Synthesis and Reactivity of Rhodium and Iridium Silyl and Silylene Complexes Supported by PNP Pincer Ligands PDF Download
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Author: Elisa E. Calimano
Publisher:
ISBN:
Category :
Languages : en
Pages : 552
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Book Description
Author: Elisa E. Calimano
Publisher:
ISBN:
Category :
Languages : en
Pages : 552
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Book Description
Author: MacLean Darren F.
Publisher:
ISBN:
Category :
Languages : en
Pages : 288
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Author: Erin Morgan
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Category :
Languages : en
Pages :
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Author: Thomas M. Hood
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Category :
Languages : en
Pages :
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Author: Baptiste Leforestier
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Category :
Languages : en
Pages :
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Author: Ann Marie Mueting
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Category :
Languages : en
Pages : 586
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Author: Stuart Edward Smith
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Category :
Languages : en
Pages : 394
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Author: Samuel Mitton
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Category :
Languages : en
Pages :
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Author: Gordon J. Hunter
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Category : Dissertations, Academic
Languages : en
Pages : 66
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Author: Amy Marie Jehl
Publisher:
ISBN: 9781085729345
Category : Carbon dioxide
Languages : en
Pages : 237
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Book Description
N-heterocyclic carbenes (NHC) are strong Lewis bases that have demonstrated broad utility as ligands for transition metal (TM) catalysts. Silicon analogues, N-heterocyclic silylenes (NHSi), are comparatively less well studied. The decreased [Pi]-[pi] overlap between the Si 3p orbital and adjacent nitrogen lone pairs creates a more accessible vacant orbital on Si, resulting in increased ambiphilic character. When bound to a transition metal, this empty orbital presents an opportunity to cooperatively bind and activate substrate molecules. To increase the stability of a potential metal-silylene complex we targeted the diphosphine ligand precursor 1,2-bis(R2PCH2NCH2)C6H4 (R = alkyl or aryl), first reported by Yamashita and Nozaki in the construction of a boron-anchored pincer. Reported here are (PCy)2Si pincer ligands and their TM-silylene complexes for small molecule activation.
