Synthesis of Platinum, Palladium and Rhodium Complexes of Α-aminophosphine Ligands PDF Download
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Languages : en
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Languages : en
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Author: Allan J. Canty
Publisher: Springer
ISBN: 3642174299
Category : Science
Languages : en
Pages : 195
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Kyle A. Grice, Margaret L. Scheuermann and Karen I. Goldberg: Five-Coordinate Platinum(IV) Complexes.- Jay A. Labinger and John E. Bercaw: The Role of Higher Oxidation State Species in Platinum-Mediated C-H Bond Activation and Functionalization.- Joy M. Racowski and Melanie S. Sanford: Carbon-Heteroatom Bond-Forming Reductive Elimination from Palladium(IV) Complexes.- Helena C. Malinakova: Palladium(IV) Complexes as Intermediates in Catalytic and Stoichiometric Cascade Sequences Providing Complex Carbocycles and Heterocycles.- Allan J. Canty and Manab Sharma: h1-Alkynyl Chemistry for the Higher Oxidation States of Palladium and Platinum.- David C. Powers and Tobias Ritter: Palladium(III) in Synthesis and Catalysis.- Marc-Etienne Moret: Organometallic Platinum(II) and Palladium(II) Complexes as Donor Ligands for Lewis-Acidic d10 and s2 Centers.
Author: Mark Ralph Lewtas
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Category : Sulfides
Languages : en
Pages :
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Author: Robert L. Cowan
Publisher:
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Category :
Languages : en
Pages : 358
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Author: Seher Kuyuldar Tastan
Publisher:
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Category :
Languages : en
Pages : 206
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Synthetic, structural, spectroscopic, and redox studies of platinum(II) and palladium(II) compounds with mer-coordinating ligands have been undertaken in an effort to better understand the role of the metal and the ligands in controlling d^6/d^8 electron-transfer reactions. A series of Pd(pip2NCN)X (pip2NCNH=1,3-bis(piperdylmethyl)benzene) and [Pd(pip2NNN)X]X (X=Cl, Br, I) (pip2NNN=2,6- bis(piperdyl-methyl)pyridine) complexes are reported. Electronic spectra are consistent with stabilization of ligand-to-metal-charge-transfer states as the ancillary ligand is varied along the ClBr
Author: Eric Mentzer
Publisher:
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Category :
Languages : en
Pages : 460
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Author: Mark Ralph Lewtas
Publisher:
ISBN:
Category : Sulfides
Languages : en
Pages : 0
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![Synthesis and Electrochemistry Studies of Palladium and Platinum Complexes Containing Chiral C[subscript]2-symmetric Bis(oxazoline) Ligands and Platinum Complexes of the Chiral C[subscript]2-symmetric Bidentate Phosphine Ligand Diop PDF](https://books.google.com/books/content/images/frontcover/nllCnQEACAAJ?fife=w80-h100)
Author: Kara Leigh Cetto
Publisher:
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Category :
Languages : en
Pages : 268
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In an effort to design complexes in which electrochemical reduction does not result in loss of the chiral ligand, five different bis(oxazoline) ligands were prepared (3, 5, 7, 8 and 9). 3 was found to have poor solubility and an exceedingly negative reduction potential of Ep[subscript]c= -2.38 V. Chemical reduction studies of 5 revealed that the bis(oxazoline) ligand is ejected during the reduction process. Compound 7 was found to have a reduction potential of Ep[subscript]c= -1.12 V. However, ejection of the chiral ligand occurs when other bis(oxazoline) platinum and palladium dichloride complexes are reduced. Therefore, a neutral PdClMe complex (8) with a reduction potential of Ep[subscript]c= -2.97 V and a cationic Pd(CH[subscript]3CN)Me complex (9) (Ep[subscript]c= -1.38 V) were also prepared. A platinum complex of the bidentate phosphine ligand was then investigated. Electrochemistry studies revealed that 11 undergoes a two-electron reduction process in which the ligand remains bound to the metal. The synthesis of Pt(DIOP)(trans-stilbene) through the chemical and electrochemical reduction of 11 further demonstrated that DIOP remains bound to platinum after reduction of 11.
Author: Janet Lynne Whittemore
Publisher:
ISBN:
Category : Ligands
Languages : en
Pages : 180
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Author: Evan Lunt
Publisher:
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Category :
Languages : en
Pages : 58
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