond any single individual's capacity for encompassing in his reading and research activities. Thus, it seemed timely to prepare a book giving in some detail a comprehen sive review of the field. Ideally, such a book would be written by one or possibly two authors. Unfortunately, the sheer bulk and variety of the studies of ion-molecule reactions has made it impractical for a single person to prepare a book on the subject in a time that would permit it to be issued before the material covered was obsolete. Consequently, the only practical, although surely not the ideal, solution is to issue a multiauthor volume. The present book represents our best efforts to accomplish this goal. We have secured from 18 authors material representing the most advanced work in the field and the resulting compilation is presented herein.

A Bibliography on Ion-molecule Reactions, January 1900 to March 1966

A Bibliography on Ion-molecule Reactions, January 1900 to March 1966 PDF Author: F. N. Harllee
Publisher:
ISBN:
Category : Ions
Languages : en
Pages : 48

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Book Description


Study of State-selected Ion Molecule Reactions Using Pulsed Field Techniques

Study of State-selected Ion Molecule Reactions Using Pulsed Field Techniques PDF Author: Denis Rolland
Publisher:
ISBN:
Category : ZEKE spectroscopy
Languages : en
Pages : 492

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Book Description


Dynamics of Ion-Molecule Complexes

Dynamics of Ion-Molecule Complexes PDF Author: William L Hase
Publisher: Elsevier
ISBN: 1483283623
Category : Science
Languages : en
Pages : 329

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Book Description
Advances in Classical Trajectory Methods, Volume 2: Dynamics of Ion-Molecule Complexes is a seven-chapter text that covers the considerable advances in the experimental and theoretical aspects of ion-molecular complexes, with particular emphasis on the dynamics and kinetics of their formation and ensuing unimolecular dissociation. This text also considers the development and testing of theoretical models for these formation and decomposition processes. The opening chapters discuss photoelectron photoion coincidence, ion cyclotron resonance, and crossed molecular beam studies of metastable ion-molecule complexes formed in ion-molecule collisions. These experimental studies involve comparisons with the predictions of statistical models, such as the Rice-Ramsperger-Kassel-Marcus and phase space theories, and comparisons with the reaction dynamics predicted by classical trajectory calculations. The succeeding chapter describes the double-well model for ion-molecular reactions taking place on a potential energy surface with a central barrier that separates two potential energy minima. These topics are followed by reviews of the quantum chemical calculation and reaction path Hamiltonian analysis of SN2 reactions, the transition state theory for ion-dipole and ion-quadrupole capture, and the capture and dynamical models for ion-molecule association to form a complex. The remaining chapters consider the temperature dependence of ion-molecule reactions, which proceed on a surface with many potential energy minima, specifically the ability to establish asymptotic limits for the reaction efficiency dependent upon the number of potential minima and the above relative probabilities. This book is of great value to experimental and theoretical chemists and physicists.

Ion-Molecule Reactions

Ion-Molecule Reactions PDF Author: J. L. Franklin
Publisher: Springer
ISBN: 9781468419405
Category : Science
Languages : en
Pages : 412

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Book Description


Ion/Molecule Attachment Reactions: Mass Spectrometry

Ion/Molecule Attachment Reactions: Mass Spectrometry PDF Author: Toshihiro Fujii
Publisher: Springer
ISBN: 1489975888
Category : Science
Languages : en
Pages : 350

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Book Description
This book explores the mechanism of alkali-metal ion/molecule association reaction, surveys the instrumental basis to study its kinetic, and describes the instrumentation to the measurement of alkali-metal ion affinities. The applications of the ion complexation mechanism in the condensed phase in reaction to direct analysis MS are also covered. Other topics include mechanism and reaction rate, experimental and theoretical ion affinities, applications of ion attachment reactions (IAR) to mass spectrometry such as alkali ion CIMS, ion attachment MS and cationization mass spectrometry of ESI, FAB, FD, LD, MALDI and SIMS and topics of IAR-based direct analysis mass spectrometry.