Synthesis and Modeling of Transition Metal Complexes Using Histidine as the Ligand PDF Download
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Author: Falonne Moumbogno Tchodimo Colbie
Publisher:
ISBN:
Category :
Languages : en
Pages : 132
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Author: Falonne Moumbogno Tchodimo Colbie
Publisher:
ISBN:
Category :
Languages : en
Pages : 132
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Author:
Publisher: John Wiley & Sons
ISBN: 0470132981
Category : Science
Languages : en
Pages : 360
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Book Description
The Inorganic Synthesis Series provides all users of inorganic substances with detailed and foolproof procedures for the preparation of important and timely compounds. This new volume includes information on water-solubilizing ligands for organometallics, labile ligand complexes, and the syntheses of cluster compounds and hydrides.
Author: P.L. Soni
Publisher: CRC Press
ISBN: 1000404137
Category : Science
Languages : en
Pages : 403
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Book Description
This book covers all important nomenclature, theories of bonding and stereochemistry of coordination complexes. The authors have made an effort to inscribe the ideas knowledge, clearly and in an interesting way to benefit the readers. The complexities of Molecular Orbital theory have been explained in a very simple and easy manner. It also deals with transition and inner transition metals. Conceptually, all transition and inner transition elements form complexes which have definite geometry and show interesting properties. General and specific methods of preparation, physical and chemical properties of each element has been discussed at length. Group wise study of elements in d-block series have been explained. Important compounds, complexes and organometallic compounds of metals in different oxidation states have been given explicitly. Note: T&F does not sell or distribute the Hardback in India, Pakistan, Nepal, Bhutan, Bangladesh and Sri Lanka.
Author: Eva Neumann
Publisher: Cuvillier Verlag
ISBN: 3736918011
Category : Science
Languages : en
Pages : 244
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Book Description
The term ligand [latin, ligare = bind] has its origin in coordination chemistry. It denotes a molecule that is able to bind to a metal center in most cases via one or several free electron pairs.[1] Ligands can be described by the number of electron-pair donor atoms as monodentate, bidentate, tridentate etc. ligands. The latter are also called chelating ligands [greek, chele = (crab’s) claw]. A typical classification of ligands is according to their electronic properties. They serve either as a σ-donating, σ-donating/π-accepting, or σ,π-donating/π-accepting ligands.[2] A more practical, often encountered approach is the classification of ligands according to their donor atoms, especially when larger molecules and molecules containing heteroatoms are regarded (compare 1.2). Coordination chemistry was already established in the 19th century. In 1893 Alfred Werner suggested an octahedral arrangement of ligands coordinated to a central metal ion for many compounds. This explained, for example, the appearance and reactivity of four different cobalt(III) complexes (Figure 1.1), when CoCl2 is dissolved in aqueous ammonia and then oxidized by air to the +3 oxidation state. The formulas of these complexes can be written as depicted in Figure 1.1. Werner’s work was rewarded with the Nobel prize in 1913.[3]
Author: Robert Joseph O'Brien
Publisher:
ISBN:
Category : Ligands (Biochemistry)
Languages : en
Pages : 202
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Author: Gregory A. Marinelli
Publisher:
ISBN:
Category :
Languages : en
Pages : 124
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Author: Louis S. Hegedus
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 488
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Book Description
The third edition of Transition Metals in the Synthesis of Complex Organic Molecules is a comprehensive revision and significant expansion of the second edition. The clear and systematic approach to the formation, manipulation, and reactivity of organometallic complexes has been maintained. The book is divided into 10 chapters starting with general formalisms, electron counting, and basic principles of organometallic reaction mechanisms. The organic chemistry of transition metals is then presented by class of metal complex, with many examples of applications in the synthesis of complex natural products and pharmaceuticals. The book is ideal for advanced undergraduate and graduate students as well as all practicing synthetic organic chemists. It is written for organic chemists and offers an easy entry into the field of organotransition metal chemistry without requiring a background in inorganic chemistry.
Author: John L Burmeister
Publisher: World Scientific
ISBN: 9814488003
Category : Science
Languages : en
Pages : 654
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Book Description
This invaluable book distils the research accomplishments of Professor Fred Basolo during the five decades when he served as a world leader in the modern renaissance of inorganic chemistry. Its primary focus is on the very important area of chemistry known as coordination chemistry.Most of the elements in the periodic table are metals, and most of the chemistry of metals involves coordination chemistry. This is the case in the currently significant areas of research, including organometallic homogenous catalysis, biological reactions of metalloproteins, and even the solid state extended structures of new materials. In these systems, the metals are of primary importance because they are the sites of ligand substitution or redox reactions. In the solid materials, the coordination number of the metal and its stereochemistry are of major importance.Some fifty years of research on transition metal complexes carried out in the laboratory of Professor Basolo at Northwestern University is recorded here as selected scientific publications. The book is divided into three different major research areas, each dealing with some aspect of coordination chemistry. In each case, introductory remarks are presented which indicate what prompted the research projects and what the major accomplishments were. Although the research was of the academic, curiosity-driven type, some aspects have proven to be useful to others involved in projects that were much more applied in nature.
Author: Satcher, Jr. (Joe Harold)
Publisher:
ISBN:
Category :
Languages : en
Pages : 622
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Author: Karoline Kristina Mosny
Publisher:
ISBN:
Category :
Languages : en
Pages :
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